Microscopic band-mixing calculations in154,156Gd

A many-body microscopic band-mixing formulation of variation after projection of angular momentum and conservation of nucleon number is used to study the yrast band and first excitedK ^π =0⁺ band in the doubly even nuclei^154,156Gd. The computed energy spectra and the interband and intra-band B (E2) values are in good agreement with corresponding experimental data. Connection with the phenomenological model of Stephens and Simon is discussed, bringing out the role played by thei _13/2 neutron pair in the microscopic formalism.     

Effect of fluorine doping on highly transparent conductive spray deposited nanocrystalline tin oxide thin films

The undoped and fluorine doped thin films are synthesized by using cost-effective spray pyrolysis technique. The dependence of optical, structural and electrical properties of SnO₂ films, on the concentration of fluorine is reported. Optical absorption, X-ray diffraction, scanning electron microscope (SEM) and Hall effect studies have been performed on SnO₂:F (FTO) films coated on glass substrates. The film thickness varies from 800 to 1572 nm. X-ray diffraction pattern reveals the presence of cassiterite structure with (2 0 0) preferential orientation for FTO films. The crystallite size varies from 35 to 66 nm. SEM and AFM study reveals the surface of FTO to be made of nanocrystalline particles. The electrical study reveals that the films are degenerate and exhibit n-type electrical conductivity. The 20 wt% F doped film has a minimum resistivity of 3.8 × 10⁻⁴ Ω cm, carrier density of 24.9 × 10²⁰ cm⁻³ and mobility of 6.59 cm² V⁻¹ s⁻¹. The sprayed FTO film having minimum resistance of 3.42 Ω/cm², highest figure of merit of 6.18 × 10⁻² Ω⁻¹ at 550 nm and 96% IR reflectivity suggest, these films are useful as conducting layers in electrochromic and photovoltaic devices and also as the passive counter electrode.     

Heuristic and meta-heuristic approaches for multi-period shelf-space optimization: the case of motion picture retailing

The retail industry is in a highly competitive situation currently. The success of the industry depends upon the efficient allocation of products in the shelf space. Several previous authors have developed mathematical models for optimal shelf-space allocation. We extend the prior research in the direction of the multi-period problem and introduce more realistic characteristics, such as product demand perishability, pricing contract and cross-elasticity. The new characteristics help us address the case of the real-life movie allocation problem in multiplexes. We formulate a linear integer programming model to represent the problem. The proposed model shows a potential benefit of at least 11% increase in revenue for a multiplex theatre situation as compared to the existing methods. We also propose two greedy heuristics and a genetic algorithm to solve the same problem. A computational study shows that the genetic algorithm performs better than the existing method.     

Hydrodynamic cavitation for sonochemical effects

A comparative study of hydrodynamic and acoustic cavitation has been made on the basis of numerical solutions of the Rayleigh-Plesset equation. The bubble/cavity behaviour has been studied under both acoustic and hydrodynamic cavitation conditions. The effect of varying pressure fields on the collapse of the cavity (sinusoidal for acoustic and linear for hydrodynamic) and also on the latter's dynamic behaviour has been studied. The variations of parameters such as initial cavity size, intensity of the acoustic field and irradiation frequency in the case of acoustic cavitation, and initial cavity size, final recovery pressure and time for pressure recovery in the case of hydrodynamic cavitation, have been found to have significant effects on cavity/bubble dynamics. The simulations reveal that the bubble/cavity collapsing behaviour in the case of hydrodynamic cavitation is accompanied by a large number of pressure pulses of relatively smaller magnitude, compared with just one or two pulses under acoustic cavitation. It has been shown that hydrodynamic cavitation offers greater control over operating parameters and the resultant cavitation intensity. Finally, a brief summary of the experimental results on the oxidation of aqueous KI solution with a hydrodynamic cavitation set-up is given which supports the conclusion of this numerical study. The methodology presented allows one to manipulate and optimise of specific process, either physical or chemical.     

Laundry process intensification by ultrasound

In domestic textile laundering processes, mass transfer and mass transport are often rate limiting. Therefore, these processes require a long processing time, large amounts of water and chemicals, and they are energy consuming. In most of these processes, diffusion and convection in the inter-yarn and intra-yarn pores of the fabric are limiting mass transport mechanisms. Intensification of mass transport, preferentially in the intra-yarn pores, is the key in the improvement of the efficiency of wet textile processes. Conventional methods of intensification of mass transport (e.g. operation at elevated temperatures) are not always feasible due to the undesired side effects such as fabric damage. Increasing the flow rate does not deliver the desired effect due to the multi-porous complex structure of textile materials. Van der Donck et al. [Tenside Surf. Det. 35 (1998) 119; 36 (1999) 222] reported that the deformation of yarns by placing a fabric in a pulsating flow or repeated mechanical elongation of the yarns improved mass transport. However, the additional mass transport caused by deformation is limited in practice. Power ultrasound is a promising technique to accelerate mass transport in textile materials. Several papers appeared in this field, which report an improvement in energy efficiency and processing time of the wet textile processes in the presence of ultrasound. In this paper, the different time and length scales are discussed in the intensification of the mass transport in laundry processes in the presence of ultrasound and compared with more conventional processes. It has been concluded that the characteristic mass transport rates in textiles can be increased by a factor of 6 applying ultrasound.     

Electrical transport and magnetic ordering in R 2Ti3Ge4 (R=Dy, Ho and Er) compounds

New R ₂Ti₃Ge₄ (R=Dy, Ho and Er) intermetallic compounds have been synthesized and characterized by X-ray diffraction and low temperature ac magnetic susceptibility, electrical resistivity and thermoelectric power measurements were carried out. The compounds crystallize in the parent, Sm₅Ge₄-type orthorhombic structure (space group Pnma) and lanthanide contraction is observed as one moves along the rare-earth series. The changeover from paramagnetic to antiferromagnetic phase happens at low temperatures and the ordering temperature scales with the de Gennes factor. The electrical resistivity is metallic with a negative curvature above 100 K. Thermopower displays a weak maximum at temperatures less than 50 K signifying the possible phonon and magnon drag effects.     

Green route fast synthesis and characterization of chemical bath deposited nanocrystalline ZnS buffer layers

Zinc sulphide (ZnS) thin films are deposited using chemical bath deposition method on the glass substrates in an aqueous alkaline reaction bath of zinc acetate and thiourea along with non-toxic complexing agent tri-sodium citrate at 95 °C. The results show noteworthy improvement in the growth rate of the deposited ZnS thin films and thickness of the film increases with the deposition time. From X-ray diffraction patterns, it is found that the ZnS thin films exhibit hexagonal polycrystalline phase reflecting from (101) and (0016) planes. The high resolution transmission electron microscopy studies confirmed the formation of hexagonal phase from the d-value calculation which was 0.3108 nm. X-ray photoelectron spectroscopy reveals that the Zn–S bonding energy is at 1022.5 and 162.1 eV for Zn 2p_3/2 and S 2p_1/2 states, respectively. Field emission scanning electron microscopy study shows that deposited thin films are highly uniform, with thin thickness and completely free from large ZnS clusters which usually form in aqueous solutions. Atomic force microscopy investigates that root mean square values of the ZnS thin films are from 3 to 4.5 nm and all the films are morphologically smooth. Energy dispersive spectroscopy shows that the ZnS thin films are relatively stoichiometric having Zn:S atomic ratio of 55:45. It is shown by ultraviolet–visible spectroscopy that ～90% transmittance and ～10% absorbance for the ZnS films in the visible region, which is significantly higher than that reported elsewhere and the band gap energy of the ZnS films is found to be 3.76, 3.74, and 3.71 eV, respectively.     

Simplistic surface active agents mediated morphological tweaking of CdS thin films for photoelectrochemical solar cell performance

This study reports on the formation of cadmium sulfide (CdS) nanostructures with controlled morphology synthesized via a simple chemical route in surface active agent environment. The effect of organic surface active agents (surfactants) as sodium dodecyl sulfate (SDS), polyethylene glycol (PEG) and cetyltrimethylammonium bromide (CTAB) on structural, morphological, optical and photoelectrochemical properties of CdS thin films have been studied. Our results reveal that the organic surfactants play key roles in tweaking the surface morphology. A compact spongy ball like morphology was observed for the CdS samples grown without organic surfactants. The cauliflower's with nanopetals from the CTAB, whereas crowded star fish like morphology is observed in PEG-mediated growth. Water hyacinth like morphology is tweaked using SDS. Considering the importance of these nanostructures, the growth mechanism has been discussed in details. Additionally, the samples are photoelectrochemically (PEC) active and having a compact surface with a nanoporous structure twig helps in improved photoelectrochemical performance compared to that of CdS deposits from surfactant free solution. This is a simplistic way to tune the morphology using surfactants, which can be applied to other energy conversion applications.