全文获取类型
收费全文 | 85篇 |
免费 | 3篇 |
国内免费 | 9篇 |
专业分类
化学 | 64篇 |
力学 | 5篇 |
数学 | 16篇 |
物理学 | 12篇 |
出版年
2022年 | 1篇 |
2017年 | 1篇 |
2015年 | 1篇 |
2014年 | 4篇 |
2013年 | 13篇 |
2012年 | 2篇 |
2011年 | 3篇 |
2010年 | 7篇 |
2009年 | 3篇 |
2008年 | 2篇 |
2007年 | 7篇 |
2006年 | 5篇 |
2005年 | 4篇 |
2004年 | 1篇 |
2003年 | 3篇 |
2002年 | 8篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有97条查询结果,搜索用时 296 毫秒
1.
An x-ray diffraction structural analysis was carried out on 1H+,10H+-1,10-diazonia-18-crown-6 diethyldithiophosphate, which exists in the crystal as isolated ionic hydrogen-bonded complexes [H2DA18C6]2+·2(EtO)2PS2
– with strong inter-ion N-HS hydrogen bonds. The centrosymmetric DA18C6 dication has an unusual two-cornered conformation stabilized by a pair of weak intra-ring furcated OH(N)O hydrogen bonds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 190–192, January, 1991. 相似文献
2.
Nail Zabirov Sergej Kashevarov Rafael Cherkasov 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4)
Abstract N-(thio)carbonyl(thio)amidophosphates, their open-chain and crown-containing analogues with a C (X) NHP (Y) fragments are NH acids with pKa 8–11 and the effective complexing agents for “soft” ion metals. 相似文献
3.
Larisa G. Shaidarova Larisa G. Popesku Nikolay A. Ulakhovich Herman C. Budnikov Nail G. Zabirov 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract Crown-containing N-(thio)phosphoryl(thio)ureas are related to a class of NH-acids due to the presence of two acceptor-groups: (thio)phosphorylic and (thio)acylic. In agreement with structure of lariat ether, it was observed a stage corresponding to the step ejection of two H* ion on the potentiometric titration curve of ligand by alkaline. Calculated step ionization constants demonstrate that these compounds are weak acids with relative values of pK1 and pK2. 相似文献
4.
5.
6.
The boron atom in C22H15BO5 is O,O’-chelated by the anions in a tetrahedral geometry, with the planar five-and six-membered chelate rings being orthogonal to each other. The molecule lies on a two-fold rotation axis. The molecule is disordered with respect to another molecule in a 93:7 ratio; the treatment of the ‘whole-molecule disorder’ by employing a large number of restraints is described. Crystal data: C22H15BO5, monoclinic C2/c, a = 17.1804(5), b = 12.9409(4), c = 9.8842(3) , β = 124.832(2)o, V = 1803.82(9) 3 at –173 K. 相似文献
7.
8.
A general formulation of the nonlinear filtering problem inRiemanman manifolds is given by use of the strong solutionsof the stochastic differential equations for the state and observationprocesses in the orthonormal frame bundles of the state andobservation process manifolds, respectively. A general Bayesformula for the conditional expectation of smooth functionsof the state process is given. This is used to give a directderivation of the Zakai equation for the general problem underconsideration. An example is presented. 相似文献
9.
10.
We obtain rigidity results on arbitrary proper holomorphic maps F from an irreducible bounded symmetric domain Ω of rank ≥2 into any complex space Z. After lifting to the normalization of the subvariety F (Ω) Z, we prove that F must be the canonical projection map to the quotient space of Ω by a finite group of automorphisms. The approach is along the line of the works of Mok and Tsai by considering radial limits of bounded holomorphic functions derived from F and proving that proper holomorphic maps between bounded symmetric domains preserve certain totally geodesic subdomains. In contrast to the previous works, in general we have to deal with multivalent holomorphic maps for which Fatou’s theorem cannot be applied directly. We bypass the difficulty by devising a limiting process for taking radial limits of correspondences arising from proper holomorphic maps and by elementary estimates allowing us to define distinct univalent branches of the underlying multivalent map on certain subsets. As a consequence of our rigidity result, with the exception of Type-IV domains, any proper holomorphic map f : Ω→ D of Ω onto a bounded convex domain D is necessarily a biholomorphism. In the exceptional case where Ω is a Type-IV domain, either f is a biholomorphism or it is a double cover branched over a totally geodesic submanifold which can be explicitly described. 相似文献