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排序方式: 共有138条查询结果,搜索用时 15 毫秒
1.
Herve Loïc 《Integral Equations and Operator Theory》1998,32(2):199-215
LetX be a locally compact space, andT, a quasi-compact positive operator onC
0(X), with positive spectral radius,r. Then the peripheral spectrum ofT is a finite set of poles containingr, and the residue of the resolvent ofT at each peripheral pole is of finite rank. Using the concept of closed absorbing set, we develop an iterative process that gives the order,p, ofr, some special bases of the algebraic eigenspaces ker(T-r)
p
and ker(T
*-r)
p
, and finally the dimension of the algebraic eigenspace associated to each peripheral pole. 相似文献
2.
Liane M. Moreau Alexandre Herve Mark D. Straub Dominic R. Russo Rebecca J. Abergel Selim Alayoglu John Arnold Augustin Braun Gauthier J. P. Deblonde Yangdongling Liu Trevor D. Lohrey Daniel T. Olive Yusen Qiao Julian A. Rees David K. Shuh Simon J. Teat Corwin H. Booth Stefan G. Minasian 《Chemical science》2020,11(18):4648
We report the structural properties of ultra-small ThO2 and UO2 nanoparticles (NPs), which were synthesized without strong binding surface ligands by employing a covalent organic framework (COF-5) as an inert template. The resultant NPs were used to observe how structural properties are affected by decreasing grain size within bulk actinide oxides, which has implications for understanding the behavior of nuclear fuel materials. Through a comprehensive characterization strategy, we gain insight regarding how structure at the NP surface differs from the interior. Characterization using electron microscopy and small-angle X-ray scattering indicates that growth of the ThO2 and UO2 NPs was confined by the pores of the COF template, resulting in sub-3 nm particles. X-ray absorption fine structure spectroscopy results indicate that the NPs are best described as ThO2 and UO2 materials with unpassivated surfaces. The surface layers of these particles compensate for high surface energy by exhibiting a broader distribution of Th–O and U–O bond distances despite retaining average bond lengths that are characteristic of bulk ThO2 and UO2. The combined synthesis and physical characterization efforts provide a detailed picture of actinide oxide structure at the nanoscale, which remains highly underexplored compared to transition metal counterparts.ThO2 and UO2 nanoparticles synthesized using a COF-5 template exhibit unpassivated surfaces and provide insight into nanoscale properties of actinides. 相似文献
3.
The three main desialylated variants (F1, S and A) of human alpha 1-acid glycoprotein (AAG), a serum acute-phase reactant, were analysed by high-performance anion-exchange chromatography in order to determine their optimum separation conditions. The analysis consisted of three steps, as follows: (1) A desialylated commercial AAG was separated into one "fast"- and one "slow"-migrating fraction by preparative isoelectrofocusing. The "fast" and "slow" fractions were shown to contain the F1 variant and a mixture of the S and A variants, respectively. (2) The pH titration curves of these two fractions were then measured by strong anion-exchange chromatography with several buffer systems of increasing pH. From the data obtained, it was not possible to select the optimum conditions to separate the "fast" variant F1 from the "slow" variants A and S. However, the S and A variants were shown to ionize very differently. (3) The specific fractionation of the S and A variants was therefore carried out by anion-exchange chromatography under operating conditions based on the data obtained from the study of their pH titration curves. This was performed both with the "slow"-migrating fraction obtained by preparative isoelectrofocusing of commercial AAG and with an AAG (containing only variants S and A) purified from an individual serum on immobilized Cibacron Blue F3G-A. Identification of the fractionated proteins was achieved by analytical isoelectrofocusing. 相似文献
4.
Herve Galons Jean Fiet Claude Combet-farnoux Marcel Miocque Georges Bram 《Molecular Crystals and Liquid Crystals》2013,570(1):521-528
Alkoxyphthalimides are prepared by alkylation of N-hydroxyphthalimide under solid-liquid phase transfer catalysis without solvent. When conversion of alkoxyphthalimides into alkoxylamines is nearly complete, neat hydrazine hydrate is added at room temperature. 相似文献
5.
Fibrous thermal insulations are widely used to conserve energy in ambient to high temperature applications including buildings, solar collectors, heat exchangers, furnaces and thermal protection systems of reusable launch vehicles. It has long been recognised that zirconia has the lowest thermal conductivity of commercial refractories. The thermal conductivity of a zirconia fibrous medium is strongly dependent of its bulk density; high bulk densities of zirconia fibers provide the most effective insulation at high temperatures. Lee's theory for radiative transfer through fibrous media is used in this paper. The two-flux model is applied to determine the backward and forward parameters of a medium of zirconia fibers oriented in parallel planes. Theoretical calculations of the backscatter factor and absorption ratio of this medium are carried out in the visible spectrum for different size parameters of the fibers and for three different temperatures. Our results show that the backscatter factor of zirconia fibrous insulations is maximum, and therefore the heat transfer by the fibrous medium is the lowest, for a size parameter of 0.45 for all the temperatures studied. We also observed that the backscatter factor decreases with increasing temperature. 相似文献
6.
We show that wetting properties crucially control the patterns in two-phase flows of immiscible fluids in microchannels. Ordered patterns, continuously entrained by the flow, are obtained when one phase completely wets the walls, while disordered patterns, intermittently adhering to the channel walls, are unavoidably produced when wetting is partial. A lower limit for the channel sizes capable of generating well structured objects (drops, pears, pearl necklaces, ...) is presented. 相似文献
7.
Oxidation behaviour of SiC coatings 总被引:1,自引:0,他引:1
K. Mergia D. Lafatzis N. Moutis T. Speliotis G. Apostolopoulos F. Cousin 《Applied Physics A: Materials Science & Processing》2008,92(2):387-395
Amorphous silicon carbide (SiC) films were deposited on silicon substrates by radio-frequency magnetron sputtering. The films
were oxidized in air in the temperature range 400–900 °C and for times from 1 to 16 h. Neutron reflectivity measurements provided
information on the thickness, density and roughness of the SiC and on the formed SiO2 layers. Fourier transform infrared spectroscopy was used to determine the bond structure of the formed SiO2 and changes in the bonding of SiC after exposure at the oxidation temperature. The surface morphology of the oxidized films
was characterized by atomic force microscopy measurements. The oxidation kinetics is initially fast and as the SiO2 layer is formed it slows down. The SiC consumption varies linearly with time at all oxidation temperatures. Exposure of the
SiC at the oxidation temperature affects its density and to some degree its bond structure, while the formed SiO2 has density and bond structure as that formed by oxidation of Si under the same conditions.
PACS 66.30.Ny; 68.47.Gh; 68.55.J- 相似文献
8.
Temperature and heat-flux measurement at the microscale for convective heat-transfer studies requires highly precise, minimally intrusive sensors. For this purpose, a new generic temperature and heat-flux sensor was designed, calibrated and tested. The sensor allows measurement of temperature and heat flux distributions along the direction of flow. It is composed of forty gold thermoresistances, 85 nm thick, deposited on both sides of a borosilicate substrate. Their sensitivities are about 37.8 μV K(-1), close to those of a K-type wire thermocouple. Using a thermoelectrical model, temperature biases due to the Joule effect were calculated using the current crossing each thermoresistance and the heat-transfer coefficient. Finally, heat-transfer measurements were performed with deionized water flowing in a straight PDMS microchannel for various Reynolds numbers. The Nusselt number was obtained for microchannels of 50 to 10 μm span. The results were found to be in good agreement with classical Nu-Re macroscopic correlations. 相似文献
9.
Poumale HM Awoussong KP Randrianasolo R Simo CC Ngadjui BT Shiono Y 《Natural product research》2012,26(8):749-755
In addition to lupeol (1a), three long-chain alkanoic acid esters of lupeol, in which two were new, were isolated from the hexane and ethyl acetate twigs extract of Dorstenia harmsiana Engl. (Moraceae). The structures of the new compounds were elucidated on the basis of 1D and 2D NMR experiments. Some isolated compounds were evaluated for their antimicrobial activities. The lupeol and its three long-chain alkanoic acid esters showed antifungal and antibacterial activities. 相似文献
10.
Piotr Hanczyc Katarzyna Matczyszyn Krzysztof Pawlik Joanna Olesiak Herve Leh Malcolm Buckle 《Liquid crystals》2013,40(4):461-468
The liquid crystalline (LC) properties of two supercoiled plasmid DNA samples, pBSK (2958 bp) and pGEM (3000 bp), have been studied using polarised light microscopy (PLM), circular dichroism (CD) and UV–Vis spectroscopy. The influence of methods of isolation on plasmid LC behaviour is described, and using PLM we have demonstrated the spontaneous formation of cholesteric fingerprint-like textures. Preliminary studies of LC phase transitions in pGEM show the irreversibility of LC phase formation, as a consequence of changes in the tertiary structure of supercoiled plasmids. Using UV–Vis spectroscopy a hyperchromic effect was observed with increasing temperature. The CD spectra clearly showed structural changes, and probably mismatching of DNA bases, during cooling. Finally, we have observed an irreversible phase transition in plasmid DNA which is very different from that previously reported in linear DNA. 相似文献