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1.
Magnani A Marchettini N Ristori S Rossi C Rossi F Rustici M Spalla O Tiezzi E 《Journal of the American Chemical Society》2004,126(37):11406-11407
The present work deals with the spatially extended oscillatory Belousov Zhabotinsky reaction-diffusion system carried out in an anisotropic environment of phosphatidylcholines/water binary system, which presents layered aqueous domains separated by lipid bilayers. We report the occurrence of stable Turing patterns, spiral waves, and other exotic structures in phospholipids bilayers that are generally used as a models for cell plasma membranes. 相似文献
2.
Combined Experimental and Multivariate Model Approaches for Glycoalkaloid Quantification in Tomatoes
Gabriella Tamasi Alessio Pardini Riccardo Croce Marco Consumi Gemma Leone Claudia Bonechi Claudio Rossi Agnese Magnani 《Molecules (Basel, Switzerland)》2021,26(11)
The intake of tomato glycoalkaloids can exert beneficial effects on human health. For this reason, methods for a rapid quantification of these compounds are required. Most of the methods for α-tomatine and dehydrotomatine quantification are based on chromatographic techniques. However, these techniques require complex and time-consuming sample pre-treatments. In this work, HPLC-ESI-QqQ-MS/MS was used as reference method. Subsequently, multiple linear regression (MLR) and partial least squares regression (PLSR) were employed to create two calibration models for the prediction of the tomatine content from thermogravimetric (TGA) and attenuated total reflectance (ATR) infrared spectroscopy (IR) analyses. These two fast techniques were proven to be suitable and effective in alkaloid quantification (R2 = 0.998 and 0.840, respectively), achieving low errors (0.11 and 0.27%, respectively) with the reference technique. 相似文献
3.
Valentino Magnani 《Calculus of Variations and Partial Differential Equations》2010,39(1-2):233-271
We characterize locally Lipschitz mappings and existence of Lipschitz extensions through a first order nonlinear system of PDEs. We extend this study to graded group-valued Lipschitz mappings defined on compact Riemannian manifolds. Through a simple application, we emphasize the connection between these PDEs and the Rumin complex. We introduce a class of 2-step groups, satisfying some abstract geometric conditions and we show that Lipschitz mappings taking values in these groups and defined on subsets of the plane admit Lipschitz extensions. We present several examples of these groups, called Allcock groups, observing that their horizontal distribution may have any codimesion. Finally, we show how these Lipschitz extensions theorems lead us to quadratic isoperimetric inequalities in all Allcock groups. 相似文献
4.
O. Beneš R. Jardin R.J.M. Konings E. Colineau F. Wastin N. Magnani 《The Journal of chemical thermodynamics》2009,41(4):560-563
The enthalpy increments of UPd3 and ThPd3 have been measured using the drop calorimetry for temperature range (480 to 1290) K. The heat capacity curves have been derived using the simultaneous linear regression of our data and the low temperature heat capacity data from previous studies. Furthermore the Schottky contributions for UPd3 were determined by comparing the ThPd3 and UPd3 heat capacity functions and correlated with the theoretical values calculated from the crystal field energy levels. 相似文献
5.
Christos Apostolidis Dr. Bernd Schimmelpfennig Dr. Nicola Magnani Dr. Patric Lindqvist‐Reis Dr. Olaf Walter Dr. Richard Sykora Dr. Alfred Morgenstern Dr. Eric Colineau Dr. Roberto Caciuffo Prof. Dr. Reinhardt Klenze Dr. Richard G. Haire Dr. Jean Rebizant Dr. Frank Bruchertseifer Dr. Thomas Fanghänel Prof. Dr. 《Angewandte Chemie (International ed. in English)》2010,49(36):6229-6229
6.
Michele Menotta Sara Biagiotti Laura Streppa Luigia Rossi Mauro Magnani 《Analytica chimica acta》2015
In the present paper we describe an atomic force microscopy (AFM)-based method for the quantitative analysis of FK506 (Tacrolimus) in whole blood (WB) samples. Current reference methods used to quantify this immunosuppressive drug are based on mass spectrometry. In addition, an immunoenzymatic assay (ELISA) has been developed and is widely used in clinic, even though it shows a small but consistent overestimation of the actual drug concentration when compared with the mass spectrometry method. The AFM biosensor presented herein utilises the endogen drug receptor, FKBP12, to quantify Tacrolimus levels. The biosensor was first assayed to detect the free drug in solution, and subsequently used for the detection of Tacrolimus in blood samples. The sensor was suitable to generate a dose–response curve in the full range of clinical drug monitoring. A comparison with the clinically tested ELISA assay is also reported. 相似文献
7.
Nicola Magnani 《International journal of quantum chemistry》2014,114(12):755-759
Magnetic exchange is an essential feature of transition‐metal nanomagnets because it combines the relatively low spin‐only moments of several ions into a “giant spin” ground state, which can make slow magnetic relaxation very favorable in an axially anisotropic environment. In contrast, most of the early research on lanthanide‐based complexes focused on single‐ion magnets, where the required large moment is generated by the unquenched orbital contribution (which is parallel to the spin in heavy rare earths). With their unfilled 5f electronic shell being on the verge between localization and itinerancy, actinides are expected to combine the best of both 3d and 4f metals in terms of exchange and anisotropy, and are therefore under consideration as potential building blocks for the next generation of single‐molecule magnets. In this Perspective, a review of the recent development in this field is given, and some discrepancies between the spectroscopic and magnetic data are discussed. © 2014 European Commission. International Journal of Quantum Chemistry published by Wiley Periodicals, Inc. 相似文献
8.
E. Colineau A. Hen J.-P. Sanchez J.-C. Griveau N. Magnani R. Eloirdi I. Halevy P. Gaczyński I. Orion A. B. Shick R. Caciuffo 《Hyperfine Interactions》2016,237(1):80
Rare-earth-based compounds R2T17 (R=Rare earth; T=Transition metal) have been extensively studied and developed for applications as permanent magnets. The actinide-based analogues, however, are much less documented and we report here about the magnetic properties of Np2Co17 and Np2Ni17, as inferred from 237Np Mössbauer spectroscopy, the best resonance in actinides, and specific heat. 相似文献
9.
Jerome S Harms Marina A Durward Diogo M Magnani Gary A Splitter 《Journal of immune based therapies and vaccines》2009,7(1):1-14
Background
There is no safe, effective human vaccine against brucellosis. Live attenuated Brucella strains are widely used to vaccinate animals. However these live Brucella vaccines can cause disease and are unsafe for humans. Killed Brucella or subunit vaccines are not effective in eliciting long term protection. In this study, we evaluate an approach using a live, non-pathogenic bacteria (E. coli) genetically engineered to mimic the brucellae pathway of infection and present antigens for an appropriate cytolitic T cell response. 相似文献10.
Schwizer D Patton JT Cutting B Smieško M Wagner B Kato A Weckerle C Binder FP Rabbani S Schwardt O Magnani JL Ernst B 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(5):1342-1351
A new class of N-acetyl-D-glucosamine (GlcNAc) mimics for E-selectin antagonists was designed and synthesized. The mimic consists of a cyclohexane ring substituted with alkyl substituents adjacent to the linking position of the fucose moiety. Incorporation into E-selectin antagonists led to the test compounds 8 and the 2'-benzoylated analogues 21, which exhibit affinities in the low micromolar range. By using saturation transfer difference (STD)-NMR it could be shown that the increase in affinity does not result from an additional hydrophobic contact of the alkyl substituent with the target protein E-selectin, but rather from a steric effect stabilizing the antagonist in its bioactive conformation. The loss of affinity found for antagonists 10 and 35 containing a methyl substituent in a remote position (and therefore unable to support to the stabilization of the core) further supports this hypothesis. Finally, when a GlcNAc mimetic containing two methyl substituents (52 and 53) was used, in which one methyl was positioned adjacent to the fucose linking position and the other was in a remote position, the affinity was regained. 相似文献