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排序方式: 共有165条查询结果,搜索用时 21 毫秒
1.
Christel Hempen Liane Glsle-Schwarz Ulrich Kunz Uwe Karst 《Analytica chimica acta》2006,560(1-2):35-40
Telmisartan is an angiotensin II receptor antagonist and a known drug against high blood pressure. In this report, the development of a new and rapid analytical technique, an enzyme-linked immunosorbent assay (ELISA) for the determination of telmisartan in human blood plasma is described. The immunoassay is based on a conversion of 4-(N-methylhydrazino)-7-nitro-2,1,3-benzooxadiazole (MNBDH) to 4-(N-methylamino)-7-nitro-2,1,3-benzooxadiazole (MNBDA), which is detected by fluorescence spectroscopy. The limit of detection was 0.1 ng/mL, the limit of quantification was 0.3 ng/mL and the working range extended from 0.3 ng/mL to 300 ng/mL. 相似文献
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A simplified form of the first-order many-body theory was used for the calculation of the coherence and correlation parameters for the excitation of the 21 P and 31 P states of helium. The excited state wave functions were calculated numerically in the fixed core Hartree-Fock(HF) approximation. The ground state wave function was used in the HF approximation. Scattering orbitals were calculated numerically in the static exchange approximation. Calculations were performed forE=29.6, 40, 50, 60 and 80 eV impact energies for the 21 P state, and forE=50 eV and 80 eV for the 31 P state. Results for the coherence and correlation parameters are compared with the experimental values obtained from electronphoton coincidence experiments, and with other theoretical results. 相似文献
4.
Rossi LM Shi L Quina FH Rosenzweig Z 《Langmuir : the ACS journal of surfaces and colloids》2005,21(10):4277-4280
We have developed a simple method to prepare bright and photostable luminescent silica nanoparticles of different sizes and narrow size distribution in high yield. The method is based on the use of St?ber synthesis in the presence of a fluorophore to form bright silica nanoparticles. Unlike micro-emulsion-based methods often used to prepare luminescent silica particles, the St?ber method is a one-pot synthesis that is carried out at room temperature under alkaline conditions in ethanol:water mixtures and avoids the use of potentially toxic organic solvents and surfactants. Our luminescent particles contained the transition metal complex tris(1,10-phenanthroline) ruthenium(II) chloride, [Ru(phen)3]Cl2. They showed higher photostability and a longer fluorescence lifetime compared to free Ru(phen)3 solutions. Leakage of dye molecules from the silica particles was negligible, which was attributed to strong electrostatic attractions between the positively charged ruthenium complex and the negatively charged silica. To demonstrate the utility of the highly luminescent silica nanoparticles in bioassays, we further modified their surface with streptavidin and demonstrated their binding to biotinylated glass slides. The study showed that digital counting of the luminescent nanoparticles could be used as an attractive alternative to detection techniques involving analogue luminescence detection in bioanalytical assays. 相似文献
5.
Liane M. Moreau Alexandre Herve Mark D. Straub Dominic R. Russo Rebecca J. Abergel Selim Alayoglu John Arnold Augustin Braun Gauthier J. P. Deblonde Yangdongling Liu Trevor D. Lohrey Daniel T. Olive Yusen Qiao Julian A. Rees David K. Shuh Simon J. Teat Corwin H. Booth Stefan G. Minasian 《Chemical science》2020,11(18):4648
We report the structural properties of ultra-small ThO2 and UO2 nanoparticles (NPs), which were synthesized without strong binding surface ligands by employing a covalent organic framework (COF-5) as an inert template. The resultant NPs were used to observe how structural properties are affected by decreasing grain size within bulk actinide oxides, which has implications for understanding the behavior of nuclear fuel materials. Through a comprehensive characterization strategy, we gain insight regarding how structure at the NP surface differs from the interior. Characterization using electron microscopy and small-angle X-ray scattering indicates that growth of the ThO2 and UO2 NPs was confined by the pores of the COF template, resulting in sub-3 nm particles. X-ray absorption fine structure spectroscopy results indicate that the NPs are best described as ThO2 and UO2 materials with unpassivated surfaces. The surface layers of these particles compensate for high surface energy by exhibiting a broader distribution of Th–O and U–O bond distances despite retaining average bond lengths that are characteristic of bulk ThO2 and UO2. The combined synthesis and physical characterization efforts provide a detailed picture of actinide oxide structure at the nanoscale, which remains highly underexplored compared to transition metal counterparts.ThO2 and UO2 nanoparticles synthesized using a COF-5 template exhibit unpassivated surfaces and provide insight into nanoscale properties of actinides. 相似文献
6.
The electrochemical reduction of antifouling agent 2-thiocyanomethylthiobenzothiazole (TCMTB) was investigated by cyclic and pulse differential voltammetry. The irreversible electrode reduction of TCMTB proceeded by ECEC reaction mechanism by two electrons transfer with one irreversible wave. Upon the basis of electrochemical evidence, the electrodic reaction mechanism was suggested to formation of mercaptobenzothiazole (MTB) in solution.Subsequently, a pulse differential method is described for the formation of TCMTB based on this electroreduction. Having been obtained a detection limit of 1.0 × 10−7 mol L−1 and recovery to 98% to concentration of 2.0 × 10−6 mol L−1. Therefore, the proposed method in this study is practical, sensitive and accurate for the analysis of TCMTB in tannery wastewater samples. 相似文献
7.
The partial hydrogenation of benzene to cyclohexene by nanoscale ruthenium catalysts in imidazolium ionic liquids 总被引:3,自引:0,他引:3
Silveira ET Umpierre AP Rossi LM Machado G Morais J Soares GV Baumvol IJ Teixeira SR Fichtner PF Dupont J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(15):3734-3740
The controlled decomposition of an Ru(0) organometallic precursor dispersed in 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMI.PF(6)), tetrafluoroborate (BMI.BF(4)) or trifluoromethane sulfonate (BMI.CF(3)SO(3)) ionic liquids with H(2) represents a simple and efficient method for the generation of Ru(0) nanoparticles. TEM analysis of these nanoparticles shows the formation of superstructures with diameters of approximately 57 nm that contain dispersed Ru(0) nanoparticles with diameters of 2.6+/-0.4 nm. These nanoparticles dispersed in the ionic liquids are efficient multiphase catalysts for the hydrogenation of alkenes and benzene under mild reaction conditions (4 atm, 75 degrees C). The ternary diagram (benzene/cyclohexene/BMI.PF(6)) indicated a maximum of 1 % cyclohexene concentration in BMI.PF(6), which is attained with 4 % benzene in the ionic phase. This solubility difference in the ionic liquid can be used for the extraction of cyclohexene during benzene hydrogenation by Ru catalysts suspended in BMI.PF(6). Selectivities of up to 39 % in cyclohexene can be attained at very low benzene conversion. Although the maximum yield of 2 % in cyclohexene is too low for technical applications, it represents a rare example of partial hydrogenation of benzene by soluble transition-metal nanoparticles. 相似文献
8.
G. D. Meneses L. M. Brescansin M. -T. Lee S. E. Michelin L. E. Machado G. Csanak 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1994,30(2):173-175
We have applied the density matrix formalism and the distorted-wave approximation to calculate the Stokes parameters for thed 3 Π u ? (v=0,1,2,3;N=1) states of H2 excited from the X1 ∑ g + (v=0,N=1) state by electron impact at the incident energies ranging from 15 to 40 eV. Our results show that these parameters are nearly independent of the vibrational quantum number of the excited states. However, the polarization of the radiation emitted by the target in the subsequent decay process increases with increasing incident energies. 相似文献
9.
Thomas Glonek Patricio Meneses 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4)
Abstract Cell membrane phospholipids can be identified and quantitated using 31P NMR spectroscopy in conjunction with an analytical reagent composed of chloroform-benzene(d6)/methanol-CsEDTA 2:l ml/ml. 3 ml of this reagent dissolves between 0.01–100 mg crude tissue lipids obtained by the Folch procedure. When the source phospholipids are strongly contaminated with cations, it is necessary to modify the extraction method, backwashing with K-EDTA, 0.6 M, pH 6, instead of KC1. Also if source tissues must be stored for long periods of time, acetone desication is recommended. Using a 500 MHz 31PNMR spectrophotometer (magnetic field ?11.75 T), the extracted phospholipids yield narrow Lorenzian signals (1.8–3.2 Hz at half-height), with these widths at half-height corresponding to their 1/πT2 values. Chemical shifts (δ) at 24 °C, following the IUPAC shift convention and relative to 85% phosphoric acid, were determined as follows:CAEP,21.09;LPG,l,O9;LPA,0.83;LPE plas,0.53;PG,0.50;LPE,0.43; PA,0.25;CL,0.18;LPI,0.10;PE plas,0.07;PE,0.03;PS,?0.O5;SPH,?0.O9; DiMePE,?b.18;LPC plas,?0.20;LPC,?0.28;PI,?0.37; PAF, ?0.70;PC plas,?0.77; PC, ?0.84. This reagent permits assays of high precision and accuracy that use little spectrometer time and that are suitable for automated procedures. 相似文献
10.
Lidiane Pinto Correia Elisana Afonso de Moura Hallisson Meneses Pires Rui Oliveira Macêdo 《Journal of Thermal Analysis and Calorimetry》2011,106(2):459-461
Water is a fundamental element of life. Its multiple uses are indispensable for a wide spectrum of human activities. This
study aims to characterize water from different salinities obtained in the Cariri region of Paraíba, Brazil. The samples were
analyzed using the DSC-coupled to the Peltier system (DSC-Cooling) and physical–chemical water tests performed employing reactive
kits, using the Spectroquant Merck? specific for each test. The calorimetric curves showed crystallization phase transitions with different characteristics in
peak format and crystallization temperatures between the samples of different salinities. The calorimetric data obtained in
the process of crystallization of water is directly correlated to the physico-chemical parameters of conductivity and total
dissolved solids, showing that the analytical technology DSC-cooling/heating is suitable for characterization of different
salinities water. 相似文献