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Nano-sphere-like Eu^3 activated lanthanum oxysulfide phosphor was first synthesized directly by solvothermal method. The phosphor was characterized by XRD, TEM and PL. Photoluminescence spectra indicate that this phosphor showed three typical transitions of Eu^3 (^5Do→^7F^1,^5D0→^7F2,^5D0→^7F4). In comparison with those prepared by high temperature solid state method, photoluminescence spectrum of Eu^3 (^5D0→^7F2)-doped nano-La2O2S:Eu^3 phosphor became broader. And the reaction mechanism was also mentioned in this paper. 相似文献
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Trapping effects in CdSiO3:In^3+ long afterglow phosphor based on photoluminescence (PL) and thermoluminescence (TL) curves are studied. The results of TL show that two intrinsic defects associated with peaks at 346 and 418 K appear in the undoped CdSiO3 phosphor; whereas only one strong cadmium vacancy VCd^11 defect associated with peak at 348 K appears in the Cd1-xInxSiO3 phosphor due to the chemical nonequivalent substitutions of Cd^2+ ions by In^3+ ions. This chemical nonequivalent substitution of In^3+ ions into the CdSiO3 host produced the highly dense cadmium vacancy VCd^11 trap level at 348 K, which resulted in the origin of the long afterglow phenomenon. The findings has enlarged the family of non-rare-earth doped long afterglow phosphors available, and offers a promising approach for searching long afterglow phosphor. 相似文献
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溶剂热合成纳米球状La2O2S:Eu3+荧光粉 总被引:5,自引:0,他引:5
Eu3+离子激活的硫氧化物荧光粉是目前国内外广泛使用的CRT红色发光材料[1]. 它具有色纯度高、色彩不失真、亮度-电流饱和度特性好和稳定性高等特性, 已成为CRT不可替代的红色荧光粉. 此外, 掺杂或不掺杂Eu3+的硫氧化镧是还原SO2有害气体为S单质的优良催化剂[2,3]. 近年来兴起的纳米材料是有可能在本世纪得到广泛应用的材料; 掺杂稀土离子的硫氧化物有望应用于各种显示技术及催化剂中. 最近, 吴长峰等[4]在Y2O3∶Eu3+纳米管中观察到发射峰展宽等特性. 因而, 研究Eu3+离子激活的硫氧化镧纳米荧光粉是很有意义的. 相似文献
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