Wasserzusatz

Ohne Zusammenfassung     

铑{001}表面的表面态及其磁性 *

自旋极化光电子谱的实验表明位于铑{001}表面Brillouin区中K₁₁=0.65ΓX处的表面态(其束缚能为-0.30 eV)和位于M点的表面共振态(其束缚能为-0.6eV)在室温下具有铁磁性.上述表面态的铁磁性随着温度的下降而增加.当表面被暴露了0.5Langmur(L)氧后,铁磁性消失.自旋分辨的光电子谱表明,上述峰的自旋交换分裂很小.由上述峰的极化率估得表面层中的原子磁矩在0.1～0.3个μ_B间.     

Determination of the c(2 × 2) structure of sulfur on Fe{001} by low-energy electron diffraction

In the early stages of reaction with sulfur, a clean Fe{001} surface develops a c(2 × 2) superstructure. A low-energy electron diffraction analysis of this structure leads to a model in which the S atoms lie in the four-fold symmetrical sites on the Fe{001} surface, the S-Fe interplanar spacing being $\text{1.09 ± 0.05}\text{A}\text{?}$ and corresponding to an effective radius of 1.06 Å for the chemisorbed S atoms. In contrast to Fe{001} 1 × 1-O, the first interlayer spacing of the substrate here is not significantly expanded.     

Atomic structure of Cu{0 0 1}c(2 × 2)-Cl

A LEED intensity analysis of Cu{0 0 1}c(2 × 2)-Cl has given an excellent fit of theory to experiment with Cl in the fourfold symmetrical hollows in a simple overlayer structure with a Cu-Cl bond length of 2.38 Å. This structure is consistent with an analysis of angle-resolved photoemission measurements made in the same experiments and published elsewhere. These results help confirm the LEED analysis of the analogous system Ag{0 0 1}c(2 × 2)-Cl which gave the same structure, but had been rejected by an independent photoemission analysis.