Adsorption of water molecules in slit pores

We report molecular dynamics (MD) simulations on the adsorption of water in attractive and repulsive slit pores, where the slit and a bulk region are in contact with each other. Water structure, surface force and adsorption behavior are investigated as a function of the overall density in the bulk region. The gas–liquid transition in both types of pores occurs at similar densities of the bulk region.     

Proton-neutron interaction at N≅Z — First observation of the Tz=1 nucleus 46 94 Pd48 in-beam

The neutron deficient nucleus⁹⁴Pd was identified and studied for the first time by in-beam spectroscopy. An I=(14⁺) isomer with t_1/2=0.8 (2) s was observed in a recoil catcher setup inside the multi-detector -array OSIRIS. Filter detectors for neutrons and charged particles were used to identify the (2p2n) exit channel of the reaction⁵⁸Ni+⁴⁰Ca, populated with only 0.06% of the total evaporation residue cross section. The structure of the isomer is discussed within the frame work of shell model calculations in the (p_1/2,g_9/2) model space with emphasis on the g ₉ ^2/2 T=0, I=1,9 pairing two-body matrix elements.Communicated by: D. Schwalm     

Isomeric states in180Os

Two new isomers have been observed in¹⁸⁰Os. A high-K isomer withI, K ≧20 and a half-life ofT _1/2=12+4 ns have been established. It deexcites via two transitions into the 18⁺ level of the yrare band indicating an unusually smallK-hindrance factor. Evidence for an isomer withI, K>16 and a half-life ofT _1/2=41±10 ns was found. A half-life of 17±3 ns was measured for the previously known 7^? state at 1862 keV. The decay scheme of the previously known 7^? isomer at 1928 keV has been extended and a revised version is presented.     

Lattice strain in garnet single crystals caused by high-energy heavy ion irradiation

The effect of high-energy heavy ion bombardment on the lattice parameter of single crystal garnets is investigated. Lattice expansion normal to the surface corresponding to lateral compressive strain is observed via x-ray reflection topography and rocking curve analysis using a double-crystal diffractometer. Studied are (111) garnet wafers of differing composition and epitaxial ferrimagnetic iron garnet films on pure and MgZr-substituted (111) Gd₃Ga₅O₁₂ substrates. Using¹³²Xe and²⁰⁸Pb ions of 1.4MeV/nucleon specific energy, the lattice expansion increases approximately linearly with dose over several orders of magnitude. The specific lattice parameter change is approximately 10⁻¹⁴ per ion per cm² for¹³²Xe ions. A triple epitaxial film is used to obtain strain depth profiles     

Transfer measurements for the Ti+Ni systems at near barrier energies

Large enhancements have been observed in the sub-barrier fusion cross sections for Ti+Ni systems in our previous studies. Coupled channel calculations incorporating couplings to 2⁺ and 3⁻ states failed to explain these enhancements completely. A possibilty of transfer channels contributing to the residual enhancements had been suggested. In order to investigate the role of relevant transfer channels, measurements of one- and two-nucleon transfer were carried out for ^46,48Ti+⁶¹Ni systems. The present paper gives the results of these studies.     

p-Nitrophenol permeability and temperature characteristics of an acryloyl-L-proline methyl ester-based porous gel membrane

Thermoresponsive porous gel membranes were synthesized by a simultaneously occurring process consisting of radiation-induced polymerization and crosslinking in aqueous solutions at various concentrations of acryloyl-L -proline methyl ester(A-ProOMe) without a crosslinker. Permeation of p-nitrophenol (PNP) through a thermoresponsive porous gel membrane obtained at a monomer concentration of 80% (w/w) drastically reduced around 14°C, the lower critical solution temperature (LCST) of linear poly(A-ProOMe) in water, from 0.60 × 10⁻³ cm/min at 10°C to no permeation at 18°C, accompanied by changes in both size and shape of pores associated with gel shrinkage. Moreover, it was found that porous gel membranes with a porosity of approximately 60% had a greater PNP permeability constant through porous gel membranes with mutually connected pores obtained at a monomer concentration of 50% (w/w) than individually supported pores obtained at a monomer concentration of 70% (w/w). © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1495–1500, 1998     

High-spin states in neutron-rich Dy isotopes populated in deep-inelastic reactions

High-spin states in neutron-rich Dy isotopes, populated in deep-inelastic processes produced by the interaction of 234 MeV ³⁷Cl ions with a ¹⁶⁰Gd target, have been studied using the highly sensitive EUROBALL IV gamma-ray detector array. The previously known level schemes for ^{159,160,161,162}Dy have been extended to significantly higher spin ( ? 30?) and the i _13/2 band crossing in ¹⁵⁹Dy has been observed for the first time. The experimental results are discussed within the framework of cranked shell model and projected shell model calculations with particular reference to the observed delayed band crossing in ¹⁶²Dy. Received: 20 October 2000 / Accepted: 16 January 2001