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1.
2.
Dr. Yasunori Minami Prof. Dr. Tamejiro Hiyama 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(2):391-399
Organo(trialkyl)silanes have several advantages, including high stability, low toxicity, good solubility, easy handling, and ready availability compared with heteroatom-substituted silanes. However, methods for the cross-coupling of organo(trialkyl)silanes are limited, most probably because of their exceeding robustness. Thus, a practical method for the cross-coupling of organo(trialkyl)silanes has been a long-standing challenging research target. This article discusses how aryl(trialkyl)silanes can be used in cross-coupling reactions. A pioneering example is CuII catalytic conditions with the use of electron-accepting aryl- or heteroaryl(triethyl)silanes and aryl iodides. The reaction forms biaryls or teraryls. This design concept can be extended to Pd/CuII-catalyzed cross-coupling polymerization reactions between such silanes and aryl bromides or chlorides and to CuI-catalyzed alkylation using alkyl halides. 相似文献
3.
Prof. Jun Ishihara Fuma Usui Tomohiro Kurose Tomohiro Baba Yasunori Kawaguchi Yuki Watanabe Prof. Susumi Hatakeyama 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(6):1543-1552
The upper fragment of spirolides A and B, which are marine phycotoxins that exhibit strong antagonistic activities on nicotinic acetylcholine receptors, was constructed. The functionalized cyclohexene in spirolides was stereoselectively synthesized from the bicyclic lactone, which could be readily accessed by the Lewis acid template-catalyzed asymmetric Diels–Alder reaction of the pentadienol and methyl acrylate. 相似文献
4.
Dr. Yasunori Toda Takayuki Yoshida Kaoru Arisue Prof. Dr. Kazuaki Fukushima Dr. Hiroyoshi Esaki Ayaka Kikuchi Prof. Dr. Hiroyuki Suga 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(41):10578-10582
Chiral Lewis acid-catalyzed asymmetric alcohol addition reactions to cyclic carbonyl ylides generated from N-(α-diazocarbonyl)-2-oxazolidinones featuring a dual catalytic system are reported. Construction of a chiral quaternary heteroatom-substituted carbon center was accomplished in which the unique heterobicycles were obtained in good yields with high stereoselection. The alcohol adducts were successfully converted to optically active oxazolidine-2,4-diones by hydrolysis. Mechanistic studies by DFT calculations revealed that alcohols could be activated by Lewis acids, enabling enantioselective protonation of the carbonyl ylides. 相似文献
5.
(S)-(-)-Ipsenol (2b) and (S)-(+)-ipsdienol (4b), a major component of the sex pheromone of the bark beetle, and their enantiomers (3b and 5b) were prepared enantioselectively using tartrate esters of (2-bromoallyl)boronic acid in the key step. 相似文献
6.
7.
Yasunori Maekawa 《Journal of Mathematical Fluid Mechanics》2011,13(4):515-532
We study a linearized operator of the equation for the axisymmetric Burgers vortex which gives a stationary solution to the
three dimensional Navier–Stokes equations with an axisymmetric background straining flow. It is numerically known that the
Burgers vortex obtains better stabilities as the circulation number (or the vortex Reynolds number) is increasing. Although
the global stability of the axisymmetric Burgers vortex is already proved rigorously, mathematical understanding of this numerical
observation has been lacking. In this paper we study a linearized operator that includes the circulation number as a parameter,
and prove that if the operator is restricted on a suitable invariant subspace, then its spectrum moves to the left as the
circulation number goes to infinity. As an application, we show that the axisymmetric Burgers vortex with a high rotation
has a better stability, in the sense that the non-radially symmetric part of solutions to the associated evolution equation
decays faster in time if the circulation number is sufficiently large. 相似文献
8.
Yasunori Fujikoshi Tamio Kan Shin Takahashi Tetsuro Sakurai 《Annals of the Institute of Statistical Mathematics》2011,63(2):387-403
Several criteria, such as CV, C
p
, AIC, CAIC, and MAIC, are used for selecting variables in linear regression models. It might be noted that C
p
has been proposed as an estimator of the expected standardized prediction error, although the target risk function of CV
might be regarded as the expected prediction error R
PE. On the other hand, the target risk function of AIC, CAIC, and MAIC is the expected log-predictive likelihood. In this paper,
we propose a prediction error criterion, PE, which is an estimator of the expected prediction error R
PE. Consequently, it is also a competitor of CV. Results of this study show that PE is an unbiased estimator when the true model
is contained in the full model. The property is shown without the assumption of normality. In fact, PE is demonstrated as
more faithful for its risk function than CV. The prediction error criterion PE is extended to the multivariate case. Furthermore,
using simulations, we examine some peculiarities of all these criteria. 相似文献
9.
A robust, practical synthesis of (20S)‐10‐(3‐aminopropyloxy)‐7‐ethylcamptothecin (T‐2513, 5 ), which is a water‐soluble analogue of camptothecin, has been developed. The key step in this synthesis is a highly diastereoselective ethylation at the C20 position by using N‐arylsulfonyl‐(R)‐1,2,3,4‐tetrahydroisoquinoline‐3‐carboxylic acid ester as a chiral auxiliary, which affords the key intermediate ethyl‐(S)‐2‐acyloxy‐2‐(6‐cyano‐5‐oxo‐1,2,3,5‐tetrahydroindolizin‐7‐yl)butanoate ( 8 k ) in 93 % yield and 87 % de. Optically pure compound 8 k was obtained by a single recrystallization from acetone and its further elaboration through Friedlander condensation afforded compound 5 . This synthesis does not require any chromatographic purification steps and can provide compound 5 on a multi‐gram scale in 6.3 % overall yield (16 steps). 相似文献
10.
Synthesis of Substituted Phenyl Esters of Amino Acids and Polycondensation in Langmuirblodgett Films
Kenji Hanabusa Takekazu Oumi Toshiki Koyama Hirofusa Shirai Tadao Hayakawa Akio Kurose 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):1397-1413
Long-alkyl-chain phenyl esters of β-alanine, glycine, and L-valine were prepared, and their monolayer properties were correlated with their molecular structures. These compounds formed stable monolayers on acidic subphases. In particular, the p-hexadecylphenyl esters of β-alanine and glycine were remarkably stable, and their monolayers could be deposited on calcium fluoride plates as Y-type film by Blodgett's technique. The polycondensation of multilayers under an atmosphere saturated with triethylamine was investigated by changes in the IR spectra. It was determined that the polycondensation proceeded by a first-order reaction mechanism in the initial stage and that the rate in multilayers was faster than that in the bulk crystalline powder. These results suggest that the polycondensation is accelerated by a regular arrangement of the monomer in the multilayers, where the active sites are concentrated and located better for the polycondensation. In the case of the polycondensation in multilayers of the glycine ester, two kinds of condensation proceeded to afford poly(glycine) and 2,5-piperazinedione. 相似文献