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1 INTRODUCTION Polyoxometalates (POMs) have been attracting extensive interest of many chemists in solid-state materials chemistry owning to the various structures and great potential applications in catalysis, medi- cine, photo-electricity and magnetism[1~9]. Over the past decades, lots of novel POMs have been pre- pared by hydrothermal synthesis, such as discrete structure[10], one-dimensional chain-like structure[11, 12] and higher dimensional architecture[13~18]. However, in these… 相似文献
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二茂铁单甲醛和联苯胺反应制备了标题化合物,用元素分析,1H NMR和X射线单晶衍射对其结构进行了表征.结构解析表明,标题化合物属于单斜晶系,P21/n空间群,晶胞参数为:a=0.590 6(2)nm,b=1.116 8(3)nm,c=1.963 9(5)nm,β=92.903(5)°,V=1.293 9(6)nm3,Z=2,Dc=1.479 Mg/m3,μ=1.148mm-1,F(000)=596,R1=0.060 2,wR2=0.126 6.该化合物由两个茂铁彼此通过Sch iff碱桥联,为中心对称,分子内Fe…Fe距离为1.7nm.电化学测量表明,两个茂铁之间的相互作用很弱. 相似文献
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1 引 言氧氟沙星是一种新型广谱抗菌素类药物,国家卫生部部颁标准中其含量的测定方法是高效液相色谱法。本文以氧氟沙星与四苯硼酸根形成的缔合物为电活性物质制备了氧氟沙星PVC膜涂层玻璃电极,同时对它的性能进行了研究。该电极制作方法简单,响应迅速,用于氧氟沙星注射液和口服胶囊的测定,结果与高效液相色谱法一致。2 实验部分2.1 仪器与试剂 PXSJ-216型离子活度计(上海雷磁分析仪器厂);pHSP1型pH计(上海大中仪器厂)。聚氯乙烯粉(PVC,化学纯),邻苯二甲酸二丁酯(DBP,化学纯),氧氟沙星(上海昆山制药厂,纯度为100.00%)… 相似文献
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Pulse Wavelength Scan of Room-Temperature Mid-Infrared Distributed Feedback Quantum Cascade Lasers for N2O Gas Detection 下载免费PDF全文
The tunable diode laser absorption spectroscopy under a pulse wavelength scan scheme is adapted to home-made room-temperature mid-infrared distributed feedback quantum cascade lasers; and identification of N2O spectral fingerprint is demonstrated experimentally. By driving the laser at 800ns pulse duration, a wave number tuning of about 1.6cm^-1 is produced, which make both 1289.04cm^-1 and 1289.86cm^-1 absorption fingerprints of N2O gas to be definitely assigned. The measured relative absorption intensity is consistent with the HITRAN data precisely. 相似文献
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We investigate the self-heating effect of mid-infrared quantum cascade lasers by using a direct-based pulse injecting current and spectroscopy method. Based on the characterization system, the thermal characteristics of gas source MBE grown 8.4μm InP-based GalnAs/AIInAs DFB-QCLs are evaluated. The method and characterization system are also useful in evaluating the thermal characteristics of other types of mid-infrared diode lasers. 相似文献
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利用Na2MoO4·2H2O,MoO3,乙二胺,和H2O通过水热合成法合成了一维锯齿状化合物[(en)2(Mo6O20H4)]n.晶体解析表明,该化合物属于单斜晶系,P21/n空间群,a=0.80680(16)nm,b=1.4371(3)nm,c=0.88874(18)nm,β=97.89(3)°,V=1.0207(4)nm3,Z=2,Dc=3.305Mg·m-3,μ=3.681mm-1,F(000)=960.该化合物结构单元由二个游离的乙二胺分子和一个阴离子Mo6O4-20阴离子中,六20构成.在Mo6O4-个钼原子和八个相邻的氧原子构成两个八员环,在每个八员环的两侧分别存在着一个与三个钼原子相连的桥氧. 相似文献