全文获取类型
收费全文 | 939篇 |
免费 | 17篇 |
国内免费 | 2篇 |
专业分类
化学 | 474篇 |
晶体学 | 6篇 |
力学 | 21篇 |
数学 | 265篇 |
物理学 | 192篇 |
出版年
2021年 | 10篇 |
2018年 | 7篇 |
2017年 | 9篇 |
2016年 | 16篇 |
2015年 | 14篇 |
2014年 | 14篇 |
2013年 | 55篇 |
2012年 | 47篇 |
2011年 | 56篇 |
2010年 | 39篇 |
2009年 | 31篇 |
2008年 | 36篇 |
2007年 | 44篇 |
2006年 | 30篇 |
2005年 | 26篇 |
2004年 | 23篇 |
2003年 | 21篇 |
2002年 | 16篇 |
2001年 | 6篇 |
2000年 | 12篇 |
1999年 | 8篇 |
1997年 | 10篇 |
1996年 | 13篇 |
1995年 | 11篇 |
1994年 | 10篇 |
1993年 | 8篇 |
1992年 | 11篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 11篇 |
1979年 | 17篇 |
1978年 | 13篇 |
1977年 | 10篇 |
1976年 | 12篇 |
1975年 | 7篇 |
1974年 | 9篇 |
1972年 | 10篇 |
1971年 | 9篇 |
1969年 | 6篇 |
1933年 | 13篇 |
1929年 | 6篇 |
1926年 | 6篇 |
1909年 | 7篇 |
1907年 | 6篇 |
排序方式: 共有958条查询结果,搜索用时 302 毫秒
1.
2.
Oded Stark 《The Journal of mathematical sociology》2020,44(3):138-146
ABSTRACTCombining a standard measure of concern about low relative wealth and a standard measure of relative risk aversion leads to a novel explanation of variation in risk-taking behavior identified and documented by social psychologists and economists. We obtain two results: (1) Holding individual i’s wealth and his rank in the wealth distribution constant, the individual’s relative risk aversion decreases when he becomes more relatively deprived as a result of an increase in the average wealth of the individuals who are wealthier than he is. (2) If relative deprivation enters the individual’s utility function approximately linearly then, holding constant individual i’s wealth and the average wealth of the individuals who are wealthier than he is, the individual’s relative risk aversion decreases when he becomes more relatively deprived as a result of a decline in his rank. Our findings provide a theoretical support for evidence about the propensity of relatively deprived individuals to gamble and resort to other risky behaviors. 相似文献
3.
Dr. Renata Kaczmarek Samuel Ward Dipra Debnath Taisiya Jacobs Alexander D. Stark Dariusz Korczyński Prof. Dr. Anil Kumar Prof. Dr. Michael D. Sevilla Dr. Sergey A. Denisov Dr. Viacheslav Shcherbakov Dr. Pascal Pernot Prof. Dr. Mehran Mostafavi Prof. Dr. Roman Dembinski Prof. Dr. Amitava Adhikary 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(43):9495-9505
The directionality of the hole-transfer processes between DNA backbone and base was investigated by using phosphorodithioate [P(S−)=S] components. ESR spectroscopy in homogeneous frozen aqueous solutions and pulse radiolysis in aqueous solution at ambient temperature confirmed initial formation of G.+-P(S−)=S. The ionization potential of G-P(S−)=S was calculated to be slightly lower than that of guanine in 5′-dGMP. Subsequent thermally activated hole transfer from G.+ to P(S−)=S led to dithiyl radical (P-2S.) formation on the μs timescale. In parallel, ESR spectroscopy, pulse radiolysis, and density functional theory (DFT) calculations confirmed P-2S. formation in an abasic phosphorodithioate model compound. ESR investigations at low temperatures and higher G-P(S−)=S concentrations showed a bimolecular conversion of P-2S. to the σ2-σ*1-bonded dimer anion radical [-P-2S 2S-P-]− [ΔG (150 K, DFT)=−7.2 kcal mol−1]. However, [-P-2S 2S-P-]− formation was not observed by pulse radiolysis [ΔG° (298 K, DFT)=−1.4 kcal mol−1]. Neither P-2S. nor [-P-2S 2S-P-]− oxidized guanine base; only base-to-backbone hole transfer occurs in phosphorodithioate. 相似文献
4.
Cover Picture: Robust Chemical Preservation of Digital Information on DNA in Silica with Error‐Correcting Codes (Angew. Chem. Int. Ed. 8/2015) 下载免费PDF全文
5.
Triphilic Ionic‐Liquid Mixtures: Fluorinated and Non‐fluorinated Aprotic Ionic‐Liquid Mixtures 下载免费PDF全文
Dr. Oldamur Hollóczki Dr. Marina Macchiagodena Henry Weber Martin Thomas Dr. Martin Brehm Prof. Dr. Annegret Stark Dr. Olga Russina Dr. Alessandro Triolo Prof. Dr. Barbara Kirchner 《Chemphyschem》2015,16(15):3325-3333
We present here the possibility of forming triphilic mixtures from alkyl‐ and fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which instead of the often observed two domains—polar and nonpolar—three stable microphases are present: polar, lipophilic, and fluorous ones. The fluorinated side chains of the cations indeed self‐associate and form domains that are segregated from those of the polar and alkyl domains. To enable miscibility, despite the generally preferred macroscopic separation between fluorous and alkyl moieties, the importance of strong hydrogen bonding is shown. As the long‐range structure in the alkyl and fluoroalkyl domains is dependent on the composition of the liquid, we propose that the heterogeneous, triphilic structure can be easily tuned by the molar ratio of the components. We believe that further development may allow the design of switchable, smart liquids that change their properties in a predictable way according to their composition or even their environment. 相似文献
6.
Kamil J. Kuder Magdalena Kotaska Katarzyna Szczepaska Kamil Mika David Reiner-Link Holger Stark Katarzyna Kie-Kononowicz 《Molecules (Basel, Switzerland)》2021,26(8)
In an attempt to find new dual acting histamine H3 receptor (H3R) ligands, we designed a series of compounds, structurally based on previously described in our group, a highly active and selective human histamine H3 receptor (hH3R) ligand KSK63. As a result, 15 obtained compounds show moderate hH3R affinity, the best being the compound 17 (hH3R Ki = 518 nM). Docking to the histamine H3R homology model revealed two possible binding modes, with key interactions retained in both cases. In an attempt to find possible dual acting ligands, selected compounds were tested for antioxidant properties. Compound 16 (hH3R Ki = 592 nM) showed the strongest antioxidant properties at the concentration of 10−4 mol/L. It significantly reduced the amount of free radicals presenting 50–60% of ascorbic acid activity in the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, as well as showed antioxidative properties in the ferric reducing antioxidant power (FRAP) assay. Despite the yet unknown antioxidation mechanism and moderate hH3R affinity, 16 (QD13) constitutes a starting point for the search of potential dual acting H3R ligands-promising tools for the treatment of neurological disorders associated with increased neuronal oxidative stress. 相似文献
7.
8.
9.
Edmund R. Peay 《The Journal of mathematical sociology》2013,37(2):319-321
A simple modification of a method presented by Doreian (1974) adapts it for finding, in a network or “valued graph”, the maximum level paths which do not have cycles or repeated points and which have a specified maximum length. 相似文献
10.
Marek Biziuk Edmund Kozłowski Alicja Błasiak 《International journal of environmental analytical chemistry》2013,93(3):147-151
Abstract The present method is based on preconcentration of organic contaminants on XAD-4 as sorbent, thermal desorption, mineralization and coulometric argentometric titration for the final determination of halides. The results were calculated as the total parameter VOX (volatile organic halogen) expressed as chlorine. The method has been used for the VOX determination in tap water, Vistula river water and Baltic Sea water. Sampling of the Baltic Sea water has been carried out during the research cruise of the r/v ‘Oceania’. The relatively high anthropogenic pollution of the river Vistula (c vox = 11–45 μg Cl/cd3), Gulf of Gdańsk (c vox = 0.6–4.5 μg Cl/dm3) and the Pomerania Bay (c vox = 2 μg Cl/dm3) has been determined. The VOX concentration in the tap water varied between 13 and 56 μg/dm3; that is, this water is seriously polluted by volatile organic halogen compounds. 相似文献