全文获取类型
收费全文 | 142篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 94篇 |
晶体学 | 4篇 |
力学 | 1篇 |
数学 | 29篇 |
物理学 | 19篇 |
出版年
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 2篇 |
2016年 | 2篇 |
2015年 | 2篇 |
2013年 | 8篇 |
2012年 | 5篇 |
2011年 | 9篇 |
2010年 | 10篇 |
2009年 | 3篇 |
2008年 | 5篇 |
2007年 | 7篇 |
2006年 | 4篇 |
2005年 | 2篇 |
2004年 | 3篇 |
2003年 | 11篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 4篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 7篇 |
1971年 | 2篇 |
1970年 | 1篇 |
1967年 | 2篇 |
1962年 | 1篇 |
1961年 | 1篇 |
1956年 | 1篇 |
1927年 | 1篇 |
排序方式: 共有147条查询结果,搜索用时 15 毫秒
1.
2.
3.
An examination of the literature reveals that only a limited number of monosubstituted cycloheptadiene compounds have been reported. An obvious synthetic route to 5-substituted -1, 3-cycloheptadiene derivatives would be the reaction of nucleophiles with the cycloheptadienyl cation, but this pathway is generally unsuccessful due to the limited stability of the cation. On the other hand, the iron tricarbonyl complex of this cation shows remarkable stability1 and an ability to react with nucleophiles2. If the -Fe(CO)3 group could be removed easily, a facile route to this family of organic compounds would be available. This work reports our investigation of the range of nucleophiles that can be utilized and the oxidizing agents that can remove efficiently the -Fe(CO)3 group. 相似文献
4.
Betty J. Gaffney 《化学:亚洲杂志》2020,15(1):42-50
Polyunsaturated fatty acids are sources of diverse natural, and chemically designed products. The enzyme lipoxygenase selectively oxidizes fatty acid acyl chains using controlled free radical chemistry; the products are regio‐ and stereo‐chemically unique hydroperoxides. A conserved structural fold of ≈600 amino acids harbors a long and narrow substrate channel and a well‐shielded catalytic iron. Oxygen, a co‐substrate, is blocked from the active site until a hydrogen atom is abstracted from substrate bis‐allylic carbon, in a non‐heme iron redox cycle. EPR spectroscopy of ferric intermediates in lipoxygenase catalysis reveals changes in the metal coordination and leads to a proposal on the nature of the reactive intermediate. Remarkably, free radicals are so well controlled in lipoxygenase chemistry that spin label technology can be applied as well. The current level of understanding of steps in lipoxygenase catalysis, from the EPR perspective, will be reviewed. 相似文献
5.
Some 1-N (3-fluoroadamantyl) ureas have been synthesized in good to excellent yields from 1-N- (3-fluoroadamantyl) isocyanate. The 3-fluoroadamantyl isocyanate has been prepared via the reaction of 1-N-(3-fluoroadamantyl) carboxamide with lead tetraacetate in N, N-dimethylformamide. 相似文献
6.
Karla Calfumán María Jesus Aguirre Diego Villagra Claudia Yañez Carmen Arévalo Betty Matsuhiro Leonora Mendoza Mauricio Isaacs 《Journal of Solid State Electrochemistry》2010,14(6):1065-1072
In this work, the modification of a glassy carbon electrode with tetraruthenated porphyrins electrostatically assembled onto
a Nafion film, previously adsorbed on the electrode surface, is reported. This modified electrode was characterized by scanning
electron microscopy–energy-dispersive X-ray, Raman spectroscopy, UV-Vis spectroelectrochemistry, and cyclic voltammetry. The
Nafion film onto the glassy carbon electrode shows a smooth disposition; when the tetraruthenated porphyrin is incorporated
on the Nafion film, the complex is adsorbed in a homogeneous way. The modified electrode catalyzes HSO3− oxidation in water–ethanol solutions and shows an enhanced stability compared with the electrode modified with the dip coating
method. Rotating disk electrode experiments showed a kinetic limitation to the electron transfer controlled by charge propagation
in the film. I/E curves show a Tafel slope of 120 mV/decade corresponding to a first electron-transfer reaction, depending on the potential,
as the determining step. Spectroelectrochemical experiments demonstrated that Ru(II) is the active site for the electrocatalysis. 相似文献
7.
A simulation technique is used to study the properties of the “hole modulated hopping” model introduced by Hirsch. The superconducting order parameter, energy gap and pair size have been determined for a range of particle densities and temperatures in the neighbourhood of the superconducting phase transition. Results are consistent with the interpretation of the superconducting transition to be Bose-like at low hole densities and BCS-like at high hole densities, with a crossover near the Tc maximum in the Tc versus hole density curve. This behaviour is related to the existence of small non-overlapping pairs at low hole densities and large strongly interpenetrating pairs at hole densities above the Tc maximum. 相似文献
8.
This paper reports on thedevelopment of a very efficient method for partitioning the networksimplex basis subtree in which dual values must be updated duringa pivot. The partitioning procedure may be concurrently executedby multiple processes. The resulting rapid decomposition of thesubtree allows an arbitrary number of processes to be utilized inthe actual dual update. This approach alleviates a primary limitationof the most efficient parallel network simplex implementationpublished to date. The new code performs at least as well as theprevious implementation on medium-scale problems and reduces averagesolution time by over 34% on large-scale problems. 相似文献
9.
Mexiletine— and lysine hydrochloride—o-phthalaldehyde and mexiletine hydrochloride—, cysteine—, cysteamine—, homocysteine— and lysine hydrochloride—fluorescamine derivatives were subjected to Triton and β-cyclodextrin enhancement treatments. Of several classical fluorescence-enhancing reagents tested (Triton, β-cyclodextrin, sodium dodecyl sulphate, Brij), Triton provided the best results, followed by β-cyclodextrin. Increases in fluorescence emission by a factor of up to about 10 (mexiletine—fluorescamine—Triton X-100) were observed, with a generally negligible influence of the enhancing reagents on the excitation and emission maxima. Fluorescence enhancement by the addition of a suitable reagent solution to the final analyte solution may, in specific instances, enhance the detectability of native or chemically induced fluorophores. 相似文献
10.
Betty W. Harris Jannie L. Singleton Michael D. Coburn 《Journal of heterocyclic chemistry》1973,10(2):167-171
The condensation of various aminopyrimidines with picryl chloride and picryl fluoride has been investigated as part of our continuing effort in the field of picrylamino-substituted heterocycles. Most of the aminopyrimidines that can tautomerize reacted with picryl fluoride to form picryl derivatives of their imino forms, but they gave picrylamino derivatives when they condensed with picryl chloride. 相似文献