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排序方式: 共有101条查询结果,搜索用时 218 毫秒
1.
A. K. Umbetova M. I. Choudhary N. A. Sultanova G. Sh. Burasheva Zh. A. Abilov 《Chemistry of Natural Compounds》2006,42(3):332-335
The taraxeran-14-ene-type triterpenoids methyl 3-β-al-D-fridoolean-14-en-28-oate (1), 3-α-[3″,4′-dihydroxytrans-cinnamoyl]-oxy-D-fridoolean-14-en-28-oic acid (2), and β-sitosterol (3) were isolated from the aerial part of plants from the genus Tamarix (T. laxa, T. elongata) (Tamaricaceae). The structures of the triterpenoids were proved using spectral data (IR, UV, PMR, 13C NMR, 2D NMR 1H-1H COSY, HMQC, HMBC, mass). Compound 1 is new and not previously described in the literature.
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Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 271–273, May–June, 2006. 相似文献
2.
L. M. Khalilov V. S. Sultanova E. V. Vasil'eva L. V. Spirikhin I. P. Baikova S. N. Lakeev F. Z. Galin G. A. Tolstikov A. A. Panasenko 《Chemistry of Natural Compounds》1989,24(4):491-497
The structures have been established and the stereochemical assignments have been made of eight pairs of diastereomers and three quartets of stereoisomers of esters of 2,2-dialkylspiro[cyclopropane-3,3-indene]-1-carboxylic acids of the pyrethroid series by the methods of13C NMR spectroscopy using the shift reagent Eu(fod)3. Criteria have been found for assigning the stereoisomers on the basis of the characteristic values of the13C NMR chemical shifts of the signals of the methyl groups at C-2 for determining configuration of the substituents of the cyclopropane moiety of the molecule and of the C-2 signal itself for identifying isomers with respect to the side chain of the pyrethroid molecule. Criteria are proposed for identifying stereoisomers from the chemical shifts of the protons of the gem-dimethyl groups at C-2 in the1H NMR spectra.Institute of Chemistry, Bashkir Branch, Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 577–583, July–August, 1988. 相似文献
3.
L. M. Khalilov O. V. Shitikova V. S. Sultanova V. A. Dokichev C. Z. Sultanov A. A. Panasenko U. M. Dzhemilev G. A. Tolstikov 《Russian Chemical Bulletin》1990,39(3):481-484
The13C NMR spectra of 15 spirocyclopropane derivatives in the (C7)-norbornane series have been investigated, signal assignments made, and the stereochemistry of isomeric products has been determined. It was found that the methylene group signals in the cyclopropane fragment may be used as criteria in making the stereochemical assignments.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 555–559, March, 1990. 相似文献
4.
5.
G. N. Sakhabutdinova G. Z. Raskil’dina S. S. Zlotskii R. M. Sultanova 《Doklady Chemistry》2018,482(2):233-236
It has been revealed that the copper(II) triflate catalyzed reaction of ethyl-2-diazo-3-oxobutanoate with phenols followed by cyclization of the intermediate enol in the presence of polyphosphoric acid is a simple and efficient method of synthesis of polysubstituted benzofurans. The use of pyrocatechol leads to the corresponding substituted 1,4-benzodioxine-2-carboxylates as major products. 相似文献
6.
A. R. Shiriazdanova R. M. Sultanova L. V. Spirikhin S. S. Zlotskii 《Russian Journal of General Chemistry》2012,82(7):1224-1227
The catalytic cyclopropanation of cis- and trans-1,3-dichlorpropenes with methyl diazoacetate in the presence of a copper catalyst was studied. The products composition and ratio were shown to depend on the spatial structure of 1,3-dichloropropene. 相似文献
7.
L. R. Yakupova R. A. Nasibullina V. A. Shamukaev R. M. Sultanova R. L. Safiullin 《Kinetics and Catalysis》2020,61(2):232-237
The antioxidant activity of 2-aminothiazoles containing a diterpene fragment in a model system of initiated radical-chain oxidation of 1,4-dioxane was evaluated. The compounds exhibited different inhibitory activities depending on their structure. The effective rate constant of the interaction of substituted 2-aminothiazoles with the 1,4-dioxane peroxyl radical was measured. 2-Aminothiazoles obtained by the chemical transformations of maleopimaric acid N-phenylamide showed higher reactivity with the peroxyl radical. 相似文献
8.
M. A. Aldzhanov A. A. Abdurragimov S. G. Sultanova M. D. Nadzhafzade 《Physics of the Solid State》2007,49(2):320-321
The specific heat of the ferromagnetic semiconductor TlCrS2 is investigated experimentally, and the thermodynamic parameters are calculated. It is demonstrated that the temperature dependence of the magnetic specific heat of the TlCrS2 compound is characteristic of quasi-two-dimensional magnetic systems. 相似文献
9.
10.
A. V. Maidanova A. D. Bakeeva R. M. Sultanova R. Z. Biglova V. A. Dokichev 《Russian Journal of Organic Chemistry》2010,46(10):1461-1465
Reactions of primary and secondary amines with methyl diazoacetate in the presence of Ru2(OAc)4Cl gave the corresponding N-substituted glycine methyl esters in almost quantitative yield. Catalytic decomposition of methyl
diazoacetate generates methoxycarbonylcarbene which is inserted into the N-H bond of amines with high regioselectivity. 相似文献