全文获取类型
收费全文 | 1026篇 |
免费 | 30篇 |
国内免费 | 5篇 |
专业分类
化学 | 807篇 |
晶体学 | 4篇 |
力学 | 11篇 |
数学 | 51篇 |
物理学 | 188篇 |
出版年
2021年 | 12篇 |
2020年 | 19篇 |
2019年 | 23篇 |
2018年 | 9篇 |
2017年 | 7篇 |
2016年 | 12篇 |
2015年 | 27篇 |
2014年 | 25篇 |
2013年 | 43篇 |
2012年 | 40篇 |
2011年 | 59篇 |
2010年 | 27篇 |
2009年 | 29篇 |
2008年 | 49篇 |
2007年 | 50篇 |
2006年 | 54篇 |
2005年 | 50篇 |
2004年 | 44篇 |
2003年 | 29篇 |
2002年 | 33篇 |
2001年 | 21篇 |
2000年 | 26篇 |
1998年 | 14篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 12篇 |
1994年 | 12篇 |
1993年 | 14篇 |
1992年 | 21篇 |
1991年 | 17篇 |
1990年 | 11篇 |
1989年 | 19篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 13篇 |
1985年 | 15篇 |
1984年 | 15篇 |
1983年 | 12篇 |
1982年 | 16篇 |
1981年 | 17篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 11篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1974年 | 10篇 |
1973年 | 8篇 |
1967年 | 8篇 |
1966年 | 6篇 |
排序方式: 共有1061条查询结果,搜索用时 265 毫秒
1.
A horizontal translation of a function is the focus of this study. We examine the explanations provided by secondary school students and secondary school teachers to a translation of a function, focusing on the example of the parabola y=(x−3)2 and its relationship to y=x2. The participants’ explanations focused on attending to patterns, locating the zero of the function, and the point-wise calculation of function values. The results confirm that the horizontal shift of the parabola is, at least initially, inconsistent with expectations and counterintuitive to most participants. We articulate possible sources of this perceived inconsistency and describe a pedagogical approach aimed at resolving it. 相似文献
2.
3.
Terahertz time-domain spectroscopy (THz-TDS) is used to study the intra- and intermolecular vibrational modes of aromatic carboxylic acids, for example, o-phthalic acid, benzoic acid, and salicylic acid, which form either intra- or intermolecular hydrogen bond(s) in different ways. Incorporating the target molecules in nano-sized spaces in mesoporous silicate (SBA-16) is found to be effective for the separate detection of intramolecular hydrogen bonding modes and intermolecular modes. The results are supported by an analysis of the differences in the peak shifts, which depend on temperature, caused by the different nature of the THz absorption. Raman spectra revealed that incorporating the molecules in the nano-sized pores of SBA-16 slightly changes the molecular structures. In the future, THz-TDS using nanoporous materials will be used to analyze the intra- and intermolecular vibrational modes of molecules with larger hydrogen bonding networks such as proteins or DNA. 相似文献
4.
Aldopyranose peracetates react with thionyl chloride and BiCl3, generated in situ from a substoichiometric amount of the procatalyst BiOCl, producing the corresponding peracylated aldopyranosyl chlorides in very good to excellent yields (82–97%) with exclusive α-anomeric selectivity. 相似文献
5.
Kentaro Suzuki Taro Toyota Katsuhiko Sato Masakazu Iwasaka Shoogo Ueno Tadashi Sugawara 《Chemical physics letters》2007,440(4-6):286-290
Collagen-containing tubular giant vesicles (Col–tGVs) under a high static magnetic field were found to constitute characteristic curved structures (e.g. circular, 8-figure, and hairpin-loop), which were sustained by polymerization of collagen units inside the tGV. We ascribed the formation of these structures to the elasticity of the tGV and to the competing diamagnetic anisotropies between collagen and the tGV. These curved structures can be well expressed by the equation of elastica. 相似文献
6.
Kumita T Sagawa H Auchincloss P Blanis D Bodek A Budd H Eno S Fry CA Harada H Ho YH Kim YK Mori T Olsen SL Shaw NM Sill A Thorndike EH Ueno K Zheng HW Abe K Fujii Y Higashi Y Kim SK Kurihara Y Maki A Nozaki T Omori T Sakai Y Sugimoto Y Takaiwa Y Terada S Walker R Imlay R Kirk P Lim J McNeil RR Metcalf W Myung SS Cheng CP Gu P Li J Li YK Ye MH Zhu YC Abashian A Gotow K Hu KP Low EH Mattson ME Piilonen L Sterner KL Lusin S Rosenfeld C Wang AT Wilson S Frautschi M Kagan H Kass R Trahern CG 《Physical review D: Particles and fields》1990,42(5):1339-1349
7.
Yuichiro Tada Masakatsu Ueno Noriaki Tsuchihashi Kiyoshi Shimizu 《Journal of solution chemistry》1992,21(9):971-985
The limiting molar conductances ° of deuterium chloride DCl in D2O were determined as a function of pressure and temperature in order to examine the proton-jump mechanism in detail. The excess deuteron conductances °E(D
+), as estimated by the equation [°E(D
+) = °(DCl/D
2
O) – °(KCl/D
2
O)], increases with an increase in the pressure and temperature as well as the excess proton conductance [°E(H
+) = °(HCl/H
2
O) – °(KCl/H
2
O)]. The isotope effect on the excess conductances, however, depends on the pressure and temperature contrary to the model proposed by Conway et al.: °E(H
+)/°E(D
+) decreases with increasing pressure and temperature. The magnitude of the decrease with pressure becomes more prominent at lower temperature. These results are discussed in terms of the pre-rotation of adjacent water molecules, the bending of hydrogen bonds with pressure, and the difference in strength of hydrogen bonds between D2O and H2O. 相似文献
8.
Kim YK Auchincloss P Blanis D Bodek A Budd H Eno S Fry CA Harada H Ho YH Kumita T Mori T Olsen SL Shaw NM Sill A Thorndike EH Ueno K Zheng HW Imlay R Kirk P Lim J McNeil RR Metcalf W Myung SS Cheng CP Gu P Li J Li YK Mao ZP Xu YT Zhu YC Abashian A Gotow K Hu KP Low EH Mattson ME Piilonen L Sterner KL Lusin S Rosenfeld C Wang AT Wilson S Frautschi M Kagan H Kass R Trahern CG Breedon RE Kim GN Ko W Lander RL Maeshima K Malchow RL Smith JR Stuart D Williams MC Abe K Fujii Y Higashi Y Kim SK 《Physical review letters》1989,63(17):1772-1775
9.
Eno S Auchincloss P Blanis D Bodek A Budd H Fry CA Harada H Ho YH Kim YK Kumita T Mori T Olsen SL Shaw NM Sill A Thorndike EH Ueno K Zheng HW Imlay R Kirk P Lim J McNeil RR Metcalf W Myung SS Cheng CP Gu P Li J Li YK Mao ZP Xu YT Zhu YC Abashian A Gotow K Hu KP Low EH Mattson ME Piilonen L Sterner KL Lusin S Rosenfeld C Wang AT Wilson S Frautschi M Kagan H Kass R Trahern CG Breedon RE Kim GN Ko W Lander RL Maeshima K Malchow RL Smith JR Stuart D Williams MC Abe K Fujii Y Higashi Y Kim SK 《Physical review letters》1989,63(18):1910-1913
10.
Shaw NM Blanis D Bodek A Budd H Coombes R Eno S Fry CA Harada H Ho YH Kim YK Kumita T Mori T Olsen SL Sill A Thorndike EH Ueno K Zheng HW Imlay R Kirk P Lim J McNeil RR Metcalf W Myung SS Cheng CP Gu P Li J Li YK Mao ZP Xu YT Zhu YC Abashian A Gotow K Hu K Low EH Mattson ME Naito F Piilonen L Sterner KL Lusin S Rosenfeld C Wang AT Wilson S Frautschi M Kagan H Kass R Trahern CG Breedon RE Kim GN Ko W Lander RL Maeshima K Malchow RL Smith JR Sparks K Williams MC Abe K Fujii Y Higashi Y Kim SK 《Physical review letters》1989,63(13):1342-1345