全文获取类型
收费全文 | 542篇 |
免费 | 32篇 |
专业分类
化学 | 256篇 |
晶体学 | 2篇 |
力学 | 26篇 |
数学 | 48篇 |
物理学 | 242篇 |
出版年
2023年 | 4篇 |
2022年 | 2篇 |
2021年 | 9篇 |
2020年 | 16篇 |
2019年 | 15篇 |
2018年 | 9篇 |
2017年 | 5篇 |
2016年 | 15篇 |
2015年 | 15篇 |
2014年 | 17篇 |
2013年 | 29篇 |
2012年 | 33篇 |
2011年 | 51篇 |
2010年 | 26篇 |
2009年 | 18篇 |
2008年 | 46篇 |
2007年 | 27篇 |
2006年 | 36篇 |
2005年 | 21篇 |
2004年 | 28篇 |
2003年 | 13篇 |
2002年 | 19篇 |
2001年 | 10篇 |
2000年 | 14篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 13篇 |
1995年 | 6篇 |
1994年 | 17篇 |
1993年 | 20篇 |
1992年 | 9篇 |
1991年 | 10篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有574条查询结果,搜索用时 15 毫秒
1.
Sang Hyun Kwon Yoshio Okamoto Chiyo Yamamoto Wonjo Cheong Myeonghee Moon Jung Hag Park 《Analytical sciences》2006,22(12):1525-1529
Porous zirconia particles are very robust material and have received considerable attention as a stationary phase support for HPLC. We prepared cellulose dimethylphenylcarbamate-bonded carbon-clad zirconia (CDMPCCZ) as a chiral stationary phase (CSP) for separation of enantiomers of a set of 14 racemic compounds in normal phase (NP) and reversed-phase (RP) liquid chromatography. Retention and enantioselectivity on CDMPCCZ were compared to those on CDMPC-coated zirconia (CDMPCZ) to see how the change in immobilization method of the chiral selector affects the retention and chiral selectivity. In NPLC, retention was longer and the number of resolved racemates was smaller on CDMPCCZ than on CDMPCZ. However, chiral selectivity factors for some resolved racemates were better on CDMPCCZ than on CDMPCZ. The longer retention on CDMPCCZ is likely due to strong, non-chiral discriminating interactions with the carbon layer on CDMPCZ. In RPLC only two racemates were resolved on CDMPCCZ, but retention times were shorter than, and resolutions were comparable to, those in NPLC, indicating a potential for improving chromatographic performance of the CDMPCCZ column in RPLC with optimized column preparation and separation conditions. 相似文献
2.
Characterization of autocatalytic decomposition reactions is important
for the safe handling and storage of energetic materials. Isothermal differential
scanning calorimetry (DSC) has been widely used to detect autocatalytic decomposition
of energetic materials. However, isothermal DSC tests are time consuming and
the choice of experimental temperature is crucial. This paper shows that an
automatic pressure tracking calorimeter (APTAC) can be a reliable and efficient
screening tool for the identification of autocatalytic decomposition behavior
of energetic materials.
Hydroxylamine nitrate (HAN) is an important
member of the hydroxylamine family. High concentrations of HAN are used as
liquid propellants, and low concentrations of HAN are used primarily in the
nuclear industry for decontamination of equipment. Because of its instability
and autocatalytic decomposition behavior, HAN has been involved in several
incidents. 相似文献
3.
Y. Zhao W.C. Zhai W.L. Seah K.Y. Lim F.C. Cheong C.H. Sow 《Applied physics. B, Lasers and optics》2007,87(2):243-247
A study of the variation of the spectral shape and the harmonic distribution of the high-order harmonics generated from silver
plasma on the frequency chirp of the driving laser radiation (793 nm 48 fs) is reported. The results of the systematic study
of the harmonic generation from the 21st order up to the 61st order (λ=13 nm) are presented. A tuning of the harmonic wavelength
up to 0.8 nm can be accomplished by variation of the laser chirp.
PACS 42.65.Ky; 42.79.Nv; 52.38.Mf 相似文献
4.
Sharmin Kharrazi S.W. Gosavi T. Venkatesan J. Urban S.-W. Cheong 《Solid State Communications》2006,138(8):395-398
We report on the synthesis of TbMnO3 nanoparticles by chemical co-precipitation route and their structural, chemical bonding, magnetic and dielectric properties. It is shown that the interesting multiferroic properties of this system as reflected by the concurrent occurrence of magnetic and dielectric transitions are retained in the nanoparticles (size∼40 nm). However, the nanoparticle constitution and properties are seen to depend significantly on the calcination temperature. While the nanoparticles obtained by calcination at 800 °C correspond very well with the reported properties of single phase TbMnO3 (all the key magnetic and dielectric features near 7, 27 and 41 K, albeit with reduced dielectric constant) the nanoparticles obtained by calcination at 900 °C develop a Tb deficient skin which softens the transitions, reducing the dielectric constant further. 相似文献
5.
6.
Yanfang Wu Yin Yao Soshan Cheong Richard D. Tilley J. Justin Gooding 《Chemical science》2020,11(46):12570
Disease diagnosis at earlier stages requires the development of ultrasensitive biosensors for detecting low-abundance biomarkers in complex biological fluids within a reasonable time frame. Here, we demonstrate the development of an ultrasensitive nanopore blockade biosensor that can rapidly diagnose a model protein biomarker, prostate-specific antigen (PSA) with high selectivity. The solid-state nanopores have gold located only along the length of the nanopore whilst the rest of the membrane is silicon nitride. The orthogonal use of materials allows nanopore arrays with a different surface chemistry inside the nanopore relative to the rest of the membrane to be fabricated. The importance of this differential surface chemistry is it can improve the detection limit of nanopore blockade sensors in quantitative analysis. Based on such functionalized nanopore devices, nanopore blockade sensors lower the limit of detection by an order of magnitude and enable ultrasensitive detection of PSA as low as 80 aM. The findings from this study open new opportunities for nanopore sensors in further developments including optical detection and ultralow detection limit biosensing at complex biological fluids.Selective detection of attomolar proteins was achieved using gold lined nanopores in a nanopore blockade sensor. 相似文献
7.
8.
9.
10.