Reynolds stress, mean velocity, and dynamic static pressure measurement by a four-hole pressure probe

An improved version of the four-hole directional pressure probe, or Cobra probe, is described, in which the frequency response has been extended to 1.5 kHz. The probe measures all three orthogonal mean and turbulent velocity components at a point in the flow field. The probe also resolves the local mean and turbulent components of static pressure, allowing moments between the fluctuating velocity components and pressure to be determined. The techniques developed to allow the improved frequency response and the use of the probe in turbulent, developed pipe flow (a calibration flow) are described. Also given are the turbulent pressure-velocity correlations, which show a high degree of anticorrelation for one velocity component.     

Velocity and Reynolds stresses in a precessing jet flow

 A novel fluid mixing device, described elsewhere, has been shown to have a dramatic effect on the combustion characteristics of a fuel jet. The main features of the flow are the deflection of the jet between 30° and 60° from the nozzle axis and its precession about that axis. Many of the factors governing the nozzle instabilities which drive the mixing in the external field are imprecisely defined. It is the aim of the present paper to examine, in isolation from the nozzle instabilities, the influence of precession on a deflected jet as it proceeds downstream from the nozzle exit. The fluid dynamically driven phenomena within the nozzle which cause the precession are in the present investigation replaced by a mechanical rotation of a nozzle from which is emerging a jet which is orientated at an angle from the nozzle axis. By this means the effect of precession on the deflected jet can be investigated independently of the phenomena which cause the precession. The experimental data reported here has been obtained from measurements made using a miniature, rapid response four-hole “Cobra” pitot probe in the field of the precessing jet. Phase-averaged three dimensional velocity components identify the large scale motions and overall flow patterns. The measured Reynolds stresses complement the velocity data and are found to be compatible with the higher entrainment rates of the jet found in earlier investigations. Received: 8 November 1995 / Accepted: 27 September 1996     

Blast wave measurements close to explosive charges

The paper reports the results of experimental measurements of the reflection pressures close to spherical charges of TNT. These measurements were made using a pressure bar technique. Charge weights of up to 3.6 kg were used, with the reflecting plane in the range 25 to 300 mm from the charge surface.A possible wave interaction model is discussed, to account for the observed pressure profiles, and its qualitative correctness checked by means of numerical simulation.This article was processed using Springer-Verlag T_EX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society.     

Bimetallic Gold(I) Complexes with Ethynyl‐Helicene and Bis‐Phosphole Ligands: Understanding the Role of Aurophilic Interactions in their Chiroptical Properties

Monometallic gold(I)‐alkynyl‐helicene complexes ( 1 a , b ) and bimetallic gold(I)‐alkynyl‐helicene architectures featuring the presence ( 2 a , b ) or absence ( 3 a , b ) of aurophilic intramolecular interactions were prepared by using different types of phosphole ligands (mono‐phosphole L1 or bis‐phospholes L2 , 3 ). The influence of the Au^I d¹⁰ metal center(s) on the electronic, photophysical, and chiroptical properties of these unprecedented phosphole‐gold(I)‐alkynyl‐helicene complexes was examined. Experimental and theoretical results highlight the importance of ligand‐to‐ligand‐type charge transfers and the strong effect of the presence or absence of Au^I–Au^I interactions in 2 a , b .     

Large‐Scale Synthesis of Helicene‐Like Molecules for the Design of Enantiopure Thin Films with Strong Chiroptical Activity

Helicenes are fascinating molecules owing to their unusual properties and applications in many fields from catalysis to organic electronics. Herein, we report a straightforward pathway for the synthesis of helicene‐like molecules on a gram scale in an enantiopure form. Thin‐film materials with good propagating optical properties and very high chiroptical responses have been grown by using pulsed laser ablation without altering the structure or the enantiopurity of the molecules. Moreover, electronic and vibrational circular dichroism spectroscopies coupled with theoretical calculations enabled some dependences of the chiroptical properties with the structure to be highlighted, for example, effects of rigidification, aromatization, or the state of matter (liquid versus solid).