利用正己烷制备负载型碳化钼催化剂及其加氢脱硫活性

 利用具有较长碳链的正己烷作为原料对氧化钼进行程序升温碳化制备碳化钼. X射线衍射、X射线光电子能谱表征和BET比表面积测定以及噻吩的加氢脱硫活性评价结果表明,正己烷作为碳化原料在600 ℃左右可对担载的氧化钼进行碳化,正己烷的使用不仅可以降低碳化所需的温度,还能在碳化过程中起到一定的改善碳化钼分散度的作用.     

Weak decays of heavy baryons in the light-front approach

In this work, we analyse semi-leptonic and non-leptonic weak decays of the heavy baryons: Λ_b,Ξ_b,?_b and Λ_c,Ξ_c,?_c. For non-leptonic decay modes, we study only the factorizable channels induced by the external Wemission. The two spectator quarks in the baryonic transitions are treated as a diquark and form factors are calculated in the light-front approach. Using the results for form factors, we also calculate some corresponding semi-leptonic and non-leptonic decay widths. We find that our results are comparable with the available experimental data and other theoretical predictions. Decay branching fractions for many channels are found to reach the level 10~(-3)~10~(-2),which is promising for discovery in future measurements at BESIII, LHCb and Belle II. The SU(3) symmetry in semi-leptonic decays is examined and sources of symmetry breaking are discussed.     

球形SiO2-Al2O3的制备、结构和性能

将Na2SiO3·9H2O 溶液通过强酸性阳离子树脂进行离子交换得到酸性硅溶胶,再将硅溶胶与铝溶胶及六次甲基四胺混合后采用油柱成型法制备了球形SiO2-Al2O3复合氧化物. 通过XRD、BET 及TPD等手段对样品进行测试和表征, 结果表明, 600 ℃焙烧得到的SiO2-Al2O3中SiO2以无定型形式存在, 其比表面、孔容与表面酸性随SiO2含量的增加而提高, 孔径、堆密度随SiO2含量的提高而减小, 压碎强度基本保持不变.     

高分子辐射交联技术及研究进展

介绍了辐射交联反应的机理;讨论了影响辐射交联反应的因素及有关动力学问题;报道了辐射交联对高分子材料性能的影响及应用技术进展;比较了辐射交联与过氧化物交联的技术经济差异。     

加氢脱硫催化剂与反应机理的研究进展

本文综述了加氢脱硫反应机理、加氢脱硫催化剂的研究与开发的最新进展.对常用的模型化合物的加氢脱硫机理及其影响因素、催化剂的结构、活性相与助剂、载体以及添加剂的性互作用与影响进行了讨论.     

Study of the s → dv■ rare hyperon decays in the Standard Model and new physics

FCNC processes offer important tools to test the Standard Model(SM)and to search for possible new physics.In this work,we investigate the s→dvv rare hyperon decays in SM and beyond.We find that in SM the branching ratios for these rare hyperon decays range from 10~(-14) to 10~(-11).When all the errors in the form factors are included,we find that the final branching ratios for most decay modes have an uncertainty of about 5% to 10%.After taking into account the contribution from new physics,the generalized SUSY extension of SM and the minimal 331 model,the decay widths for these channels can be enhanced by a factor of 2～7.     

Discovery potentials of doubly charmed baryons

The existence of doubly heavy flavor baryons has not been well established experimentally so far. In this Letter we systematically investigate the weak decays of the doubly charmed baryons, Ξ~(++)_(cc)and Ξ~+_(cc), which should be helpful for experimental searches for these particles. The long-distance contributions are first studied in the doubly heavy baryon decays, and found to be significantly enhanced. Comparing all the processes, Ξ~(++)_(cc)→Λ~+_cK~-π~+π~+andΞ~+_cπ~+ are the most favorable decay modes for experiments to search for doubly heavy baryons.