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V. V. Istratov V. T. Tarasyuk V. A. Vasnev N. A. Borisova 《Polymer Science Series B》2013,55(3-4):218-225
A series of new branched block copolymers was synthesized and investigated, and their physicochemical and surface properties were determined. It was shown that all of the prepared block copolymers demonstrate well-defined surface activity dependent on the ratio of hydrophilic and lipophilic fragments of macromolecule as well as on the copolymer structure. The resulting copolymers were used as surfactants to obtain microemulsions and microcapsules. It was found that the size of emulsion drops stabilized by branched copolymers increased more slowly than that of drops stabilized by linear copolymers. During the preparation of microcapsules through the use of branched copolymers as surfactants, unlike that through the use of linear copolymer surfactants, a high effectiveness of encapsulation and a smaller particle size were observed. 相似文献
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In this study, new biodegradable and biocompatible amphiphilic polymers were obtained by modifying the peripheral hydroxyl groups of branched polyethers and polyesters with organosilicon substituents. The structures of the synthesized polymers were confirmed by NMR and GPC. Organosilicon moieties of the polymers were formed by silatranes and trimethylsilyl blocks and displayed hydrophilic and hydrophobic properties, respectively. The effect of the ratio of hydrophilic to hydrophobic organosilicon structures on the surface activity and biological activity of macromolecules was studied, together with the effect on these activities of the macromolecules’ molecular weight and chemical structure. In particular, the critical micelle concentrations were determined, the effect of the structure of the polymers on their wetting with aqueous solutions on glass and parafilm was described, and the aggregation stability of emulsions was studied. Finally, the effect of the polymer structures on their antifungal activity and seed germination stimulation was examined. 相似文献
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AA Yan LI Kai CAO ZhongHua & HU WenRui Key Laboratory of Microgravity 《中国科学:物理学 力学 天文学(英文版)》2011,(2)
The dependency of the critical Marangoni number on the geometrical aspect ratio of the floating half zone is essential to predict the onset of oscillatory thermocapillary convection.The experimental studies in the microgravity conditions on floating half zones of several centimeters in diameter have predicted that the critical Marangoni number increases with the increasing aspect ratio,and the terrestrial experimental studies have predicted the contradictory conclusion for floating half zones of several mil... 相似文献
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Non-Gravitational Effects with Density-Matching in Evaluating the Influence of Sedimentation on Colloidal Coagulation 下载免费PDF全文
The method of density matching between the solid and liquid phases is often adopted to effectively eliminate the effect of sedimentation of suspensions in studies on dynamic behaviour of a colloidal system. However, the associated changes in the solvent composition may bring side effects to the properties investigated and therefore might lead to a faulty conclusion if the relevant correction is not made. To illustrate the importance of this side effect, we present an example of the sedimentation influence on the coagulation rate of suspensions of 2μm (diameter) polystyrene. The liquid mixtures, in the proper proportions of water (H2O), deuterium oxide (D2O) and methanol (MeOH) as the liquid phase, density-matched and unmatched experiments are performed. Besides the influence of viscosity, the presence of methanol in solvent media, used to enhance the sedimentation effect, causes significant changes (reduction) in rapid coagulation rates compared to that in pure water. Without the relevant corrections for those non-gravitational factors it seems that gravitational sedimentation would retard the coagulation. The magnitude of the contribution from the non-gravitational factor is quantitatively determined, making the relevant correction possible. After necessary the influence of the sedimentation on coagulation rates at corrections for all factors, our experiments show that the initial stage of the coagulation is not observable. 相似文献
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M. N. Gerke A. V. Istratov D. N. Bukharov O. A. Novikova I. O. Skryabin S. M. Arakelian 《Bulletin of the Russian Academy of Sciences: Physics》2017,81(12):1387-1390
The surface resistance of bimetallic granular films prepared by means of laser-induced deposition is studied. The possibility of modeling their conductivity is demonstrated, depending on their morphological properties. 相似文献
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We discuss the notion of spin squeezing considering two mutually exclusive classes of spin-s states, namely, oriented and non-oriented states. Our analysis shows that the oriented states are not squeezed while non-oriented
states exhibit squeezing. We also present a new scheme for construction of spin-s states using 2s spinors oriented along different axes. Taking the case of s=1, we show that the ‘non-oriented’ nature and hence squeezing arise from the intrinsic quantum correlations that exist among
the spinors in the coupled state. 相似文献