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排序方式: 共有287条查询结果,搜索用时 31 毫秒
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Journal of Theoretical Probability - We study a multi-group version of the mean-field Ising model, also called Curie–Weiss model. It is known that, in the high-temperature regime of this... 相似文献
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In some practical applications (e.g. cavity with a lip), even at low Mach numbers, acoustic feedback mechanisms excite flow structures. The compressible flow simulation cannot distinguish between a pure fluid dynamic part and acoustic phenomena. With this in mind, we propose a workflow based on Helmholtz-Hodge decomposition, to extract pure source terms of the compressible flow simulation, to model the sound radiation. (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Solution or Gas Phase? Oxidation and Radical Formation in Electrospray Ionization Mass Spectrometry (ESI MS) 下载免费PDF全文
The relationship between one‐electron (e?) oxidation processes and the formation of radical cations of endogenous and exogenous compounds in vivo is of considerable interest. This paper reports on the experiments that allow FTICR mass spectrometric (MS) detection of ion signals that are consistent with the formation of radical cations of caffeine (CA) and theophylline (TP) during electrospray ionization (ESI) in ESI FTICR MS and in on‐line electrochemistry (EC)/ESI FTICR MS in positive mode. Significantly, the signals of the radicals of CA?+ and TP?+can be enhanced by simple modifications of the operating conditions in ESI MS, facilitating investigations of radical formation and related reactions. 相似文献
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Milos Toth 《Applied Physics A: Materials Science & Processing》2014,117(4):1623-1629
Electron beam-induced etching (EBIE) has traditionally been used for top-down, direct-write, chemical dry etching, and iterative editing of materials. The present article reviews recent advances in EBIE modeling and emerging applications, with an emphasis on use cases in which the approaches that have conventionally been used to realize EBIE are instead used for material analysis, surface functionalization, or bottom-up growth of nanostructured materials. Such applications are used to highlight the shortcomings of existing quantitative EBIE models and to identify physicochemical phenomena that must be accounted for in order to enable full exploitation and predictive modeling of EBIE and related electron beam fabrication techniques. 相似文献
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Bogdan Tita Ionut Ledeti Geza Bandur Dumitru Tita 《Journal of Thermal Analysis and Calorimetry》2014,118(2):1293-1304
Thermal analysis is a routine method for analysis of drugs and substances of pharmaceutical interest. Thermogravimetry/derivative thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC) are thermoanalytical methods which offer important information about the physical and chemical properties of drugs (purity, stability, phase transition, polymorphism, compatibility, kinetic analysis, etc.). This work exemplifies a general method of studying the drug-excipient interactions with the aim of predicting rapidly and inexpensively the long thermal stability of their mixtures. The TG/DTG and DSC were used as screening techniques for assessing the compatibility between indomethacin (IND) and its physical associations as binary mixtures with some common excipients. Based on their frequent use in preformulations eleven different excipients: corn starch, microcrystalline cellulose (PH 101; PH 102), colloidal silicon dioxide, lactose (monohydrate and anhydre), polyvinilpyrrolidone K30, magnesium stearate, talc, stearic acid, and manitol were blended with IND. The samples were prepared by mixing the analyte and excipients in a proportion of 1:1 (w:w). In order to investigate the possible interactions between the components, the thermal curves of IND and each selected excipient were compared with those of their 1:1 (w/w) physical mixtures. FT-IR spectroscopy and X-ray powder diffraction were used as complementary techniques to adequately implement and assist in interpretation of thermal results. On the basis of thermal results, confirmed by FT-IR and X-ray analyses, a possible interaction was found between IND with polyvinylpyrrolidone K30, magnesium stearate, and stearic acid. 相似文献
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Consistent time and frequency domain formulations for a fully anisotropic, linear visco-elastic material model are presented. The finite element implementation leads to a complex valued stiffness matrix in the frequency domain. A homogenisation procedure based on unit-cell analyses in the frequency domain is presented to derive input parameters for the material model. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Robert A. Toth 《Journal of Molecular Spectroscopy》2011,265(2):59-68
The necessity to revisit water spectroscopy at 6 μm was prompted by recent work indicating that some prior measurements of H216O line strengths (ranging through seven orders of magnitude) had larger than expected systematic errors for the stronger transitions. To investigate this, linestrengths of stronger transitions were re-measured (with 14 new H2O spectra recorded with a Bruker 125 HR Fourier transform spectrometer at the Jet Propulsion Laboratory) and combined with re-analyzed prior results (obtained at higher optical densities from 32 spectra recorded with the FTS at Kitt Peak). Systematic differences for some of the older data sets were identified and corrected. In this paper, an internally-consistent sampling of 1243 selected line strengths are reported for (0 1 0)-(0 0 0) and (0 2 0)-(0 1 0) transitions between 783 and 2378 cm−1. To confirm experimental precisions, observed and calculated line strengths are compared. 相似文献