全文获取类型
收费全文 | 97篇 |
免费 | 5篇 |
专业分类
化学 | 66篇 |
力学 | 4篇 |
数学 | 19篇 |
物理学 | 13篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 1篇 |
2020年 | 5篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 16篇 |
2012年 | 3篇 |
2011年 | 8篇 |
2010年 | 1篇 |
2009年 | 1篇 |
2008年 | 7篇 |
2007年 | 8篇 |
2006年 | 5篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 4篇 |
2002年 | 6篇 |
2000年 | 1篇 |
1994年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有102条查询结果,搜索用时 31 毫秒
1.
Klai Nadia Berredjem Malika Khettache Nawel Belghit Med Yazid Rgaïnia Zine Nour‐Eddine Aouf 《Journal of heterocyclic chemistry》2004,41(1):57-60
Dedicated to the memory of Pr. Ladjama Daif A series of chiral cyclosulfamides have been synthesized by alkaline cyclisation starting from N‐benzoylamino acids (Ala, Val, Leu, Phe) derivatives and chlorosulfonyl isocyanate. A simplified and regioselective deprotection of the cyclic compounds (cyclosulfamides) containing the tert‐butyloxycarbonyl group (Boc) has been achieved in good yield by fusion under reduced pressure. 相似文献
2.
Nicolas Meyer Mohamad Nasser Eddine Christelle Delaite Guy Hurtrez Philippe Dumas 《Journal of polymer science. Part A, Polymer chemistry》2003,41(21):3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1‐diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium, hyperbranched structures were synthesized. Extensions of an already proposed mechanism in polar and nonpolar media were examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3329–3335, 2003 相似文献
3.
A general procedure has been developed for the simulation of charged liquid and electrostatically atomized sprays. The procedure follows a Lagrangian approach for simulation of spray droplets and a Eulerian approach for gas‐phase variables, including the electric field generated by the charge presence on droplets. Validation of the procedure was examined through simulations of previously published charged spray experiments. Results showed that for the specification of initial droplet charge, modelling the droplet charge–diameter relationship through a scaling law is as reliable a method as using a directly obtained charge–diameter relationship from experimental measurements. The normalized root‐mean‐square errors for sprays using the two methods were shown to be within 12% of one another, for the prediction of spatially averaged profiles of mean droplet diameters, mean axial velocities and mean radial droplet velocities. Results showed that the general spatial characteristics and dynamics of a charged liquid spray can successfully be reproduced, including the axial and radial dispersal pattern of droplets and the distribution of mean droplet diameters throughout the spray plume. For all sprays with droplet charges defined through a scaling law relationship, the normalized root‐mean‐square errors range from 9.0% to 31.6% for mean droplet diameters, 10.4% to 67.9% for mean axial droplet velocities and 16.8% to 38.6% for mean radial droplet velocities. Lastly, we present a brief set of general recommendations for simulating electrostatically atomized dielectric liquid sprays.Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
4.
BedrʼEddine Ainseba Mostafa Bendahmane Ricardo Ruiz-Baier 《Journal of Mathematical Analysis and Applications》2012,388(1):231-247
In the present paper, an optimal control problem constrained by the tridomain equations in electrocardiology is investigated. The state equations consisting in a coupled reaction–diffusion system modeling the propagation of the intracellular and extracellular electrical potentials, and ionic currents, are extended to further consider the effect of an external bathing medium. The existence and uniqueness of solution for the tridomain problem and the related control problem is assessed, and the primal and dual problems are discretized using a finite volume method which is proved to converge to the corresponding weak solution. In order to illustrate the control of the electrophysiological dynamics, we present some preliminary numerical experiments using an efficient implementation of the proposed scheme. 相似文献
5.
Radia Bouasla Hadjira Berredjem Malika Berredjem Malika Ibrahim‐Oualid Assia Allaoui Marc Lecouvey Nour‐Eddine Aouf 《Journal of heterocyclic chemistry》2013,50(6):1328-1332
A new series of chiral 5‐substituted bis‐oxazolidinones containing an acylsulfonamide moiety has been synthesized starting from chlorosulfonyl isocyanate, (l )‐ethyl lactate, and oxazolidin‐2‐ones. All the reactions were conducted at ambient temperature, and the N‐acylsulfonamide bis‐oxazolidin‐2‐ones were obtained with high yields within 2 h. Some of the newly synthesized compounds were evaluated in vitro against the virulent strain RH of Toxoplasma gondii and the human lymphocytes, and showed promising results. 相似文献
6.
7.
Zou Y Fahmi NE Vialas C Miller GM Hecht SM 《Journal of the American Chemical Society》2002,124(32):9476-9488
Metabolic inactivation of the antitumor antibiotic bleomycin is believed to be mediated exclusively via the action of bleomycin hydrolase, a cysteine proteinase that is widely distributed in nature. While the spectrum of antitumor activity exhibited by the bleomycins is believed to reflect the anatomical distribution of bleomycin hydrolase within the host, little has been done to characterize the product of the putative inactivation at a chemical or biochemical level. The present report describes the synthesis of deamidobleomycin demethyl A(2) (3) and deamido bleomycin A(2) (4), as well as the respective aglycones. These compounds were all accessible via the key intermediate N(alpha)-Boc-N(beta)-[1-amino-3(S)-(4-amino-6-carboxy-5-methylpyrimidin-2-yl)propion-3-yl]-(S)-beta-aminoalanine tert-butyl ester (16). Synthetic deamido bleomycin A(2) was shown to be identical to the product formed by treatment of bleomycin A(2) with human bleomycin hydrolase, as judged by reversed-phase HPLC analysis and (1)H NMR spectroscopy. Deamido bleomycin A(2) was found to retain significant DNA cleavage activity in DNA plasmid relaxation assays and had the same sequence selectivity of DNA cleavage as bleomycin A(2). The most significant alteration of function noted in this study was a reduction in the ability of deamido bleomycin A(2) to mediate double-strand DNA cleavage, relative to that produced by BLM A(2). 相似文献
8.
Liliane Bokobza Mostafa Rahmani Colette Belin Jean‐Luc Bruneel Nour‐Eddine El Bounia 《Journal of Polymer Science.Polymer Physics》2008,46(18):1939-1951
The reinforcement of a styrene‐butadiene rubber (SBR) by single fillers—carbon black (CB) or multiwall carbon nanotubes (MWNTs)—or by mixtures of CB and MWNTs, is investigated. The morphologies, mechanical and electrical properties of the composites, are analyzed. A significant improvement in the tensile properties is observed for samples containing a dual phase. Using atomic force (AFM) and transmission electron (TEM) microscopies, we demonstrate that the double loading improves the dispersion of the nanotubes in SBR. Electrical measurements show lower resistivity and a lower percolation threshhold for composites containing blends of fillers, which provides further evidence of better dispersion. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 46: 1939–1951, 2008 相似文献
9.
Kherroub Djamal Eddine Belbachir Mohammed Lamouri Saad 《Research on Chemical Intermediates》2017,43(10):5841-5856
Research on Chemical Intermediates - A new green technique to synthesize polysiloxane-type polymers is suggested based on use of chemically modified clay (Maghnite-H+) as heterogeneous,... 相似文献
10.
Nasser Eddine Mouhoub Abdelhamid Benhocine Hocine Belouadah 《Applied Mathematical Modelling》2011,35(9):4575-4588
A project is an enterprise consisting of several activities which are to be carried out in some specific order. The activities and the order in which they need to be carried out can be represented by a PERT network. The PERT technique is a traditional, well-known approach to the expert of project management. When networks are used, it often becomes necessary to draw dummy activities. Since the computation of project completion time is proportional to the number of arcs, including dummy arcs, it is desirable to draw a network with as few dummy activities as possible.In this paper, we propose a new method for constructing, for a given project scheduling problem, a PERT network having as small as possible the number of dummy arcs by using some results on line graphs. This algorithm deals with the existence of transitive arcs. The paper contains illustrative examples, proofs of some theoretical results as well as a comparative study with a similar algorithm known in the literature. Computational results showed the superiority of our algorithm. 相似文献