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1.
A Lewis basic platinum(0)–CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.  相似文献   
2.
Carbon-coated LiFePO4 cathode materials were prepared by a solid-state method incorporating different sizes of polystyrene (PS) spheres as carbon sources. In scanning electron microscope images, small PS spheres appear more effective at preventing aggregation of LiFePO4 particles. From transmission electron microscopy images, it was found that the LiFePO4 particles were completely uniformly coated with 5-nm carbon layer when the carbon source was 0.22 μm PS spheres. When the size of PS sphere was increased to 2.75 μm, a network of carbon was formed and wrapped around the LiFePO4 to create a conductive web. Raman spectroscopy and four-point probe conductivity measurement showed that using larger sizes of PS spheres as carbon sources leads to greater conductivity of LiFePO4/C. The LiFePO4 precursor sintered with 0.22 μm PS spheres delivered an initial discharge capacity of 145 mAh g?1 at a 0.2 C rate, but it only sustained 289 cycles at 80% capacity. When the diameter of PS spheres was increased to 2.75 μm, the discharge capacity of LiFePO4/C decreased, but the cycle life reached 755 cycles, the highest number in this work probably due to the network formation of carbon wrapping around LiFePO4 particles.  相似文献   
3.
This paper considers a modeling and analysis approach for the investigation of the linear and nonlinear steady-state dynamics of a base excited 3D tensegrity module carrying a top mass. The tensegrity module contains three compressive members, which may buckle and six cables (tendons). First, a dynamic model of the system is derived using Lagrange’s equation with constraints. The buckling modeling of the compressive members is based on the assumed-mode method with a single mode discretization. The tendons are modeled as piecewise linear springs, which can only take tensile forces. This research focusses on the dynamic stability of the tensegrity structure by defining the geometrical and material properties in such a way that the system is just below the static stability boundary. Static and linear dynamic analysis is performed. In the nonlinear steady-state analysis, frequency-amplitude plots, power spectral density plots, bifurcation point continuation diagrams, and Poincaré maps are presented. A tensegrity structure is designed and manufactured and an experimental set-up is realized in order to validate the model by comparing experimentally and numerically obtained responses. In the validation stage, the numerical results are based on an amplifier-shaker-tensegrity structure model. It can be concluded that the numerical results match partly quantitatively and partly qualitatively with the experimentally obtained responses.  相似文献   
4.
5.
We study the abelian sandpile growth model, where n particles are added at the origin on a stable background configuration in ? d . Any site with at least 2d particles then topples by sending one particle to each neighbor. We find that with constant background height h≤2d?2, the diameter of the set of sites that topple has order n 1/d . This was previously known only for h<d. Our proof uses a strong form of the least action principle for sandpiles, and a novel method of background modification. We can extend this diameter bound to certain backgrounds in which an arbitrarily high fraction of sites have height 2d?1. On the other hand, we show that if the background height 2d?2 is augmented by 1 at an arbitrarily small fraction of sites chosen independently at random, then adding finitely many particles creates an explosion (a sandpile that never stabilizes).  相似文献   
6.
The zeta-potentials of silica, copper, platinum and gold particles have been measured as a function of pH. The isoelectric points were found to be at pH 3.0, 5.8, 3.0 and 3.5, respectively. In the pH range 3.0 to 5.8 copper and silica particles are oppositely charged and accordingly the coating of silica with copper particles could be demonstrated. In the case of gold and platinum the sign of the charge is such that direct adhesion to silica particles cannot be expected and this was also demonstrated in the case of platinum.  相似文献   
7.
In this paper, nonlinear resonances in a coupled shaker-beam-top mass system are investigated both numerically and experimentally. The imperfect, vertical beam carries the top mass and is axially excited by the shaker at its base. The weight of the top mass is below the beam’s static buckling load. A semi-analytical model is derived for the coupled system. In this model, Taylor-series approximations are used for the inextensibility constraint and the curvature of the beam. The steady-state behavior of the model is studied using numerical tools. In the model with a single beam mode, parametric and direct resonances are found, which affect the dynamic stability of the structure. The model with two beam modes not only shows an additional second harmonic resonance, but also reveals some extra small resonances in the low-frequency range, some of which can be identified as combination resonances. The experimental steady-state response is obtained by performing a (stepped) frequency sweep-up and sweep-down with respect to the harmonic input voltage of the amplifier-shaker combination. A good correspondence between the numerical and experimental steady-state responses is obtained.  相似文献   
8.

Background  

Microglia provide continuous immune surveillance of the CNS and upon activation rapidly change phenotype to express receptors that respond to chemoattractants during CNS damage or infection. These activated microglia undergo directed migration towards affected tissue. Importantly, the molecular species of chemoattractant encountered determines if microglia respond with pro- or anti-inflammatory behaviour, yet the signaling molecules that trigger migration remain poorly understood. The endogenous cannabinoid system regulates microglial migration via CB2 receptors and an as yet unidentified GPCR termed the 'abnormal cannabidiol' (Abn-CBD) receptor. Abn-CBD is a synthetic isomer of the phytocannabinoid cannabidiol (CBD) and is inactive at CB1 or CB2 receptors, but functions as a selective agonist at this Gi/o-coupled GPCR. N-arachidonoyl glycine (NAGly) is an endogenous metabolite of the endocannabinoid anandamide and acts as an efficacious agonist at GPR18. Here, we investigate the relationship between NAGly, Abn-CBD, the unidentified 'Abn-CBD' receptor, GPR18, and BV-2 microglial migration.  相似文献   
9.
Single-phase undoped LiNi0.8Co0.2O2 and Sr2+-doped LiNi0.8Co0.2O2 were synthesized by a low temperature tartaric acid assisted sol-gel method. Small quantities of Sr2+ were used as dopants in order to improve the electrochemical characteristics, especially the capacity and cycling performance of LiNi0.8Co0.2O2. The electrochemical performance of the undoped material was promising with a first discharge capacity of 174 mAh/g and 165 mAh/g after 10 cycles with a 100% cycling efficiency in the tenth cycle. Addition of Sr2+ for Li in minimum quantities with the Sr2+/Li+ dopant mole ratio ranging from 10−4 to 10−8 resulted in improved electrochemical properties for dopant mole ratio of 10−6. The first discharge capacity was 182 mAh/g and the tenth was 174 mAh/g at the 10th discharge. The synthesis of Sr2+-doped LiNi0.8Co0.2O2 and its improved electrochemical properties have been discussed for the first time. The improved electrochemical properties of Sr2+-doped LiNi0.8Co0.2O2 system are explained based on defect models.  相似文献   
10.
The vision for school mathematics described by the National Council of Teachers of Mathematics (NCTM) suggests a need for new approaches to the teaching and learning of mathematics, as well as new curriculum materials to support such change. This article discusses implications of the NCTM standards for mathematics curriculum and instruction and provides three examples of lessons from problem-based curricula for various grade levels. These examples illustrate how the teaching of important mathematics through student exploration of interesting problems might unfold, and they highlight the differences between a problem-based approach and more traditional approaches. Considerations for teaching through a problem-based approach are raised, as well as reflections on the potential impact on student learning.  相似文献   
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