全文获取类型
收费全文 | 4617篇 |
免费 | 141篇 |
国内免费 | 12篇 |
专业分类
化学 | 2597篇 |
晶体学 | 30篇 |
力学 | 142篇 |
数学 | 501篇 |
物理学 | 1500篇 |
出版年
2022年 | 39篇 |
2021年 | 72篇 |
2020年 | 78篇 |
2019年 | 82篇 |
2018年 | 90篇 |
2017年 | 62篇 |
2016年 | 116篇 |
2015年 | 89篇 |
2014年 | 113篇 |
2013年 | 289篇 |
2012年 | 260篇 |
2011年 | 315篇 |
2010年 | 186篇 |
2009年 | 167篇 |
2008年 | 243篇 |
2007年 | 231篇 |
2006年 | 244篇 |
2005年 | 210篇 |
2004年 | 157篇 |
2003年 | 141篇 |
2002年 | 123篇 |
2001年 | 79篇 |
2000年 | 81篇 |
1999年 | 64篇 |
1998年 | 45篇 |
1997年 | 44篇 |
1996年 | 57篇 |
1995年 | 53篇 |
1994年 | 49篇 |
1993年 | 56篇 |
1992年 | 48篇 |
1991年 | 36篇 |
1990年 | 51篇 |
1989年 | 41篇 |
1988年 | 39篇 |
1987年 | 39篇 |
1986年 | 30篇 |
1985年 | 47篇 |
1984年 | 40篇 |
1983年 | 41篇 |
1982年 | 38篇 |
1981年 | 33篇 |
1980年 | 39篇 |
1979年 | 32篇 |
1978年 | 39篇 |
1977年 | 33篇 |
1976年 | 37篇 |
1975年 | 31篇 |
1974年 | 34篇 |
1973年 | 36篇 |
排序方式: 共有4770条查询结果,搜索用时 421 毫秒
1.
Dr. Jordan Donat Mr. Patrick Dubourdeaux Dr. Martin Clémancey Dr. Julia Rendon Clara Gervasoni Mr. Morgan Barbier Jessica Barilone Dr. Jacques Pécaut Prof. Dr. Serge Gambarelli Prof. Dr. Pascale Maldivi Prof. Dr. Jean-Marc Latour 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202201875
Nitrene transfer reactions have emerged as one of the most powerful and versatile ways to insert an amine function to various kinds of hydrocarbon substrates. However, the mechanisms of nitrene generation have not been studied in depth albeit their formation is taken for granted in most cases without definitive evidence of their occurrence. In the present work, we compare the generation of tosylimido iron species and NTs transfer from FeII and FeIII precursors where the metal is embedded in a tetracarbene macrocycle. Catalytic nitrene transfer to reference substrates (thioanisole, styrene, ethylbenzene and cyclohexane) revealed that the same active species was at play, irrespective of the ferrous versus ferric nature of the precursor. Through combination of spectroscopic (UV-visible, Mössbauer), ESI-MS and DFT studies, an FeIV tosylimido species was identified as the catalytically active species and was characterized spectroscopically and computationally. Whereas its formation from the FeII precursor was expected by a two-electron oxidative addition, its formation from an FeIII precursor was unprecedented. Thanks to a combination of spectroscopic (UV-visible, EPR, Hyscore and Mössbauer), ESI-MS and DFT studies, we found that, when starting from the FeIII precursor, an FeIII tosyliodinane adduct was formed and decomposed into an FeV tosylimido species which generated the catalytically active FeIV tosylimide through a comproportionation process with the FeIII precursor. 相似文献
2.
3.
Anindya Ghose Choudhury Asesh Roy Chowdhury 《International Journal of Theoretical Physics》2002,41(2):321-330
A new integrable long-range model is derived from a new asymmetric R-matrix recently discussed by Bibikov in relation to a XXZ spin chain in an external magnetic field. The algebraic Bethe Ansatz is used to derive the eigenvalues and equations for the eigen momenta both for the usual and long-range model. 相似文献
4.
The electro-optic and complex dielectric behaviour of an antiferroelectric liquid crystal 4-(1-methylheptyloxycarbonyl)phenyl 4'-(n-butanoyloxyprop-1-oxy)biphenyl-4-carboxylate, having chiral SmCA* and hexatic smectic phases, have been investigated. Complex dielectric permittivities were measured as a function of frequency, d.c. bias field and temperature. Spontaneous polarization was measured by the current reversal technique; tilt angle was measured under a polarizing microscope using a low frequency electric field. The electro-optic properties and dielectric behaviour of the material are compared with results obtained by DSC and polarizing optical microscopy. Dielectric relaxation processes in SmCA* and hexatic smectic phases were determined. The dielectric strength at the SmCA* to hexatic smectic phase transition is discussed in terms of coupling between the long range bond orientational order and smectic C director. It seems from the results of spontaneous polarization and dielectric relaxation spectroscopy that the material might possess an additional phase between the SmCA* and hexatic smectic I* phases. 相似文献
5.
Ayan Roy Chaudhuri 《Solid State Communications》2005,133(9):611-614
Bi3.99Ti2.97V0.03O12 (BTV) thin films were grown by pulsed laser deposition at substrate temperatures ranging between 650 and 750 °C. The structural phase, and orientation of the deposited films were investigated in order to understand the effect of the deposition parameters on the properties of the BTV films. As the substrate temperature was increased to 700 °C, the films started showing a tendency of assuming a c-axis preferred orientation, while at lower temperatures polycrystalline films were formed. The Au/BTV/Pt capacitor showed an interesting dependence of the remnant polarization (Pr) as well as dc leakage current values on the growth temperature. The film deposited at 675 °C showed a very large 2Pr of 42 μC cm−2, which is the largest for BTV thin films among the values reported so far. 相似文献
6.
Riaan Schmuhl Sankhanilay Roy Chowdhury Johan E. ten Elshof Albert van den Berg Dave H.A. Blank 《Journal of Sol-Gel Science and Technology》2004,31(1-3):249-252
Templated MCM-48 silica was prepared using CTAB as surfactant. The MCM-48 powders and thin films were characterized by different techniques. MCM-48 layers were deposited on macroporous α-alumina supports and silicon nitride microsieves. The water permeability of MCM-48 was compared with the permeability of conventional mesoporous γ-alumina membranes. The applicability of MCM-48 as ion-selective electric field-driven switchable interconnect for microfluidic devices was demonstrated. 相似文献
7.
S. Aravinda N. Shamala Rituparna S. Roy P Balaram 《Journal of Chemical Sciences》2003,115(5-6):373-400
An overview of the use of non-protein amino acids in the design of conformationally well-defined peptides, based on work from
the author’s laboratory, is discussed. The crystal structures of several designed oligopeptides illustrate the useα-aminoisobutyric acid (Aib) in the construction of helices, D-amino acids in the design of helix termination segments andDPro-Xxx segments for nucleating ofβ-hairpin structures.β- andγ-amino acid residues have been used to expand the range of designed polypeptide structures.
Dedicated to Professor C N R Rao on his 70th birthday 相似文献
8.
The ferromagnetic shape memory alloy with nominal composition Ni54Fe19Ga27 is investigated by Ac susceptibility and resistivity measurements. The alloy shows long-range ferromagnetic order below 290 K. The anomaly due to the martensitic transition is observed in the susceptibility and resistivity data in the temperature range around 220 K, which is associated with clear thermal hysteresis. Minor hysteresis loop technique was used to investigate the phase coexistence across the martensitic transition, and our analysis indicate that both martensite and austenite phases mutually coexist in the region of hysteresis. 相似文献
9.
10.
Arup Baksi Bidyut Kumar Roy Rasajit Kumar Bera 《Mathematical and Computer Modelling》2006,44(11-12):1069-1079
The fundamental equations of the problems of generalized thermoelasticity with one relaxation parameter including heat sources in infinite rotating magneto-thermo-viscoelastic media have been derived in the form of a vector matrix differential equation in the Laplace transform domain for a one dimensional problem. These equations have been solved by the eigenvalue approach to determine deformations, stress, and temperature. The results have been compared to those available in the existing literature. The graphs have been drawn to show the effect of rotation in the medium. 相似文献