Polycationic‐Shelled Capsular and Tubular Nanostructures and Their Anionic–Guest Binding Properties

For the development of novel nanospace with unique electrostatic character, we prepared new capsular and tubular nanostructures by the quantitative assembly of metal ions and bent bisacridinium ligands. The capsule and tube have closed spherical and open cylindrical cavities, respectively, with diameters of around 1 nm surrounded by cationic polyaromatic panels. Thanks to the facile synthetic protocol (three steps), another polycationic capsule with an elliptical nanocavity was also prepared by using an elongated ligand. In spite of the absence of pendant hydrophilic groups, the spherical polyaromatic capsule shows sufficient water solubility due to the polycationic shell. Moreover, the highly cationic cavity (12+) can selectively encapsulate anionic organic compounds in water.     

Chemoselective Catalytic Conjugate Addition of Alcohols over Amines

A highly chemoselective conjugate addition of alcohols in the presence of amines is described. The cooperative nature of the catalyst enabled chemoselective activation of alcohols over amines, allowing the conjugate addition to soft Lewis basic α,β‐unsaturated nitriles. Divergent transformation of the nitrile functionality highlights the utility of the present catalysis.     

Alkylation‐, Heating‐, and Doping‐Induced Emission Enhancement of a Polyaromatic Tube in the Solid State

A polyaromatic tube with a subnanometer‐sized cavity was efficiently prepared on a gram‐scale through the stereo‐controlled cyclotrimerization of a diphenylanthracene derivative as a key step. The facile exterior alkylation of the polyaromatic framework leads to a moderately fluorescent tube (R=‐OC₁₀H₂₁; Φ_F=20 %) in the solid state. The emission intensity of the solid‐state alkyl‐substituted tube is remarkably enhanced upon heating (up to 1.6 times, Φ_F=31 %) as well as doping with fluorescent dyes (up to 4.2 times, Φ_F=83 %) through efficient energy transfer.     

An M2L4 Molecular Capsule with a Redox Switchable Polyradical Shell

Preparation of molecular nanostructures with polyradical frameworks remains a significant challenge because of the limited synthetic accessibility which is entirely different from that of neutral and ionic ones. Herein we report the quantitative formation of a new M₂L₄ molecular capsule from metal ions and dihydrophenazine‐based ligands. The capsule has a spherical nanocavity (ca. 1 nm in diameter) enclosed by eight redox‐active, dihydrophenazine panels. Electrochemical oxidation of the capsule leads to the generation of multiple radical cations on the shell framework. Moreover, a stable tetra(radical cation) capsule can be reversibly obtained by chemical as well as electrochemical oxidation.     

Pion condensation in symmetric nuclear matter

The problem of pion condensation in isospin symmetric nuclear matter is investigated in the framework of the σ-model with a residual nucleon-nucleon interaction (g′σ₁ · σ₂τ₁ · τ₂δ(x)) and Δ-isobars. The equation of state for the pion condensed phase is calculated and applied to a low-energy heavy-ion collision in the TDHF approximation. The effective particle-hole interaction and the response to spin-isospin excitation are used to determine the magnitude of the Landau-Migdal parameter g′. For a reasonable range of g′(0.5 < g′ ≦ in units of g²/4m²_N = 410 MeV · fm³) pion condensation occurs at densities above normal nuclear matter density and leads to an equation of state with no stable density isomer.     

Effects of annealing on gap states in amorphous Si films

Annealing behaviors of the activation energy for electrical conduction, the optical gap, and the spin density in amorphous Si are investigated. It is found that the Fermi level shifts downwards with the decrease of the spin density, increasing the decay length of the wave function of localized state at the Fermi level. The downward shift of the Fermi level suggests that the localized states in the upper energy region in the gap are annealed out more easily than those in the lower one.     

QCD sum rules for heavy quark systems

In this paper we present in a detailed and coherent fashion our work on QCD sum rules for equal mass heavy quark meson states. We discuss the technical procedures used to calculate the perturbative and non-perturbative contributions to the vacuum polarization, which have been calculated for all currents up to and including spin 2⁺⁺. Using dispersion relations, sum rules are derived. Extensive applications are made to the lowest lying states of the charmonium and upsilon systems. The masses of the S- and P-wave charmonium levels are reproduced to a high degree of accuracy, and the mass of the ¹P₁ level is predicted at 3.51 GeV. For the upsilon system it only appears to be possible to predict the γ-η_b splitting which gives 60 MeV. Very accurate values are given for the current quark masses at p² = ?m_q²: m_c = 1.28 GeV and m_b = 4.25 GeV.     

Life time of soft multipole excitations

Decay of soft multipole excitations in halo nuclei is studied in comparison with the potential resonance state. Although the soft excitation has a sharp peak just above the particle threshold and carries extremely large transition strength, the decay rate looks much faster than that expected for a resonance state. Consequently, the half life is shown to be several orders of magnitude shorter than what one naively expects from the uncertainty principle. It is shown also that the soft excitations accumulate large transition strength as a non-resonant single-particle excitation, but not as particle-hole collective excitations like giant resonances.     

Ferromagnetic interaction between spins in amorphous SiGe films

Temperature dependence of the ESR signal intensity in amorphous SiGe films annealed at various temperatures is investigated. As a result, it is found that spins undergo a ferromagnetic interaction and the Curie-Weiss θ in the relation χ = C/ (T-θ) distributes between 40 and 135 K. The ferromagnetic behavior suggests that spins are inhomogeneously distributed and closely located together.