The flameless atomic absorption spectrometric determination of aluminum with a carbon atomization system

The atomic absorption spectrometry of aluminum with a carbon tube atomizer is described, with particular reference to the heating cycle, argon flow rate and amplifier time constant. Interferences are eliminated by pre-atomization heating or with a hydrogen-argon-entrained air flame. Under optimal conditions, the sensitivity (1 % absorbance) is 5·10^?11g, and the relative standard deviation is 2.3 for 2.5 ng Al.     

Optimal allocation of amplifiers in a dispersion-managed line for a wavelength-division-multiplexed soliton transmission system

Optimal allocation of amplifiers in a dispersion-managed line is theoretically derived by means of minimizing the collision-induced frequency shift in a two-channel wavelength-division-multiplexed soliton transmission system. Almost complete cancellation of the frequency shift can be obtained for such a system with any strength of dispersion management.     

A Characterization of Some Minihypers and its Application to Linear Codes

Any {f,r- 2+s; r,q}-minihyper includes a hyperplane in PG(r, q) if fr-1 + s 1 + q – 1 for 1 s q – 1, q 3, r 4, where i = (qi + 1 – 1)/ (q – 1 ). A lower bound on f for which an {f, r – 2 + 1; r, q}-minihyper with q 3, r 4 exists is also given. As an application to coding theory, we show the nonexistence of [ n, k, n + 1 – qk – 2 ]q codes for k 5, q 3 for qk – 1 – 2q – 1 < n qk – 1 – q – 1 when k > q – q - \sqrt q + 2$$ " align="middle" border="0"> and for when , which is a generalization of [18, Them. 2.4].     

Evidence for a kaon-bound state K(-)pp produced in K(-) absorption reactions at rest

We have searched for a deeply bound kaonic state by using the FINUDA spectrometer installed at the e(+)e(-) collider DAPhiNE. Almost monochromatic K(-)'s produced through the decay of phi(1020) mesons are used to observe K(-) absorption reactions stopped on very thin nuclear targets. Taking this unique advantage, we have succeeded to detect a kaon-bound state K(-)pp through its two-body decay into a Lambda hyperon and a proton. The binding energy and the decay width are determined from the invariant-mass distribution as 115(+6)(-5)(stat)(+3)(-4)(syst) MeV and 67(+14)(-11)(stat)(+2)(-3)(syst) MeV, respectively.     

2D computations of FREI with cool flames for n-heptane/air mixture

Two-dimensional axisymmetric numerical simulation reproduced flames with repetitive extinction and ignition (FREI) in a micro flow reactor with a controlled temperature profile with a stoichiometric n-heptane/air mixture, which have been observed in the experiment. The ignition of hot flame occurred from consumption reactions of CO that was remained in the previous cycle of FREI. Between extinction and ignition locations of hot flames, several other heat release rate peaks related to cool and blue flames were observed for the first time. After the extinction of the hot flame, cool flame by the low-temperature oxidation of n-heptane appeared first and was stabilized in a low wall temperature region. In the downstream of the stable cool flame, a blue flame by the consumption reactions of cool flame products of CH₂O and H₂O₂ appeared. After that, the hot flame ignition occurred from the remaining CO in the downstream of the blue flame. Then after the next hot flame ignition, the blue flame was swept away by the propagating hot flame. Soon before the hot flame merged with the stable cool flame, the hot flame propagation was intensified by the cool flame. After the hot flame merged with the stable cool flame, the hot flame reacted with the incoming fresh mixture of n-C₇H₁₆ and O₂.     

Optimal pseudo-cyclic codes and caps in PG (3,q)

Existence and uniqueness of pseudo-cyclic [q ²+1,q ²–3, 4]-codes over GF(q) are proved. Elliptic quadrics are characterized as those (q ²+1)-caps in PG(3,q) whose corresponding [q ²+1,q ²–3, 4]-codes are pseudo-cyclic.     

Phenomenological kinetics of the thermal decomposition of sodium hydrogencarbonate

Aiming to find rigorous understanding and novel features for their potential applications, the physico-geometrical kinetics of the thermal decomposition of sodium hydrogencarbonate (SHC) was investigated by focusing on the phenomenological events taking place on a single crystalline particle during the course of the reaction. The overall kinetics evaluated by systematic measurements of the kinetic rate data by thermogravimetry under carefully controlled conditions were interpreted in association with the morphological studies on the precursory reaction, mechanism of surface reaction, structure of the surface product layer, diffusion path of evolved gases, crystal growth of the solid product, and so on. The precursory reaction was identified as the decomposition of impurity, taking place at the boundary between the surface of the SHC crystal and the adhesive small SHC particles deposited on the surface. In flowing dry N(2), the thermal decomposition of SHC proceeds by two-dimensional shrinkage of the reaction interface controlled by chemical reaction with the apparent activation energy of about 100 kJ mol(-1), after rapid completion of the surface reaction and formation of porous surface product layer. Atmospheric CO(2) and water vapor influence differently on the overall kinetics of the thermal decomposition of SHC. Added gas phase of CO(2) slightly inhibits the overall rate because of the increasing contribution of the surface reaction. Under higher water vapor pressure, the physico-geometrical mechanism of the surface reaction changes drastically, indicating the preliminary reformation of reactant surface and the formation of needle crystals of solid product on the surface. The mechanistic change and extended contribution of the surface reaction result in the deceleration of the surface reaction and acceleration of the established reaction.     

Some unusual reactions of dimers of F-propene with thiols

Reactions of $\text{F}$-2- and -4-methly-2-pentenes with thiols were found to involve an oxidation-reduction system. 1,4-Elimination of sulfenyl fluorides from thio-substituted perfluoroolefins to form 1,3-dienes and disulfides is suggested as the reaction pathway.