Adsorption of fast green and erythrosin-B to montmorillonite modified with crystal violet

Adsorption of erythrosin-B (EB) and fast green (FG) to a non-charged organosmectite based on crystal violet adsorbed up to 100% of the cation exchange capacity (CEC) was tested. Adsorption isotherms of EB and FG were prepared at 3, 24 and 50°C. All isotherms are of H-type reaching loads of approximately up to 20% of the original CEC of the crude montmorillonite (up to 0.15 and 0.10 mol dye kg^–1 clay for EB and FG, respectively). Adsorption decreases with temperature, indicating an exothermic process. Enthalpy was evaluated using van’t Hoff equation, yielding approximately –20 kJ mol^–1 for both dyes.     

Mode-Grüneisen parameters in disordered molecular crystals: Raman spectra of NH4Br and NH4I under hydrostatic pressure

The Raman spectrum of NH₄I has been measured under hydrostatic pressure. The high pressure phase of NH₄I was identified with the disordered CsCl-type phase by comparing the spectrum with that of NH₄ Br. The mode-Grünesen parameters of NH₄Br and NH₄I were determined from the frequency shift of phonon bands under hydrostatic pressure. These values were compared with the thermodynamic value and that obtained from the Slater relation. Contributions to the thermodynamic Grüneisen constant are discussed from free energy terms of NH⁺₄-orientation and -interactions with lattice modes.     

Self-injection length in La0.7Ca0.3MnO3-YBa2Cu3O7-δ ferromagnet-superconductor multilayer thin films

We have carried out extensive studies on the self-injection problem in barrierless heterojunctions between La_0.7Ca_0.3MnO₃ (LCMO) and YBa₂Cu₃O_7-δ (YBCO) thin films. The heterojunctions were formed in situ by sequentially growing LCMO and YBCO films on 〈100〉 LaAlO₃ (LAO) substrate using a pulsed laser deposition (PLD) system. YBCO micro-bridges with 64 μm width were patterned both on the LAO (control) and LCMO side of the substrate. Critical current, I _c, was measured at 77 K on both the control side as well as the LCMO side for different YBCO film thickness. It was observed that while the control side showed a J _c of ∼ 2 × 10⁶ A/cm², the LCMO side showed about half the value for the same thickness (1800 ?). The difference in J _c indicates that a certain thickness of YBCO has become ‘effectively’ normal due to self-injection. From the measurement of J _c at two different thicknesses (1800 ? and 1500 ?) of YBCO films both on the LAO as well as the LCMO side, the value of self-injection length (at 77 K) was estimated to be ∼ 900 ?. To the authors’ best knowledge, this is the first time that self-injection length has been quantified. A control experiment carried out with LaNiO₃ deposited by PLD on YBCO did not show any evidence of self-injection.     

Observation of the transfer of the local angular momentum density of a multiringed light beam to an optically trapped particle

We observe the spinning and orbital motion of a microscopic particle trapped within a multiringed light beam that arises from the transfer of the spin and orbital components of the light's angular momentum. The two rotation rates are measured as a function of the distance between the particle and the axis of the trapping beam. The radial dependence of these observations is found to be in close agreement with the accepted theory.     

Electron-lattice interaction in the absorption spectra of thallium doped alkali halides

The electron-lattice interaction of NaCl:Tl⁺, KCl:Tl⁺, KBr:Tl⁺, and KI:Tl⁺ is discussed using the moments of the absorption bands. The discussion is based on a theory ofToyozawa andInoue andHonma. Consistency of the data is found for the absorption measurements. An analysis of the band shift under applied stress shows for theA-band in KCl and KBr and for theA- andB-band in KI that the electronlattice coupling constants derived from these data assuming next neighbour interaction differ considerably from those derived from the second moments of the bands.     

Magnetoelectric effect in cobalt ferrite-barium titanate composites and their electrical properties

CoFe₂O₄-BaTiO₃ composites were prepared using conventional ceramic double sintering process with various compositions. Presence of two phases in the composites was confirmed using X-ray diffraction. The dc resistivity and thermoemf as a function of temperature in the temperature range 300 K to 600 K were measured. Variation of dielectric constant (ɛ′) with frequency in the range 100 Hz to 1 MHz and also with temperature at a fixed frequency of 1 kHz was studied. The ac conductivity was derived from dielectric constant (ɛ′) and loss tangent (tan δ). The nature of conduction is discussed on the basis of small polaron hopping model. The static value of magnetoelectric conversion factor has been studied as a function of magnetic field.     

Energy dependence of multiplicity in proton-nucleus collisions and models of multiparticle production

This is a continuation of our earlier investigation (Gurtuet al 1974Phys. Lett. 50 B 391) on multiparticle production in proton-nucleus collisions based on an exposure of emulsion stack to 200 GeV/c beam at the NAL. It is found that the ratioR _em = 〈n _s〉/〈n _ch〉, where 〈n _ch〉 is the charged particle multiplicity in pp-collisions, increases slowly from about 1 at 10 GeV/c to 1·6 at 68 GeV/c and attains a constant value of 1·71 ± 0·04 in the region 200 to 8000 GeV/c. Furthermore,R _em = 1·71 implies an effectiveA-dependence ofR _A =A ^0.18,i.e., a very weak dependence. Predictions ofR _em on various models are discussed and compared with the emulsion data. Data seem to favour models of hadron-nucleon collisions in which production of particles takes place through adouble step mechanism,e.g., diffractive excitation, hydrodynamical and energy flux cascade as opposed to models which envisage instantaneous production.     

Interferometric optical path measurement of a glass wedge with single photons and biphotons

We have measured the phase structure of a glass wedge with single photons and biphotons in a Mach-Zehnder interferometer using parametric downconverted light from a Hong-Ou-Mandel particle interferometer as the source. By scanning the wedge through the focus of a microscope objective we find a doubling of the period of the interference pattern in the coincidence counts for biphotons compared to the single-photon experiment. We compare our measurement setup with classical ones and discuss some of the problems of superresolution in quantum lithography.