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排序方式: 共有307条查询结果,搜索用时 15 毫秒
1.
2.
Curved Ferroelectric Liquid Crystal Matrix Displays Driven by Field-Sequential-Color and Active-Matrix Techniques 总被引:1,自引:0,他引:1
Hideo Fujikake Hiroto Sato Takeshi Murashige Yoshihide Fujisaki Taiichiro Kurita Tadahiro Furukawa Fumio Sato 《Optical Review》2006,13(1):14-19
This paper describes a curved field-sequential-color matrix display using fast-response ferroelectric liquid crystal. Black
matrix and transparent electrode patterns were formed on a thin plastic substrate by a transfer method from a glass substrate.
While a composite film of liquid crystal and micro-polymers of walls and fibers was formed between the flexible substrates
by printing, laminating and curing processes of a solution of monomers and liquid crystal, the mechanical stability was enhanced
by use of multi-functional monomers to form large display panels. The image pixels of the matrix panel were driven by an active
matrix scheme using an external switch transistor array at a frequency of 180 Hz for intermittent three-primary-color backlight
illumination. The flexible A4-paper-sized color display with 24 × 16 pixels and 60 Hz field frequency was demonstrated by
illuminating it with sequential three-primary-color lights from light-emitting diodes of the backlight. Our display system
is useful in various information displays because of its freedom of setting and location. 相似文献
3.
The structure of senecicannabine(), a new mcrocyclic pyrrolizidine alkaloid isolated from , has been established by chemical study and X-ray analysis. 相似文献
4.
5.
Racemic 2-amino-3-(heteroaryl)propanoic acids (1), mostly with a furan or thiophene nucleus as a heteroaryl group, were synthesized in 48-94% yield by the reduction of 3-(heteroaryl)-2-(hydroxyimino)propanoic acids (5) with zinc dust and formic acid in the presence of a catalytic amount of iron dust at 60 degrees C for 2 h. Under these conditions, unfavorable hydrogenolysis of bromine on the thiophene nucleus does not occur. Traditional N-formylation of the prepared 3-(heteroaryl)alanine (1) with a mixture of formic acid and acetic anhydride afforded 2-(formylamino)-3-(heteroaryl)propanoic acids (6) in 51-95% yield. 相似文献
6.
Thermal nitrogen extrusion of 2-methylene-6,7-diazabicyclo[3.2.2]non-6-enes and 6,7- diazabicyclo[3.2.2]nona-2,6-diene,6 proceeded easily to give closure and cleavage products the corresponding 5-methylene-1,4-cycloheptylenes and 4-cyclohepten-1,3-ylenes, respectively. 相似文献
7.
Akiko Sekihara Hidekazu Honma Tadahiro Fukuju Kiminori Maeda Hisao Murai 《Research on Chemical Intermediates》1998,24(8):859-877
Photooxidation (charge transfer) reactions of carbazole derivatives by maleic anhydride (MA) in alcoholic media are studied
by a time-resolved cw-ESR (TRESR) and Fourier transform ESR (FTESR) techniques. The CIDEP spectra observed in the systems
(methyl-, ethyl-, and phenyl-substituted carbazoles with MA) remarkably depend on the MA concentration. Under the high concentration
conditions, an emissive TM (triplet mechanism) polarization with a slight A/E (absorption/emission) pattern of the RPM (radical
pair mechanism) is observed. In the low concentration of MA, a TM-like absorptive polarization is superimposed on the A/E
pattern of the RPM. Since this reaction takes place exclusively through the triplet state, this spectral phase reveals that
the singlet state of the radical-ion pair (RIP) has an energy higher than that of the triplet state, in other words, the sign
of the apparent exchange interaction of the present RIP systems is positive. The total absorptive polarization observed in
the low concentration of MA is tentatively explained by the polarization transfer from the excited triplet state of carbazoles
in thermal equilibrium. 相似文献
8.
The systems AeAl(2-x)Mgx (Ae = Ca, Sr, Ba) display electron concentration induced Laves phase structural changes. However, the complete sequence MgCu2 --> MgNi2 --> MgZn2 with increasing x (decreasing electron count) is only observed for Ae = Ca. Compounds SrAl(2-x)Mgx (0 < x < or = 2) and BaAl(2-x)Mgx (x = 0.85 and 2.0) were synthesized and structurally characterized by X-ray diffraction experiments. For the Sr system the structural sequence CeCu2 --> MgNi2 --> MgZn2 occurs with increasing Mg content x. Thus, larger Sr does not allow the realization of the MgCu2 structure at low x. For Ae = Ba a binary compound BaAl2 does not exist, but more Ba-rich Ba7Al13 forms. The reinvestigation of the crystal structure of Ba7Al13 by selected area and convergent beam electron diffraction in a transmission electron microscope revealed a superstructure, which subsequently could be refined from single X-ray diffraction data. The formula unit of the superstructure is Ba21Al40 (space group P31m, Z = 1, a = 10.568(1) angstroms, c = 17.205(6) angstroms). In Ba21Al40 a size match problem between Ba and Al present in Ba7Al13 is resolved. The structure of Ba7Al13 (Ba21Al40) can be considered as a Ba excess variant of the hexagonal MgNi2 Laves phase type structure. An incommensurately modulated variant of the MgNi2 structure is obtained for phases BaAl(2-x)Mgx with x = 0.8-1. At even higher Mg concentrations a structural change to the proper MgZn2 type structure takes place. 相似文献
9.
Toshiko Kido Katsumi Hashizume Kenji Soda Kozi Asada ‡ 《Photochemistry and photobiology》1978,28(4-5):729-732
Abstract— 2-Nitropropane dioxygenase (EC 1. 13. 11) of the yeast Hansenula mrakii catalyzes the oxygenative denitrification of 2-nitropropane as follows:
The enzyme is significantly inhibited by superoxide dismutase and various scavengers for superoxide such as cytochrome c , epinephrine, thiols and polyhydric phenols. The scavengers added to the reaction mixture were oxidized or reduced. The addition of superoxide dismutase and the omission of 2-nitropropane or oxygen prevented the oxidation and the reduction of the scavengers. The enzyme catalyzes the formation of nitrite from 2-nitropropane by KO2 added anaerobically.
One mole of NADH is bound per mole of the enzyme and predominantly the pro-R hydrogen of bound NADH is transferred to superoxide formed enzymatically or provided externally. The enzyme shows incomplete stereospecificity for hydrogen transfer from NADH. 相似文献
The enzyme is significantly inhibited by superoxide dismutase and various scavengers for superoxide such as cytochrome c , epinephrine, thiols and polyhydric phenols. The scavengers added to the reaction mixture were oxidized or reduced. The addition of superoxide dismutase and the omission of 2-nitropropane or oxygen prevented the oxidation and the reduction of the scavengers. The enzyme catalyzes the formation of nitrite from 2-nitropropane by KO
One mole of NADH is bound per mole of the enzyme and predominantly the pro-R hydrogen of bound NADH is transferred to superoxide formed enzymatically or provided externally. The enzyme shows incomplete stereospecificity for hydrogen transfer from NADH. 相似文献
10.
Mamoru Sato Yukiteru Katsube Masaaki Katai Jun' ichi Katakawa Tadahiro Tetsumi 《Journal of chemical crystallography》1996,26(2):153-156
The crystal and molecular structure of a grayanotoxin III derivative, 6-0-acetylgrayanotoxin III is presented. The crystal is orthorhombic, space group P212121, witha=15.582(3),b=21.304(3),c=6.339(3)Å,V=2104(1) Å3
Z=4. The structure was solved by direct methods and refined by full matrix least-squares methods to a finalR=0.047 for 1763 independent reflections withF
0>3 (F
0) The molecule is based on a tetracyclic structure consisting of two five-membered, one six-membered, and one seven-membered ring with various conformations. 相似文献