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GLPC法测定二元系中挥发组分有限浓度时的活度系数曾为Chueh和Ziegler、Conder和Purnell、Chch和Parcher等所探讨,但因后续工作太少,迄今未能成熟,将这一方法得到肯定,对于研究二元溶液的热力学是有意义的,经过反复比较,我们决定对Chueh和Ziegler的方法作进一步探讨。 相似文献
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掺杂功能磺酸的导电聚苯胺的合成及其红外光谱研究 总被引:8,自引:0,他引:8
合成了参杂对甲苯磺酸(TSA),十二烷基苯磺酸(DBSA),樟脑磺酸(CSA)和磺基水杨酸(SSA)的导电聚苯胺要品:Dpan/TS,Dpan/DBSA,Dpan/CSA,Dpan/SSA,并对这些样品进行了表征,研究了它们的红外光谱特性。 相似文献
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Precursors were synthesized with hydrazine oxalic acid and tungstic acid in different ratios and a series of tungsten oxides, O/W ratios from 2.90 to 2.30,were obtained by thermal decomposition from the precursors under nitrogen atmosphere at 640~760℃. This kind of tungsten oxides were found to belong to mixed valence compounds which have some special electrical properties. The experimental result indicated that the electrical conductivity of this tungsten oxide has a close relation with its O/W ratio and reach the maximum at WO2.50. Seclecting WO2.50 as an example, its conductivity was measured at different temperatures from -197 ℃ to -2.5 ℃ and it was found that the mixed valence tungsten oxide as conductor belongs to the class of metal ones. Owing to their relatively high electrical conductivity and stability in air, mixed valence tungsten oxide shows some potential use in polymer products as additives. 相似文献
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