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1.
To improve our understanding of the combustion characteristics of propyne, new experimental data for ignition delay times (IDTs), pyrolysis speciation profiles and flame speed measurements are presented in this study. IDTs for propyne ignition were obtained at equivalence ratios of 0.5, 1.0, and 2.0 in ‘air’ at pressures of 10 and 30 bar, over a wide range of temperatures (690–1460 K) using a rapid compression machine and a high-pressure shock tube. Moreover, experiments were performed in a single-pulse shock tube to study propyne pyrolysis at 2 bar pressure and in the temperature range 1000–1600 K. In addition, laminar flame speeds of propyne were studied at an unburned gas temperature of 373 K and at 1 and 2 bar for a range of equivalence ratios. A detailed chemical kinetic model is provided to describe the pyrolytic and combustion characteristics of propyne across this wide-ranging set of experimental data. This new mechanism shows significant improvements in the predictions for the IDTs, fuel pyrolysis and flame speeds for propyne compared to AramcoMech3.0. The improvement in fuel reactivity predictions in the new mechanism is due to the inclusion of the propyne + H?2 reaction system along with ?H radical addition to the triple bonds of propyne and subsequent reactions.  相似文献   
2.
Yang  J.  Tao  J. L.  Franck  C. 《Experimental Mechanics》2021,61(7):1181-1191
Experimental Mechanics - Digital Image Correlation (DIC) is a popular experimental technique for measuring full-field deformations in materials. Accurate motion and displacement field...  相似文献   
3.
Doklady Physics - The dependence of Raman spectra of the molecules containing polyene chains on the conjugation length, structure of side and end groups, and isomer type is analyzed theoretically.  相似文献   
4.
Gohl  J. A.  Thiele-Sardina  T. C.  Rencheck  M. L.  Erk  K. A.  Davis  C. S. 《Experimental Mechanics》2021,61(7):1209-1213
Background

Peel tests are frequently used to perform measurements of adhesive strength for pressure sensitive adhesive (PSA) tapes. Current lab methodologies for 90° peel tests translate the model substrate orthogonally to the peel direction in order to maintain the peel angle, precluding testing from immovable substrates.

Objective

It was our objective to develop a peel fixture capable of testing temporary pavement marking (TPM) tapes and other PSA tapes from immovable substrates such as roadways surfaces.

Methods

We present a modular peel fixture for conducting peel experiments directly on immovable substrates. The fixture was validated through a series of peel tests on consumer tapes to reproduce the linear width dependence and viscoelastic rate dependence found in traditional peeling setups. To test the capabilities of the fixture, a series of peel tests were conducted with various tapes on controlled surfaces, and a commercial tape on various immovable substrates.

Results

We demonstrate the ability of our fixture to reproduce results reported for traditional peel tests from literature. In addition, we were able to conduct peel tests directly on immovable substrates such as the benchtop.

Conclusions

This fixture shows potential for both traditional peeling tests, and for use in in-situ peel experiments from substrates relevant to the end application of the PSA tape.

  相似文献   
5.
Marconi  J.  Tiso  P.  Quadrelli  D. E.  Braghin  F. 《Nonlinear dynamics》2021,104(4):3039-3063
Nonlinear Dynamics - We present an enhanced version of the parametric nonlinear reduced-order model for shape imperfections in structural dynamics we studied in a previous work. In this model, the...  相似文献   
6.
Mechanics of Composite Materials - Aiming at the phenomenon of delamination and serious tool wear when processing carbon-carbon composite materials by traditional mechanical tools, an abrasive...  相似文献   
7.
Set-Valued and Variational Analysis - R. Tyrell Rockafellar and his collaborators introduced, in a series of works, new regression modeling methods based on the notion of superquantile (or...  相似文献   
8.
Acta Mathematica Hungarica - A subgroup H of a group G is said to be an $$IC\mathrm{\Phi}$$ -subgroup of G if $$H \cap [H,G] \le \mathrm{\Phi}(H)$$ . We prove the p-nilpotency of a finite group G...  相似文献   
9.
In this article, the effect of ionization on the energy spectrum of electrons within the interaction of a laser pulse with hydrogen atoms is investigated using particle-in-cell simulation codes. The results show that the behaviour of electrons' energy distribution function in the field-ionized plasma, which occurred due to the field ionization, compared with that in the pre-plasma strongly depends on the pulse shape. For short rise-time pulses (here 30 fs), due to the rapid enhancement of laser electric field, ionization occurs quickly, and as a result, there is not much difference in the electron energy in both the media. However, for pulses with rise time of 40 fs, in the pre-plasma state, the electron population reaches higher energies compared with the field-ionized plasma state. The main reason for this difference is the nonlinear wave breaking that happens earlier due to density inhomogeneity in the field-ionized plasma. On the other hand, at longer rise-time pulses (here 60 and 70 fs), electrons achieve higher energies in the field-ionized plasma than those in the case of pre-plasma. In this case, because of density fluctuations in the field-ionized plasma, the Raman backscattered radiations are seeded by a strong initial noise at the earlier times and the Mendonca condition for chaos threshold is met sooner. Therefore, the electrons gain more energy through the stochastic mechanism that is in agreement with chaotic nature of the motion.  相似文献   
10.
Kobayashi  M.  Zhang  Y.  Ishikawa  H.  Sun  J.  Oddershede  J.  Juul Jensen  D.  Miura  H. 《Experimental Mechanics》2021,61(5):817-828
Experimental Mechanics - The internal strain distribution developing during plastic deformation is important for understanding the mechanical properties of polycrystalline materials. Such...  相似文献   
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