In Alicandro et al. (J Mech Phys Solids 92:87–104, 2016) a simple discrete scheme for the motion of screw dislocations toward low energy configurations has been proposed. There, a formal limit of such a scheme, as the lattice spacing and the time step tend to zero, has been described. The limiting dynamics agrees with the maximal dissipation criterion introduced in Cermelli and Gurtin (Arch Ration Mech Anal 148, 1999) and predicts motion along the glide directions of the crystal. In this paper, we provide rigorous proofs of the results in [3], and in particular of the passage from the discrete to the continuous dynamics. The proofs are based on \(\Gamma \)-convergence techniques. 相似文献
We have recently discussed how organic nanocrystal dissolution appears in different morphologies and the role of the solution pH in the crystal detriment process. We also highlighted the role of the local molecular chemistry in porphyrin nanocrystals having comparable structures: in water-based acid solutions, protonation of free-base porphyrin molecules is the driving force for crystal dissolution, whereas metal (ZnII) porphyrin nanocrystals remain unperturbed. However, all porphyrin types, having an electron rich π-structure, can be electrochemically oxidized. In this scenario, a key question is: does electrochemistry represent a viable strategy to drive the dissolution of both free-base and metal porphyrin nanocrystals? In this work, by exploiting electrochemical atomic force microscopy (EC-AFM), we monitor in situ and in real time the dissolution of both free-base and metal porphyrin nanocrystals, as soon as molecules reach the oxidation potential, showing different regimes according to the applied EC potential. 相似文献
Conifers have long been recognized for their therapeutic potential in different disorders. Alkaloids, terpenes and polyphenols are the most abundant naturally occurring phytochemicals in these plants. Here, we provide an overview of the phytochemistry and related commercial products obtained from conifers. The pharmacological actions of different phytochemicals present in conifers against bacterial and fungal infections, cancer, diabetes and cardiovascular diseases are also reviewed. Data obtained from experimental and clinical studies performed to date clearly underline that such compounds exert promising antioxidant effects, being able to inhibit cell damage, cancer growth, inflammation and the onset of neurodegenerative diseases. Therefore, an attempt has been made with the intent to highlight the importance of conifer-derived extracts for pharmacological purposes, with the support of relevant in vitro and in vivo experimental data. In short, this review comprehends the information published to date related to conifers’ phytochemicals and illustrates their potential role as drugs. 相似文献
This paper proposes an approximate explicit probability density function for the analysis of external and parametric oscillation of a simply supported beam driven by random pulses. The impulsive loading model adopted is Poisson white noise, which is a process having Dirac delta occurrences with random intensity distributed in time according to Poisson's law. The response probability density function can be obtained by solving the related Kolmogorov–Feller integro-differential equation. An approximate solution is derived by transforming this equation to a first-order partial differential equation. The method of characteristics is then applied to obtain an explicit solution. The theory has been validated through numerical simulations. 相似文献
The stability of a cantilever elastic beam with rectangular cross-section under the action of a follower tangential force and a bending conservative couple at the free end is analyzed. The beam is herein modeled as a non-linear Cosserat rod model. Non-linear, partial integro-differential equations of motion are derived expanded up to cubic terms in the transversal displacement and torsional angle of the beam. The linear stability of the trivial equilibrium is studied, revealing the existence of buckling, flutter and double-zero critical points. Interaction between conservative and non-conservative loads with respect to the stability problem is discussed. The critical spectral properties are derived and the corresponding critical eigenspace is evaluated. 相似文献
Finite homogeneous deformations of hyperelastic cylindrical bodies subjected to in-plane equibiaxial dead-load tractions are analyzed. Four basic equilibrium problems are formulated considering incompressible and compressible isotropic bodies under plane stress and plane deformation condition. Depending on the form of the stored energy function, these plane problems, in addition to the obvious symmetric solutions, may admit asymmetric solutions. In other words, the body may assume an equilibrium configuration characterized by two unequal in-plane principal stretches corresponding to equal external forces. In this paper, a mathematical condition, in terms of the principal invariants, governing the global development of the asymmetric deformation branches is obtained and examined in detail with regard to different choices of the stored energy function. Moreover, explicit expressions for evaluating critical loads and bifurcation points are derived. With reference to neo-Hookean, Mooney-Rivlin and Ogden-Ball materials, a broad numerical analysis is performed and the qualitatively more interesting asymmetric equilibrium branches are shown. Finally, using the energy criterion, a number of considerations are put forward about the stability of the computed solutions. 相似文献
A fundamental issue in turbomachinery design is the dynamical stress assessment of turbine blades. In order to reduce stress peaks in the turbine blades at engine orders corresponding to blade natural frequencies, friction dampers are employed. Blade response calculation requires the solution of a set of non-linear equations originated by the introduction of friction damping.
Such a set of non-linear equations is solved using the iterative numerical Newton–Raphson method. However, calculation of the Jacobian matrix of the system using classical numerical finite difference schemes makes frequency domain solver prohibitively expensive for structures with many contact points. Large computation time results from the evaluation of partial derivatives of the non-linear equations with respect to the displacements.
In this work a methodology to compute efficiently the Jacobian matrix of a dynamic system having wedge dampers is presented. It is exact and completely analytical.
The proposed methods have been successfully applied to a real intermediate pressure turbine (IPT) blade under cyclic symmetry boundary conditions with underplatform wedge dampers. Its implementation showed to be very effective, and allowed to achieve relevant time savings without loss of precision. 相似文献
The chemical composition of three rockrose Cistus species, Cistus monspeliensis, Cistus libanotis and Cistus villosus, collected in Tunisia, was studied by HPTLC, focusing on the terpenes and phenols constituents. Diterpenes of Cistus are important as the main constituents of the leaf sticky aromatic resin, known as labdanum, which are highly appreciated in perfumery. Polyphenols in the methanolic extracts of each species were identified, quantified as total and as flavonoids and tannins, and tested for antioxidant activity. Diterpenes were evident in C. libanotis and C. monspeliensis, whereas they were practically absent in C. villosus; C. libanotis had higher phenolic amount, whereas antioxidant activities were important, but different according to the following tests: DPPH radical scavenging, conversion of the Fe3+/ferricyanide complex and inhibition of β-carotene bleaching. The reported data confirm the validity of utilisation of Cistus sp. in marketed herbal products, as well as the relevant presence of diterpenes in species actually not used for labdanum production. 相似文献