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排序方式: 共有289条查询结果,搜索用时 15 毫秒
1.
This work presents the implementation of a high‐order, finite‐volume scheme suitable for rotor flows. The formulation is based on the variable extrapolation MUSCL‐scheme, where high‐order spatial accuracy (up to fourth‐order) is achieved using correction terms obtained through successive differentiation. A variety of results are presented, including 2‐ and 3‐dimensional test cases. Results with the proposed scheme, showed better wake and higher resolution of vortical structures compared with the standard MUSCL, even when coarse meshes were employed. The method was also demonstrated for 3‐dimensional unsteady flows using overset and moving grids for the UH‐60A rotor in forward flight and the Enhanced Rotorcraft Innovative Concept Achievement tiltrotor in aeroplane mode. For medium grids, the present method adds reasonable CPU and memory overheads and offers good accuracy on relatively coarse grids. 相似文献
2.
Mathematical Notes - A theory of singular cubic homology of digraphs is developed; the obtained homology groups are proved to be functorial and homotopy invariant. Commutative diagrams of exact... 相似文献
3.
The Synthesis of B2(SIDip)2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes 下载免费PDF全文
Julian Bhnke Holger Braunschweig Theresa Dellermann William C. Ewing Kai Hammond J. Oscar C. Jimenez‐Halla Thomas Kramer Jan Mies 《Angewandte Chemie (International ed. in English)》2015,54(46):13801-13805
A new compound with the formula L‐B2‐L wherein the stabilizing ligand (L) is 1,3‐bis[diisopropylphenyl]‐4,5‐dihydroimidazol‐2‐ylidene (SIDip) has been synthesized, isolated, and characterized. The π‐acidity of the SIDip ligand, intermediate between the relatively non‐acidic IDip (1,3‐bis[diisopropylphenyl]imidazol‐2‐ylidene) ligand and the much more highly acidic CAAC (1‐[2,6‐diisopropylphenyl]‐3,3,5,5‐tetramethylpyrrolidin‐2‐ylidene) ligand, gives rise to a compound with spectroscopic, electrochemical, and structural properties between those of L‐B2‐L compounds stabilized by CAAC and IDip. Reactions of all three L‐B2‐L compounds with CO demonstrate the differences caused by their respective ligands, as the π‐acidities of the CAAC and SIDip carbenes enabled the isolation of bis(boraketene) compounds (L(OC)B‐B(CO)L), which could not be isolated from reactions with B2(IDip)2. However, only B2(IDip)2 and B2(SIDip)2 could be converted into bicyclic bis(boralactone) compounds. 相似文献
4.
The electron microanalyzer (EPMA): a powerful device for the microanalysis of filled polymeric materials 下载免费PDF全文
S. Bellayer M. Jimenez B. Gardelle G. Delaplace J. Bouquerel S. Duquesne S. Bourbigot 《先进技术聚合物》2015,26(8):1020-1026
The electron probe microanalyzer is a device often used in the field of geology or in the glass and steel industries. However, it is barely known or used in the polymer field. Thus, in this paper, we investigate the use of electron probe microanalyzer for polymer microanalyses and compared it with a scanning electron microscope equipped with an energy dispersive spectrometer. To show the unique potential of this technique only develop in our lab for polymer application, three different samples were studied: (i) a fire protective epoxy‐based coating submitted to aging in salt water, (ii) the distribution of organometallic catalysts into a thermal isolative silicone polymer, and (iii) the fouling growth of milk protein (biopolymer) on a stainless steel surface. Compared to an energy dispersive spectrometer, with an electron probe microanalyzer it is possible to quickly create X‐ray mappings of low concentration elements at a good resolution, as well as allowing the interpretation of the mechanism of action for the three samples which was impossible using only an energy dispersive spectrometer because of its too low detection resolution. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
5.
Résumé Les auteurs étudient le jet libre laminaire bidimensionnel d'un fluide viscoélastique obéissant à une loi de comportement semiempirique. Ils appliquent la méthode de raccordement des développements asymptotiques afin de déterminer le profil de vitesses à l'intérieur du jet, et l'entraînement du fluide extérieur. Les résultats obtenus illustrent l'influence de l'élasticité sur le champ de vitesse et la présence d'un gradient de pression à l'intérieur du jet. Les lignes de courant obtenues montrent que le fluide externe est aspiré vers l'axe du jet.
A 1;A 2;A 3 tenseurs de Rivlin-Ericksen - A constante définie par [27] - D domaine d'écoulement - f 1();f 0() fonctions définies par la transformation [20] - I tenseur unité - J nombre adimensionnel [12] - L longueur de référence - M flux total d'impulsion [19]m: µ/ - N Re nombre de Reynolds - N w nombre de Weissenberg - n indice de comportement - p pression - s indice de comportement «élastique» - T tenseur des contraintes - U 0 vitesse de référence - u, v composantes du vecteur vitesse - x, y coordonnées cartésiennes - Y coordonnée de «couche limite» [9] - Z variable complexe - angle entre les parois de la fente - paramètre de perturbation - variable affine [20] - () fonction définie par [2c] - coefficient d'élasticité - fonction de viscosité [2a] - µ indice de consistance - masse volumique - ; fonctions de courant - fonction définie par [2b] - 2ème invariant principal du tenseurA 1 Avec 7 figures 相似文献
Summary A two-dimensional laminar free jet of a viscoelastic fluid following a semiempiric constitutive equation is studied. The method of matching asymptotic expansions is applied to determine the velocity profiles inside the jet and the entrainment of the external fluid. The results thus obtained highlight the influence of elasticity on the velocity field and the presence of a pressure gradient inside the jet. The streamlines obtained show that the external fluid is sucked in towards the axis of the jet.
Zusammenfassung Es wird der laminare zweidimensionale Freistrahl einer viskoelastischen Flüssigkeit, die einem halbempirischen Stoffgesetz folgt, untersucht. Asymptotische Entwicklungen werden aneinandergefügt, um die Geschwindigkeitsverteilung in der Strahlströmung und die Ansaugkraft der äußeren Flüssigkeit zu bestimmen. Die erzielten Ergebnisse zeigen den Einfluß der Elastizität auf die Geschwindigkeitsverteilung und das Bestehen eines Druckgradienten innerhalb der Strahlströmung. Die abgeleiteten Stromlinien zeigen weiter, daß die äußere Flüssigkeit zur Strahlachse hin angesaugt wird.
A 1;A 2;A 3 tenseurs de Rivlin-Ericksen - A constante définie par [27] - D domaine d'écoulement - f 1();f 0() fonctions définies par la transformation [20] - I tenseur unité - J nombre adimensionnel [12] - L longueur de référence - M flux total d'impulsion [19]m: µ/ - N Re nombre de Reynolds - N w nombre de Weissenberg - n indice de comportement - p pression - s indice de comportement «élastique» - T tenseur des contraintes - U 0 vitesse de référence - u, v composantes du vecteur vitesse - x, y coordonnées cartésiennes - Y coordonnée de «couche limite» [9] - Z variable complexe - angle entre les parois de la fente - paramètre de perturbation - variable affine [20] - () fonction définie par [2c] - coefficient d'élasticité - fonction de viscosité [2a] - µ indice de consistance - masse volumique - ; fonctions de courant - fonction définie par [2b] - 2ème invariant principal du tenseurA 1 Avec 7 figures 相似文献
6.
P. Perez‐Tejeda A. Jimenez‐Ruiz E. M. Grueso R. Prado‐Gotor C. Carrasco A. Pastor N. Alvarez M. Garcia‐Lora M. Garcia‐Pageo 《国际化学动力学杂志》2013,45(12):780-786
The electron transfer reaction between [Ru(NH3)5pz]2+ and [Co(C2O4)3]3? was studied in the presence of monomers and aggregates of bile salts (sodium deoxycholate, sodium taurodeoxycholate, and sodium glycocholate) at 298.2 ± 0.1 K. The results show a decreasing rate constant with the successive addition of bile salts. To rationalize the trends of the reaction rate on the [bile salts], two models were used. One of them takes into account the aggregation feature by considering a stepwise self‐association between monomers, whereas the other assumes the formation of a critical micellar concentration. Binding constants between [Ru(NH3)5pz]2+ species and deoxycholate or taurodeoxycholate aggregates were higher than that for glycocholate aggregates. These results are consistent with the way in which the monomers are added to form the bile anion aggregates. 相似文献
7.
Wilson Merchan-Merchan Alexei V. Saveliev Walmy Cuello Jimenez 《Proceedings of the Combustion Institute》2011,33(2):1899-1908
In this paper we report the growth of 1-D and 3-D tungsten-oxide nanostructures on tungsten wire probes inserted in an opposed-flow oxy-fuel flame. The probe diameter and oxygen content in the oxidizer were varied to study their influence on the growth of tungsten-oxide nanostructures. The introduction of a 1-mm diameter W probe into the flame environment with an oxidizer composition of 50%O2 + 50%N2, resulted in the formation of 1-D nanorods on the upper surface of the probe. The formation of triangular, rectangular, square, and cylindrical 3-D channels with completely hollow or semi-hollow morphology was achieved by reducing the probe diameter to 0.5 mm. Whereas, the increase of the O2 content to 100% and the employment of a 1-mm probe resulted in the growth of ribbon-like micron-sized structures. The lattice spacing of ∼0.38 nm measured for the 1-D W-oxides closely matches a monoclinic WO3 structure. X-ray photoelectron spectroscopy analysis revealed that the larger 3-D structures also consist of WO3 confirming that the chemical composition of the structures remains the same while varying the probe and flame parameters. The proposed growth mechanism states that the 3-D WO3 structures are formed through the lateral coalescence of 1-D W-oxide nanorods. 相似文献
8.
Platinum‐Promoted Ga/Al2O3 as Highly Active,Selective, and Stable Catalyst for the Dehydrogenation of Propane 下载免费PDF全文
Jesper J. H. B. Sattler Dr. Ines D. Gonzalez‐Jimenez Dr. Lin Luo Brien A. Stears Dr. Andrzej Malek Dr. David G. Barton Dr. Beata A. Kilos Dr. Mark P. Kaminsky Tiny W. G. M. Verhoeven Eline J. Koers Prof. Dr. Marc Baldus Prof. Dr. Bert M. Weckhuysen 《Angewandte Chemie (International ed. in English)》2014,53(35):9251-9256
A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt % Ga, and 0.25 wt % K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga3+ species are the active species and where Pt functions as a promoter. 相似文献
9.
Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ ME Multiple Bonds 下载免费PDF全文
Florian Hupp Dr. Mengtao Ma Franziska Kroll Dr. J. Oscar C. Jimenez‐Halla Dr. Rian D. Dewhurst Dr. Krzysztof Radacki Dr. Andreas Stasch Prof. Dr. Cameron Jones Prof. Dr. Holger Braunschweig 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(51):16888-16898
We present the isolation of the first mononuclear dihalogermylene, and mono‐ and dinuclear stannylene complexes of transition metals. These exhibit exceptionally pyramidalized Group 14 centers. Additionally, removal of the halide substituents from the Ge/Sn atom was successfully performed in two ways, halide abstraction and reduction, leading to a variety of unusual structural motifs. 相似文献
10.
Water‐Stable Zirconium‐Based Metal–Organic Framework Material with High‐Surface Area and Gas‐Storage Capacities 下载免费PDF全文
Dr. Oleksii V. Gutov Dr. Wojciech Bury Dr. Diego A. Gomez‐Gualdron Dr. Vaiva Krungleviciute Dr. David Fairen‐Jimenez Dr. Joseph E. Mondloch Dr. Amy A. Sarjeant Salih S. Al‐Juaid Prof. Dr. Randall Q. Snurr Prof. Dr. Joseph T. Hupp Prof. Dr. Taner Yildirim Prof. Dr. Omar K. Farha 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(39):12389-12393
We designed, synthesized, and characterized a new Zr‐based metal–organic framework material, NU‐1100 , with a pore volume of 1.53 ccg?1 and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g?1; to our knowledge, currently the highest published for Zr‐based MOFs. CH4/CO2/H2 adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g?1, which corresponds to 43 g L?1. The volumetric and gravimetric methane‐storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g?1, respectively. 相似文献