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排序方式: 共有93条查询结果,搜索用时 19 毫秒
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Havva Esma OKUR KUTAY 《Turkish Journal of Chemistry》2020,44(6):1463
The existence of cation-vacancy sites in fullerides might lead to long-range ordering and generate a new vacancy-ordered superstructure. The purpose of this work is to search whether or not long-range ordering of vacant tetrahedral sites, namely superstructure emerges in nonstoichiometric K 1.5 Ba 0.25 CsC 60 fulleride. Therefore, K 1.5 Ba 0.25 CsC 60 with cation-vacancy sites is synthesized using a precursor method to avoid inadequate stoichiometry control and formation of impurity phases within the target composition. For this purpose, first, phase-pure K 6 C 60 , Ba 6 C 60 and Cs 6 C 60 precursors are synthesized. Stoichiometric quantities of these precursors are used for further reaction with C 60 to afford K 1.5 Ba 0.25 CsC 60 . Rietveld analysis of the high-resolution synchrotron X-ray powder diffraction data of the precursors and K 1.5 Ba 0.25 CsC 60 confirms that K 6 C 60 , Ba 6 C 60 and Cs 6 C 60 are single-phase and they crystallize in a body-centered-cubic structure ( Im 3) as reported in the literature. The analysis also shows that K 1.5 Ba 0.25 CsC 60 phase can be perfectly modeled using a face-centered cubic structure. No new peaks appear which could have implied the appearance of a superstructure. This suggests that there is no long-range ordered arrangement of vacant tetrahedral sites in K 1.5 Ba 0.25 CsC 60 . 相似文献
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Tris(pentafluorophenyl)borane [B(C6F5)3] has been used as an efficient catalyst for reductive alkylation of alkoxy benzenes using aldehydes as an alkylating agent in the presence of polymethylhydrosiloxane (PMHS). Various alkylated trimethoxybenzene derivatives have been prepared in good to high yields. In addition, B(C6F5)3 was also used as a catalyst for the reaction of electron-rich arenes with aldehydes to obtain triarylmethanes. The use of reductive alkylation protocol for the synthesis of an isochroman and tetrahydroisoquinoline derivatives has also been demonstrated. 相似文献
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Bayesian networks (BNs) are a useful tool for applications where dynamic decision-making is involved. However, it is not easy to learn the structure and conditional probability tables of BNs from small datasets. There are many algorithms and heuristics for learning BNs from sparse datasets, but most of these are not concerned with the quality of the learned network in the context of a specific application. In this research, we develop a new heuristic on how to build BNs from sparse datasets in the context of its performance in a real-time recommendation system. This new heuristic is demonstrated using a market basket dataset and a real-time recommendation model where all items in the grocery store are RFID tagged and the carts are equipped with an RFID scanner. With this recommendation model, retailers are able to do real-time recommendations to customers based on the products placed in cart during a shopping event. 相似文献
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The complex formations of homopolymers and copolymers of poly(N‐isopropyl acrylamide) (PNIPAAm), polyacrylamide (PAAm) and poly(itaconic acid) (PIA) with Cu(II) ions in aqueous solutions were studied by using UV‐visible spectra in the region of 200–1100 nm and cyclic voltammograms between ?0.800 V and 0.600 V. According to the optical and electrochemical spectra of the polymer‐ and copolymer‐Cu(II) complexes and their ternary complexes with alanine, i.e., absorptions and the shifts in the wavelength of the maximum absorptions, currents and potentials of the peaks in the pH range of 3–12, the intensities of anodic and cathodic peak currents of polymers containing IA groups decrease with increasing pH and they show maximum absorptions at lower wavelengths than do the homopolymers used in this work. The peak point of the visible band shifts from 800 to 650 nm, with increasing pH, while the intensity of the third anodic peak observed after pH=4 increases in the case of both Ala‐Cu(II) and its ternary solution with P(NIPAAm‐co‐IA, 9.8 mol%). Both the pH‐dependent shifts of maximum absorptions and the appearence of the third anodic peaks as the pH raised were interpreted as a presence of tetracoordinated Cu(II) complexes in the solution and on the electrode surface, involving combined carboxyl, amide and amine interaction. 相似文献
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Deniz Altunöz-Erdoğan Nevin Erk Esma Kılıç 《Central European Journal of Chemistry》2013,11(5):706-716
Reboxetine (RBX) electrochemical redox behavior at hanging mercury drop (HMDE) and glassy carbon electrodes (GCE) was studied in various pH Britton-Robinson universal buffers using cyclic voltammetry and square-wave voltammetry. RBX was reduced at the HMDE and oxidized at the GCE with reversible adsorption controlled and irreversible diffusion controlled processes respectively. The anodic peak is due to the amine and the cathodic peak may correspond to oxygen protonation. An oxidation reaction mechanism is proposed. The linear relation between peak currents and RBX concentration allowed simple, sensitive, precise and inexpensive voltammetric procedures to be developed. The limit of detection was 0.04 µM RBX. The procedures were successfully applied to human urine and RBX tablet assay. Therapeutic RBX concentrations in human serum were not detected due to strong drug-protein binding. Using bovine serum albumin, the methods were used to investigate the effect of serum protein binding on RBX determination. 相似文献
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Anil Kumar Sudeep SharanNitin Kumar Udaybir SinghH. Khatun V. VyasA.K. Sinha 《Infrared Physics & Technology》2012,55(1):93-97
This paper describes the design of a large sized diamond window for 1 MW, 170 GHz gyrotron. The diameter and the thickness of the diamond window are 80 mm and 1.482 mm, respectively, whose edge is directly cooled by water. The CST microwave studio has been used for the S-parameter, and finite element analysis code ANSYS has been used for the thermal and the structural simulation. The return loss (S11) and insertion loss (S21) of the 170 GHz gyrotron window have been found −39.80 dB and −0.011 dB, respectively. The thermal and structural analysis of RF window the 397 K temperature at disk center and maximum displacement 0.01 mm has been found in the window disk during the thermal analysis. 相似文献
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