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1.
Photoelectrochemical (PEC) water splitting is a promising method for the conversion of solar energy into chemical energy stored in the form of hydrogen. Nanostructured hematite (α-Fe2O3) is one of the most attractive materials for a highly efficient charge carrier generation and collection due to its large specific surface area and the short minority carrier diffusion length. In the present work, the PEC water splitting performance of nanostructured α-Fe2O3 is investigated which was prepared by anodization followed by annealing in a low oxygen ambient (0.03 % O2 in Ar). It was found that low oxygen annealing can activate a significant PEC response of α-Fe2O3 even at a low temperature of 400 °C and provide an excellent PEC performance compared with classic air annealing. The photocurrent of the α-Fe2O3 annealed in the low oxygen at 1.5 V vs. RHE results as 0.5 mA cm−2, being 20 times higher than that of annealing in air. The obtained results show that the α-Fe2O3 annealed in low oxygen contains beneficial defects and promotes the transport of holes; it can be attributed to the improvement of conductivity due to the introduction of suitable oxygen vacancies in the α-Fe2O3. Additionally, we demonstrate the photocurrent of α-Fe2O3 annealed in low oxygen ambient can be further enhanced by Zn-Co LDH, which is a co-catalyst of oxygen evolution reaction. This indicates low oxygen annealing generates a promising method to obtain an excellent PEC water splitting performance from α-Fe2O3 photoanodes.  相似文献   
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Arene ruthenium(II) complexes bearing the cyclic amines RuCl26-p-cymene)(pyrrolidine)] ( 1 ), [RuCl26-p-cymene)(piperidine)] ( 2 ), and [RuCl26-p-cymene)(peridroazepine)] ( 3 ) were successfully synthesized. Complexes 1 – 3 were fully characterized by means of Fourier transform infrared, UV–visible, and NMR spectroscopy, elemental analysis, cyclic voltammetry, computational methods, and one of the complexes was further studied by single crystal X-ray crystallography. These compounds were evaluated as catalytic precursors for ring-opening metathesis polymerization (ROMP) of norbornene (NBE) and atom-transfer radical polymerization (ATRP) of methyl methacrylate (MMA). NBE polymerization via ROMP was evaluated using complexes 1 – 3 as precatalysts in the presence of ethyl diazoacetate (EDA) under different [NBE]/[EDA]/[Ru] ratios, temperatures (25 and 50°C), and reaction times (5–60 min). The highest yields of polyNBE were obtained with [NBE]/[EDA]/[Ru] = 5000/28/1 for 60 min at 50°C. MMA polymerization via ATRP was conducted using 1 – 3 as catalysts in the presence of ethyl-α-bromoisobutyrate (EBiB) as initiator. The catalytic tests were evaluated as a function of the reaction time using the initial molar ratio of [MMA]/[EBiB]/[Ru] = 1000/2/1 at 95°C. The increase in molecular weight as function of time indicates that complexes 1–3 were able to mediate the MMA polymerization with an acceptable rate and some level of control. Differences in the rate of polymerization were observed in the order 3 > 2 > 1 for the ROMP and ATRP.  相似文献   
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Diaportheone A (1), a chromone natural product was previously isolated from the endophytic fungi Diaporthe sp. P 133. Its structure was established by spectroscopic methods, however, its absolute configuration remained undefined. This study dealt on the total synthesis of diaportheone A (1) utilizing the cyclization and in situ thermal syn-elimination of a β-ketosulfoxide. The C-1R absolute configuration of the natural product was established by X-ray crystallography of the synthetic diaportheone A (1) (>99%?ee) and comparison with the optical rotation.  相似文献   
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Confocal Raman spectra of a lithium–sulfur battery electrolyte are recorded operando in a depth‐of‐discharge resolved manner for an electrochemical cell with a realistic electrolyte/sulfur loading ratio. The evolution of various possible polysulfides is unambiguously identified by combining Raman spectroscopy data with DFT simulations.  相似文献   
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We introduce non-associative Ore extensions, S = R[X; σ, δ], for any nonassociative unital ring R and any additive maps σ, δ: RR satisfying σ(1) = 1 and δ(1) = 0. In the special case when δ is either left or right R δ -linear, where R δ = ker(δ), and R is δ-simple, i.e. {0} and R are the only δ-invariant ideals of R, we determine the ideal structure of the nonassociative differential polynomial ring D = R[X; id R , δ]. Namely, in that case, we show that all non-zero ideals of D are generated by monic polynomials in the center Z(D) of D. We also show that Z( D ) = R δ [p] for a monic pR δ [X], unique up to addition of elements from Z(R) δ . Thereby, we generalize classical results by Amitsur on differential polynomial rings defined by derivations on associative and simple rings. Furthermore, we use the ideal structure of D to show that D is simple if and only if R is δ-simple and Z(D) equals the field R δ Z(R). This provides us with a non-associative generalization of a result by Öinert, Richter and Silvestrov. This result is in turn used to show a non-associative version of a classical result by Jordan concerning simplicity of D in the cases when the characteristic of the field R δ Z(R) is either zero or a prime. We use our findings to show simplicity results for both non-associative versions of Weyl algebras and non-associative differential polynomial rings defined by monoid/group actions on compact Hausdorff spaces.  相似文献   
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