A functional graphene oxide nanoribbons/manganese dioxide composite material (MnO2-GONRs) was synthesized by hydrothermal method using graphene oxide nanoribbons (GONRs) as raw material which were formed by longitudinal unzipping of multi-walled carbon nanotubes with KMnO4 and H2SO4. The microstructure of MnO2-GONRs was characterized by SEM and FT-IR. The various factors affecting the adsorption of Th(IV) in aqueous solution such as pH, solid–liquid ratio, contact time, initial concentration and temperature were investigated by batch static adsorption experiments, and the adsorption mechanism is also discussed. The results showed that MnO2-GONRs had a good adsorption effect on Th(IV) with a maximum adsorption of 166.11 mg/g.
A study was made on the adsorption kinetics and thermodynamics of methylene blue(MB) and acid blue 80(AB80) onto powder of activated carbon(PAC) prepared by chemical method from dry potato residue(DPR). The PAC was characterized by N2 adsorption-desorption isotherms analysis and scanning electron microscopy. The ma- ximum adsorption capacities of PAC for MB and AB80 at 303 K are 532.19 and 156.22 mg/g, respectively. The results indicate that the adsorption kinetics of the selected dyes on PAC is well-described by the pseudo-second order model. And their thermodynamic data were analyzed via the isotherms of Langmuir, Freundlich, Redlich-Peterson, Toth and Sips, and the thermodynamic parameters were calculated. The results show that PAC is a fast and effective adsorbent for removing the cationic dyes from aqueous solutions. 相似文献
With the fast development of financial products and services, bank’s credit departments collected large amounts of data, which risk analysts use to build appropriate credit scoring models to evaluate an applicant’s credit risk accurately. One of these models is the Multi-Criteria Optimization Classifier (MCOC). By finding a trade-off between overlapping of different classes and total distance from input points to the decision boundary, MCOC can derive a decision function from distinct classes of training data and subsequently use this function to predict the class label of an unseen sample. In many real world applications, however, owing to noise, outliers, class imbalance, nonlinearly separable problems and other uncertainties in data, classification quality degenerates rapidly when using MCOC. In this paper, we propose a novel multi-criteria optimization classifier based on kernel, fuzzification, and penalty factors (KFP-MCOC): Firstly a kernel function is used to map input points into a high-dimensional feature space, then an appropriate fuzzy membership function is introduced to MCOC and associated with each data point in the feature space, and the unequal penalty factors are added to the input points of imbalanced classes. Thus, the effects of the aforementioned problems are reduced. Our experimental results of credit risk evaluation and their comparison with MCOC, support vector machines (SVM) and fuzzy SVM show that KFP-MCOC can enhance the separation of different applicants, the efficiency of credit risk scoring, and the generalization of predicting the credit rank of a new credit applicant. 相似文献
Mesoporous titania nanoparticles (denoted as MTN) with high surface area (e.g., 252 m2 g−1) were prepared using tetrapropyl orthotitanate (TPOT) as a titania precursor and 10–20 nm or 20–30 nm silica colloids as
templates. Co-assembly of TPOT and silica colloids in an aerosol-assisted process and immediate calcination at 450 °C resulted
in anatase/silica composite nanoparticles. Subsequent removal of the silica colloids from the composite by NaOH solution created
mesopores in the TiO2 nanoparticles with pore size corresponding to that of silica colloids. Effects of silica colloids’ contents on MTN porosity
and crystallites’ growth at a higher calcination temperature (e.g., 1000 °C) were investigated. Silica colloids suppressed
the growth of TiO2 crystallites during calcination at a higher calcination temperature and controllable contents of the silica colloids in precursor
solution resulted in various atomic ratios of anatase to rutile in the calcinated materials. The mesostructure and crystalline
structure of these titania materials were characterized by transmission electron microscope (TEM), scanning electron microscope
(SEM), X-ray diffraction (XRD), differential thermal analysis (DTA)-thermo-gravimetric analysis (TGA), and N2 sorption. 相似文献
Seven different aminomethyl polystyrene resins supported dendritic Sn complexes were prepared by solid phase synthesis methodology. All the synthesized complexes show promising catalytic activities for the Baeyer‐Villiger oxidation of ketones with hydrogen peroxide and affording the corresponding lactones or esters. The influence of different pore structures and the degree of crosslinking of the aminomethyl polystyrene resins on catalytic properties of the supported dendritic Sn complexes were well discussed. 相似文献
A novel zeolitic imidazolate framework (ZIF‐8) nanoparticles@polyphosphazene (PZN) core‐shell architecture was synthesized, and then, ZIF‐8@PZN and ammonium polyphosphate (APP) were applied for increasing the flame retardancy and mechanical property of epoxy resin (EP) through a cooperative effect. Herein, ZIF‐8 was used as the core; the shell of PZN was coated to ZIF‐8 nanoparticles via a polycondensation method. The well‐designed ZIF‐8@PZN displayed superior fire retardancy and smoke suppression effect. The synthesized ZIF‐8@PZN observably raised the flame retardancy of EP composites, which could be demonstrated by thermogravimetric analysis (TGA) and a cone calorimeter test (CCT). The chemical structure of ZIF‐8@PZN was characterized by X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). Compared with pure epoxy, with the incorporation of 3 wt% ZIF‐8@PZN and 18 wt% APP into the EP, along with 80.8%, 72.6%, and 64.7% decreased in the peak heat release rate (pHRR), the peak smoke production rate (pSPR), and the peak CO production rate (pCOPR), respectively. These suggested that ZIF‐8@PZN and APP generated an intumescent char layer, and ZIF‐8@PZN can strengthen the char layer, resulting in the enhancement in the flame resistance of EP. 相似文献
Journal of Radioanalytical and Nuclear Chemistry - The main structure of polystyrene-divinylbenzene (PSD) was synthesized by suspension method, and chlorinated resin (PSD-Cl) obtained by... 相似文献