On circular–linear one-factorizations of the complete graph

In Korchmáros et al. (2018)one-factorizations of the complete graph $K_n$ are constructed for $n=q+1$ with any odd prime power $q$ such that either $q\equiv 1(mod4)$ or $q=2^h?1$. The arithmetic restriction $n=q+1$ is due to the fact that the vertices of $K_n$ in the construction are the points of a conic $\Omega$ in the finite plane of order $q$. Here we work on the Euclidean plane and describe an analogous construction where the role of $\Omega$ is taken by a regular $n$-gon. This allows us to remove the above constraints and construct one-factorizations of $K_n$ for every even $n\ge 6$.     

On spectral synthesis in varieties containing the solutions of inhomogeneous linear functional equations

As a continuation of our previous work [2] the aim of the recent paper is to investigate the solutions of special inhomogeneous linear functional equations by using spectral synthesis in translation invariant closed linear subspaces of additive/multiadditive functions containing the restrictions of the solutions to finitely generated fields. The idea is based on the fundamental work of [5]. Using spectral analysis in some related varieties we can prove the existence of special solutions (automorphisms) of the functional equation but spectral synthesis allows us to describe the entire space of solutions on a large class of finitely generated fields. It is spanned by the so-called exponential monomials which can be given in terms of automorphisms of \({\mathbb C}\) and differential operators. We apply the general theory to some inhomogeneous problems motivated by quadrature rules of approximate integration [8], see also [7, 9].     

Thermal Effects and Structural Changes of Photosynthetic Reaction Centers Characterized by Wide Frequency Band Hydrophone: Effects of Carotenoids and Terbutryn

Photothermal characteristics and light‐induced structural (volume) changes of carotenoid‐containing and noncontaining photosynthetic reaction centers (RCs) were investigated by wide frequency band hydrophone. We found that the presence of carotenoid either does not play considerable role in the light‐induced conformational movements, or these rearrangements are too slow for inducing a photoacoustic (PA) signal. The kinetic component with a few tens of microseconds, exhibited by the carotenoid‐less RCs, appears to be similar to that of triplet state lifetimes, identified by other methods. The binding of terbutryn to the acceptor side is shown to affect the dynamics of the RC. Our results do not confirm large displacements or volume changes induced by the charge movements and by the charge relaxation processes in the RCs in few hundreds of microseconds time scale that accompanies the electron transfer between the primary and secondary electron acceptor quinones.     

Artificial intelligence in electrostatic risk management

In the last two decades protection against electrostatic hazards became a very important topic. The increase in the range of possible faults fast automated systems and complex fault analysis is required.The tools of artificial intelligence and expert systems have been applied successfully on this field and this paper aims to take a step further. While giving some insight to the currently used tools, another AI method, the 'support vector machines' are introduced in this paper. Besides a brief review on SVMs they are introduced to the SCOUT system, a novel approach to electrostatic hazard management.     

Comparison of different electrode arrangements for gas decomposition efficiency using experimental method

The environmental pollution is a central issue in the present industrial societies. Within that the air pollution and the removal of hazardous components of flue and exhaust gases are very much important.In this paper the target is to decrease of the NO_x emission by means of a technology similar to that is used in the electrostatic precipitators. In most of the papers dealing with this technique cylindrical precipitator is used as a discharge chemical reactor, and fast rising electric discharges are applied for energizing the reactor. In the industry the over helming majority of the electrostatic precipitators are plate type one.In the cylindrical precipitator the discharge electrode is parallel with the gas flow, and the corona discharge filament is perpendicular to both of them. In the case of plate type industrial electrostatic precipitator the discharge electrodes are positioned vertically, and the flow of the flue gas is horizontal. Consequently, the discharge filaments are mainly perpendicular to both the flow and the discharge electrode.In cylindrical precipitator the decomposition of NO_x is done in one filament very soon, but there is no chance to modify the byproducts with a new pulse, because the energization is the same for the whole length of the discharge electrode.In the present paper a cylindrical precipitator, a plate type precipitator with horizontal electrode, and a plate type precipitator with vertical electrode were tested. The total length of the discharge electrodes of all of the precipitators was the same.The results of the NO_x decomposition were experimentally determined, and the differences between the precipitators were investigated. The cylindrical and the plate type precipitators with vertical electrodes had shown basically similar decomposition rate, while the plate type one with horizontal discharge electrode had proven inferior to the others.     

Improvement of spatial homogeneity in GdBCO/IBAD-MgO coated conductor

Recent process optimization allows improving homogeneity and a significant increase of J_c in GdBa₂Cu₃O_7-δ deposited on ion-beam assisted deposited MgO template (GdBCO/IBAD-MgO). We applied low-temperature laser scanning microscopy and laser scanning thermo-electric microscopy (LSTEM) to investigate local dissipation and defects simultaneously in recent GdBCO/IBAD-MgO coated conductor. By using high-resolution LSTEM, we could detect current blocking obstacles which are responsible for the large scale local dissipation. Data on the present GdBCO/IBAD-MgO coated conductors point out a significant reduction of current blocking obstacles compared to the previous process. We have shown the improvement of spatial homogeneity in the recent GdBCO/IBAD-MgO coated conductors. Current blocking obstacles are much less densely distributed as compared to previous YBCO/IBAD-GZO coated conductor. Obstacles larger than several micrometer significantly increase local dissipation whereas smaller defects do not influence it noticeably. 2D map of the phase delay component of the thermoelectric voltage lock-in signal is effective to analyze current blocking obstacles having action upon local dissipation.     

The speciation of vanadium in human serum

A knowledge of the speciation of vanadium in human serum is essential for an understanding of the biotransformation of antidiabetic vanadium complexes in human blood and of how vanadium is transported to the target cells. Such information may be acquired by two completely different approaches: separation techniques and modeling calculations. This review focuses on the latter.The two major metal ion binders in human serum are apotransferrin (apoTf) and human serum albumin (HSA), the interactions of which with V^IVO and V^V are discussed in detail. A partially new model for HSA–V^IVO interactions is introduced, in which the two binding sites (one for two and one for one metal ion) compete not only with each other, but also with hydrolysis of the metal ion.Focus is also placed on the possibility and importance of ternary complex formation between V^IVO, serum proteins and drug candidate ligands (maltol (mal), 1,2-dimethyl-3-hydroxy-4(1H)-pyridinone (dhp), acetylacetone (acac) and picolinic acid, (pic)): the structures and formation constants of different ternary complexes reported by the different research groups are critically reviewed.The serum speciations for V^IVO and V^V are calculated through use of the most recent stability constants; at biologically relevant concentrations (～1 μM, but definitely <10 μM) the apoTf complexes predominate for both metal ions. This has the consequences that the primary role of the drug candidate ligands of the original complexes is a carrier function until the vanadium is taken up into the serum, and the vanadium ion itself is the active metabolite responsible for the antidiabetic effect.     

Photocatalytic Water Oxidation by a Pyrochlore Oxide upon Irradiation with Visible Light: Rhodium Substitution Into Yttrium Titanate

A stable visible‐light‐driven photocatalyst (λ≥450 nm) for water oxidation is reported. Rhodium substitution into the pyrochlore Y₂Ti₂O₇ is demonstrated by monitoring Vegard′s law evolution of the unit‐cell parameters with changing rhodium content, to a maximum content of 3 % dopant. Substitution renders the solid solutions visible‐light active. The overall rate of oxygen evolution is comparable to WO₃ but with superior light‐harvesting and surface‐area‐normalized turnover rates, making Y₂Ti_1.94Rh_0.06O₇ an excellent candidate for use in a Z‐scheme water‐splitting system.     

Comparative evolved gas analytical and structural study on trans-diammine-bis(nitrito)-palladium(II) and platinum(II) by TG/DTA–MS, TG–FTIR, and single crystal X-ray diffraction

Detailed study on identification and thermal decomposition of solid title compounds 1 and 2 crystallized from the used aqueous ammonia solutions of Pd(NH₃)₂(NO₂)₂ and Pt(NH₃)₂(NO₂)₂, has been carried out. Beyond the composition of complexes 1 and 2, their trans square planar configuration have already been recognized by reference IR spectra and powder XRD patterns, nevertheless their exact molecular and crystal structure as of trans-Pd(NH₃)₂(NO₂)₂ (1, Pd-NN) and trans-Pt(NH₃)₂(NO₂)₂ (2, Pt-NN) has been determined by single crystal X-ray diffraction (R = 0.0515 and 0.0341), respectively. Despite their compositional and configuration analogy, they crystallize in different crystal systems and space groups. The crystals of 1 (Pd-NN) are triclinic (space group No. 2, P-1, a = 5.003(1) Å, b = 5.419(1) Å, c = 6.317(1) Å, α = 91.34(2)°, β = 111.890(10)°, γ = 100.380(10)°), while those of 2 (Pt-NN) are monoclinic (space group No. 5, C2, a = 7.4235(16) Å, b = 9.130(2) Å, c = 4.4847(10) Å, β = 99.405(7)°).The pyrolytic processes of 1 and 2 (which might be sensitive to shock and heat) have been followed by simultaneous thermogravimetric and differential thermal analysis (TG/DTA), while the evolved gaseous species have been traced in situ by online coupled TG/DTA–EGA–MS and TG–EGA–FTIR instruments in He and air. Pd and Pt powders, forming as final solid products in single step, are captured and checked by TG and XRD. Whilst the unified evolved gas analyses report evolution of N₂, H₂O, NH₃, N₂O, NO, and NO₂ gases as gaseous product components in the exothermic decomposition of both trans-Pd(NH₃)₂(NO₂)₂ (1) and trans-Pt(NH₃)₂(NO₂)₂ (2) starting from ca. 230 and 220 °C, in sealed crucibles with a pinhole on the top, respectively.