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1.
Etsuro Yoshimura Mariko Akashi Tomonari Umemura Kin-ichi Tsunoda 《Analytical sciences》2004,20(2):373-374
27Al NMR spectra of an equimolar (10 mM) Al(III)-citrate system were obtained at different temperatures. The linewidths of the signals decreased in the spectra recorded at elevated temperatures, which enabled us to unequivocally identify the resonance lines. From the spectrum recorded at 65 approximately C, a mononuclear Al(III)-citrate complex was identified at a solution pH of 3.0 in addition to trinuclear Al(III)-citrate complex, which dominated at pH 4.0. 相似文献
2.
Synthesis and hypotensive activity of benzopyran derivatives 总被引:1,自引:0,他引:1
M Shiratsuchi K Kawamura T Akashi M Fujii H Ishihama Y Uchida 《Chemical & pharmaceutical bulletin》1987,35(2):632-641
3.
Sumio Sakka 《Journal of Sol-Gel Science and Technology》1994,2(1-3):451-455
The present state of our knowledge on sol-gel coating films has been reviewed. A qualitative discussion is made on the limit of the film thickness which can be achieved in the sol-gel method and the factors affecting the film thickness. Considering that properties of the film are intimately related to the microstructure, types of microstructures accomplished by the sol-gel coating are introduced with examples. 相似文献
4.
Toshiyuki Uryu Toshiyuki Seki Tokiji Kawamura Akashi Funamoto Kei Matsuzaki 《Journal of polymer science. Part A, Polymer chemistry》1976,14(12):3035-3044
The stereoregularity of polystyrene prepared by anionic polymerization was determined by means of 13C-NMR spectroscopy. The stereoregularity changed with such polymerization conditions as catalyst, solvent, and temperature. Sodium naphthalene as catalyst gave a syndiotactic-rich polystyrene of 66–68% syndiotactic dyads independently of solvent and temperature, while potassium and cesium naphthalenes as catalyst produced polystyrenes with different stereoregularities ranging from syndiotactic-rich to isotactic-rich configurations, depending on solvent and temperature. The mechanism of anionic polymerization which caused the difference in stereoregularity was discussed from the viewpoint of growing ionic species. 相似文献
5.
Sumio Aisawa 《Journal of solid state chemistry》2003,174(2):342-348
The intercalation of non-ionized guest pentoses (ribose and 2-deoxyribose) into the Mg-Al and Zn-Al layered double hydroxides (LDHs) was carried out at 298 K by the calcination-rehydration reaction using the Mg-Al and Zn-Al oxide precursors calcined at 773 K. The resulting solid products reconstructed the LDH structure with incorporating pentoses, and the maximum amount of ribose intercalated by the Mg-Al oxide precursor was approximately 20 times that by the Zn-Al oxide precursor. The ribose/Mg-Al LDH was observed to have the expanded LDH structure with a broad (003) spacing of 0.85 nm. As the thickness of the LDH hydroxide basal layer is 0.48 nm, the interlayer distance of the ribose/Mg-Al LDH is 0.37 nm. This value corresponds to molecular size of ribose in thickness (0.36 nm), supporting that ribose is horizontally oriented in the interlayer space of LDH. The maximum amount of ribose intercalated by the Mg-Al oxide precursor was approximately 5 times that of 2-deoxyribose. Ribose is substituted only by the hydroxyl group at C-2 position for 2-deoxyribose. Therefore, the number of hydroxyl group of sugar is essentially important for the intercalation of sugar molecule into the LDH, suggesting that the intercalation behavior of sugar for the LDH was greatly influenced by hydrogen bond between hydroxyl group of the intercalated pentose and the LDH hydroxide basal layers. 相似文献
6.
Double-walled carbon nanotubes (DWNTs) have been synthesized by catalytic chemical vapor deposition (CCVD) over supported metal catalysts decomposed from Fe(CH3COO)2 and Co(CH3COO)2 on mesoporous silica. Bundles of tubes with relatively high percentage of DWNTs, in areas where tubular layered structures could be clearly resolved, have been observed by transmission electron microscopy (TEM). In other areas, crystal-like alignment of very uniform DWNTs was observed for the first time, suggesting that mesoporous silica might play a templating role in guiding the initial nanotube growth. In addition, compatible with nano-electronics research, bridging of catalytic islands by DWNTs has also been demonstrated. 相似文献
7.
Summary In the aqueous solutions of poly(N-vinylacetamide) in the presence of Na2SO4 or (NH4)2SO4, the intrinsic viscosities were small and the Huggins constants were large compared with those in water. Similar but much
less effects were observed for NaF. Opposite effects were found, however, for NaSCN. The poor solvent quality of aqueous sulfate
solutions was significantly improved by the addition of guanidine hydrochloride to 3 M or higher. Urea was much less effective
in improving the solvent quality. The different M28.8neffects observed between urea and GdnHCl may be explained by their different
binding affinities to amide group. Solubilization of PNVA flocculates induced by the presence of 0.8 M Na2SO4 took place by adding urea to 1 M, although only small changes were detected in the viscosity behavior accompanying the addition
of 1 M urea.
Received: 12 June 1997 Accepted: 4 August 1997 相似文献
8.
Kubo Y Tokita S Kojima Y Osano YT Matsuzaki T 《The Journal of organic chemistry》1996,61(11):3758-3765
A new family of indoaniline-derived calix[4]arenes has been synthesized for the purpose of developing a new chromogenic receptor. A condensing reaction of calix[4]arene (1) with 4-(diethylamino)-2-methylaniline hydrochloride (2) in the presence of an oxidizing agent under alkaline conditions affords mono- (3), 1,2-bis- (4), 1,3-bis- (5), and tetrakisindoaniline-derived (6) calix[4]arenes after careful column chromatography. Compound 3 is crystallized from a CHCl(3)-MeOH solution, and the crystal structure was determined by X-ray analysis. The crystal is monoclinic, space group P2(1)/n, Z = 4, a = 19.507(6) ?, b = 18.591(6) ?, c = 8.524(2) ?, beta = 94.69(2) degrees. The final R value for 2406 reflections of F(o) > 3sigma(F(o)) is 0.085. A unique intramolecular hydrogen-bonding network involving the carbonyl oxygen of indoaniline for 3 implied that the quinone carbonyl group as an acceptor of the chromophore can easily be subjected to an electrostatic interaction in the lower rim. Indeed, 1,3-bis(indoaniline)-derived 2,4-bis((ethoxycarbonyl)methoxy)calix[4]arene 7, prepared by the reaction of 5 with ethyl bromoacetate in the presence of NaH, is capable of undergoing an efficient ion-dipole interaction between the binding cation and the two quinone carbonyl groups of the chromophores, so that a selective Ca(2+)-induced pronounced color change (wavelength change > 100 nm) occurs with an association constant on the order of 10(6) in 99% EtOH, making 7 of potential use as an optical sensor for Ca(2+) detection. The IR and NMR studies have indicated that Ca(2+) is encapsulated in the cavity made by the distally located OCH(2)CO(2) groups on the lower rim of the cone-shaped calix[4]arene segment. Interestingly, however, the shape of the cavity in which Ca(2+) has been encapsulated does not have a C(2) axis of symmetry, as inferred from the (1)H-(1)H COSY experiment. On the other hand, 1,2-bis(indoaniline)-derived analogue 8 shows no response with metal ions, which can be interpreted to mean the absence of a cavity for encapsulation on the lower rim. 相似文献
9.
10.
Ikuta A Mizuta N Kitahata S Murata T Usui T Koizumi K Tanimoto T 《Chemical & pharmaceutical bulletin》2004,52(1):51-56
Six novel branched beta-cyclodextrins (betaCDs) having beta-D-galactose residues on the non-reducing terminal of the sugar side chains, namely 6(1),6(4)-di-O-(beta-D-galactosyl)-betaCD (10), 6-O-(beta-D-galactosyl)-betaCD (11), 6(1),6(4)-di-O-(beta-lactosyl)-betaCD (14), 6-O-(beta-lactosyl)-betaCD (15), 6(1),6(4)-di-O-(4'-O-beta-D-galactosyl-beta-lactosyl)-betaCD (18), and 6-O-(4'-O-beta-D-galactosyl-beta-lactosyl)-betaCD (19), were chemically synthesized using the trichloroacetimidate method. The reaction products were separated by HPLC on an amino column into dibranched and monobranched betaCDs. Their structures were confirmed by mass spectrometry (MS) and two-dimensional (2D) NMR spectroscopic analysis. To study the length of the sugar side chains attached to the CD ring, which leads to differences in the functions of the branched CDs, interactions of these compounds with peanut (Arachis hypogaea) agglutinin (PNA) were investigated using an optical biosensor and an inhibition assay based on hemagglutination. The results showed that all branched betaCDs interacted with PNA, and the binding affinity was 18>14>10 and 19>15>11 when the derivatives were compared on the basis of side chain length. 相似文献