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排序方式: 共有1319条查询结果,搜索用时 31 毫秒
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Kikuchi Shin Koga Nobuyoshi Yamazaki Atsushi 《Journal of Thermal Analysis and Calorimetry》2019,137(4):1211-1224
Journal of Thermal Analysis and Calorimetry - Thermal behaviors of two different siliceous concretes used in a sodium-cooled fast reactor were comparatively investigated in a temperature range from... 相似文献
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Daniel Rozsar Alistair J. M. Farley Iain McLauchlan Benjamin D. A. Shennan Ken Yamazaki Darren J. Dixon 《Angewandte Chemie (International ed. in English)》2023,62(21):e202303391
Herein we describe the enantioselective intermolecular conjugate addition of nitroalkanes to unactivated α,β-unsaturated esters, catalyzed by a bifunctional iminophosphorane (BIMP) superbase. The transformation provides the most direct access to pharmaceutically relevant enantioenriched γ-nitroesters, utilizing feedstock chemicals, with unprecedented selectivity. The methodology exhibits a broad substrate scope, including β-(fluoro)alkyl, aryl and heteroaryl substituted electrophiles, and was successfully applied on a gram scale with reduced catalyst loading, and, additionally, catalyst recovery was carried out. The formal synthesis of a range of drug molecules, and an enantioselective synthesis of (S)-rolipram were achieved. Additionally, computational studies revealed key reaction intermediates and transition state structures, and provided rationale for high enantioselectivities, in good agreement with experimental results. 相似文献
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Synthesis,Properties, and π‐Dimer Formation of Oligothiophenes Partially Bearing Orthogonally Fused Fluorene Units 下载免费PDF全文
Dr. Yutaka Ie Yuji Okamoto Saori Tone Prof. Yoshio Aso 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(46):16688-16695
A series of oligothiophenes that incorporate cyclopenta[c]thiophene‐based units bearing spiro‐substituted dialkylfluorene was synthesized. Photophysical measurements indicated that there was no interruption in the conjugation along the oligothiophene backbones, irrespective of the number or position of this unit. Electrochemical measurements showed that the thiophene 7‐mers and 11‐mer exhibit reversible multi‐oxidation waves. The formation of cationic species was clearly observed from UV/Vis/NIR measurements. Furthermore, the UV/Vis/NIR spectra at 223 K under one‐electron oxidation conditions revealed that the unsubstituted thiophene or bithiophene units remained in the absence of intermolecular π–π interactions, whereas the formation of π‐dimeric species was observed for the thiophene 7‐mer containing an unsubstituted terthiophene ( U3 ) unit. Theoretical calculations indicated that the combination of the U3 unit and the all‐trans conformation decreased the intermolecular steric repulsion between the fused cyclopentene ring and its facing thiophene, which may contribute to the formation of the dimeric structure. 相似文献
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The effect of a non-uniform parallel high magnetic field on flow control characteristics is investigated experimentally for a magnetic fluid single-phase flow and an air—magnetic fluid two-phase flow in a vertical channel. It is found that as the magnetic field strength is increased, the friction factor of the single-phase flow increases significantly. For the two-phase flow, the friction pressure loss and the head pressure loss, which is smaller than the friction loss, are negligibly small compared with the magnetic pressure loss. In the case where air is injected 27.9d upstream from the maximum magnetic field, the air flow is blocked by the magnetic force in the entrance of the magnetic field, which leads to increases in both local void fraction and pressure drop there. In the case where air is injected 1.43d downstream from the maximum magnetic field, the air flow is accelerated, resulting in a decrease in void fraction and an increase in pressure rise. In the latter case and under the present range of experimental conditions, the magnetic pumping head reaches 0.02 MPa at the highest, and the maximum circulation flow rate reaches twice as high as non-magnetically driven flow rate. 相似文献
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N. Kuroda S. Ulmer D. J. Murtagh S. Van Gorp Y. Nagata M. Diermaier S. Federmann M. Leali C. Malbrunot V. Mascagna O. Massiczek K. Michishio T. Mizutani A. Mohri H. Nagahama M. Ohtsuka B. Radics S. Sakurai C. Sauerzopf K. Suzuki M. Tajima H. A. Torii L. Venturelli B. Wünschek J. Zmeskal N. Zurlo H. Higaki Y. Kanai E. Lodi Rizzini Y. Nagashima Y. Matsuda E. Widmann Y. Yamazaki 《Hyperfine Interactions》2015,235(1-3):13-20
In order to test CPT symmetry between antihydrogen and its counterpart hydrogen, the ASACUSA collaboration plans to perform high precision microwave spectroscopy of ground-state hyperfine splitting of antihydrogen atom in-flight. We have developed an apparatus (“cusp trap”) which consists of a superconducting anti-Helmholtz coil and multiple ring electrodes. For the preparation of slow antiprotons and positrons, Penning-Malmberg type traps were utilized. The spectrometer line was positioned downstream of the cusp trap. At the end of the beamline, an antihydrogen beam detector was located, which comprises an inorganic Bismuth Germanium Oxide (BGO) single-crystal scintillator housed in a vacuum duct and surrounding plastic scintillators. A significant fraction of antihydrogen atoms flowing out the cusp trap were detected. 相似文献
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