Geometry of an Accelerated Rotating Disk

We analyze the geometry of a rotating disk with a tangential acceleration in the framework of the theory of Special Relativity, using the kinematic linear differential system that verifies the relative position vector of time-like curves in a Fermi reference. A numerical integration of these equations for a generic initial value problem is made up and the results are compared with those obtained in other works.     

Inclusive (γ, N), (γ, NN) and (γ, Nπ) reactions in nuclei at intermediate energies

Differential cross sections of nucleons excited in photonuclear reactions in medium and heavy nuclei are studied by considering all relevant reaction mechanisms leading to the excitation of protons or neutrons. We take advantage of previous microscopic studies for the absorption and scattering of photons and photoproduced pions, and implement a simulation code in order to take into account the propagation of the nucleons as well as their collisions with other nucleons in the nuclear medium, which generate secondary excited nucleons. Comparison with experimental data is done. Cross sections for nucleon emission in coincidence with one pion are also calculated, and some coincidence observables are discussed.     

Comparison of Several Calibration Procedures for Glass Electrodes in Proton Concentration

Several reported procedures for calibrating glass electrodes in proton concentration are compared. Some recommendations for non-experts are also given. The examined procedures can be classified into two broad categories, namely: those based on direct potential difference measurements of solutions of known proton concentration and those that use one or several pH standards to calibrate the electrode and subsequently measure the pH of solutions containing known proton concentrations. With a single buffer, the two types of procedures lead to equivalent results. However, if two pH buffers are used, the slope of the calibration graph in proton concentration will differ from the real electrode slope to an extent proportional to the difference between the liquid junction potentials of the two buffers. Therefore, any other method is preferable under these circumstances.     

Voltammetric determination of methyl parathion, ortho, meta and para nitrophenol with a carbon paste electrode modified with C18

Summary The determination of methyl-parathion (MPT), ortho (ONP), meta (MNP) and para nitrophenol (PNP) has been studied by differential pulse voltammetry with a carbon-paste electrode modified with 50% (w/w) of C₁₈. A study of the influence of the pH in the preconcentration cell and the measurement cell was carried out for an electrode with 50% modifier and an accumulation time of 5 min. The voltammograms were recorded with a sweep rate of 40 mV s^–1 and a pulse amplitude of 50 mV. With the optimum conditions of pH for both of the steps, various other variables were studied. The variables for each compound were optimized and the possibility of application to the determination of a mixture of the four compounds was investigated. The determination limits found for all the compounds are: 2 ng ml^–1 for ONP, 5 ng ml^–1 for MNP, 4.3 ng ml^–1 for PNP and 7.9 ng ml^–1 for MPT. The method was applied to samples of a small lake which gathers rain water and water filtered from land on which cereals are grown.     

Enzymatic synthesis of 3-hydroxybutyramides and their conversion to optically active 1,3-aminoalcohols

3-Hydroxybutyramides are obtained in high optical yield from ethyl (±)-3-hydroxybutyrate and aliphatic amines when the reaction is catalyzed by Candida antartica lipase. The chemical reduction of these 3-hydroxybutyramides yields the corresponding 1,3 -aminoalcohols.