MY准则解析复合型裂尖塑性区

首次以MY(平均屈服)准则对I-II复合型裂纹在小范围屈服下的裂尖塑性区进行了分析,分别获得了平面应力和平面应变状态下塑性区尺寸的解析解。这两解表明,塑性区尺寸是材料屈服强度、应力强度因子、极角θ的函数。与Tresca准则、TSS屈服准则获得的解以及Mises解比较表明:Tresca准则预测塑性区上限,TSS屈服准则预测塑性区下限,MY准则预测的塑性区居于Tresca与TSS塑性区之间,逼近Mises解。另外,文中讨论了平面应力和平面应变状态下裂纹尖端的开裂问题,结果表明:当裂纹角β=π4时,平面应力状态下裂纹沿0-θ=0.2952π方向开裂;平面应变状态下裂纹沿0-θ=0.3188π方向开裂。     

活性炭负载钌基氨合成催化剂的制备和催化活性

A series of active carbon supported ruthenium based catalysts, promoted by alkali and alkaline earth nitrate, are prepared by impregnation method and with RuCl 3·3H 2O as precursor. Effects of support, promoter and preparation conditions on catalytic activity are discussed. The catalytic activity is evaluated with a fixed bed micro reactor at lower pressure. The results show that the impregnation sequence affects the catalytic activity obviously. Ba Ru K/C is the preferred impregnation sequence. And effects of nature, producing area and pre treatment of the support on catalytic activity are also examined. Catalytic activity increases with the amount of Ru deposited on the support, it attains maximum when Ru loading is 8%. Optimal molar ratio of promoter to Ru is 10.     

3D打印激光制备多孔镍合金组织和力学性能研究

采用3D打印激光熔化技术制备了多孔镍基合金,并对其显微组织构成和压缩力学性能进行了分析。研究结果表明,采用3D打印激光熔化技术制备的多孔镍合金,孔隙率为14.68%~18.97%、抗压强度为461~535 MPa,其微观组织主要呈现γ-Ni枝晶,压缩断口为撕裂式枝晶断裂。     

激光烧结石墨烯铜复合材料温度场有限元模拟

在激光烧结石墨烯增强铜基复合材料的过程中，了解瞬时温度场分布对优化工艺参数、控制烧结质量有重要作用。建立了激光烧结预涂在42CrMo基板上的石墨烯铜的混合粉末的有限元模型。研究了激光烧结过程温度场分布，熔池的几何参数以及烧结层与基体的冶金结合宽度。为了验证模拟结果，使用与模拟相同的参数进行了单道激光烧结的实验。研究表明，热传导、热辐射和相变潜热在激光烧结过程的温度场分布中起重要作用。实验结果与模拟结果较为一致。所以可以依据模拟结果预测实验的温度场分布和熔池几何参数，同时也可以据此优化激光烧结参数。     

激光熔敷镍石墨烯立方氮化硼涂层的耐磨性能

在AISI 4140基体上采用预置材料激光熔敷的方法制备了镍石墨烯立方氮化硼(Ni-Graphene-CBN)复合材料涂层。X射线衍射(XRD)和Raman测试证明了石墨烯和CBN存在于所制备的涂层材料中。扫描电镜(SEM)图片给出了所制备的复合材料涂层的表面和断面形貌。进行了复合材料涂层的纳米机械性能和耐磨性的测试。测试结果表明:随着CBN含量的增加,复合涂层的硬度及弹性模量相应提高,分别由4.3 GPa提高到6.2 GPa和101 GPa提高到140 GPa; 同时其耐磨性也有明显改善，6% CBN含量的涂层摩擦系数由基体材料的0.2降低到0.15，最大磨损量降到基体磨损量的一半。     

EPR character of gadolinium complexes with noncyclic polyether Schiff bases and its solvent effects

EPR characters of three new gadolinium complexes with noncydic polyether Schiff bases in powder or organic solvents, including various oxyethylene chain lengths and different substituting groups in ligands, are investigated respectively. Some regularities are summed up. The difference of EPR character in various solvents, particularly at different temperatures, has been examined. The 'single peak effect' due to THF solvent at low temperature is observed for the first time. This phenomenon is explicated.     

热连轧粗轧调宽轧制过程边角部金属流动三维数值模拟

以梅山钢铁股份有限公司热轧机组的粗轧板坯边部出现“黑线”为背景,对孔型立辊的5道次可逆立-平轧制过程进行了数值模拟.模拟结果表明：孔型立辊轧制能更有效地纠正双鼓变形,避免产生边部夹层;轧件的边角部金属在轧制过程中逐渐流动到轧件的上下表面;在相同轧制工艺条件下,随着孔型内倒角半径的增加翻平量逐渐增大;轧制过程中,低温、高应力应变状态的金属在轧件边部的累积最终可能导致轧件边部沿长度方向产生“黑线”缺陷;合理地设计立辊的形状和优化立轧压下制度可以避免边部夹层的产生,并减少“黑线”缺陷甚至消除该缺陷. 关键词： 热连轧 数值模拟 “黑线”缺陷