Distribution of a local magnetic field in superconductors with an uncorrelated random lattice of abrikosov vortices

The distribution of a local magnetic field near the surface of a uniaxial anisotropic type-II superconductor is determined in the framework of the London model in the case when the Abrikosov vortices are randomly distributed in the superconductor. The distribution of a local magnetic field is obtained as a function of the distance from the surface of the superconductor. It is demonstrated that the shape of the distribution of the local magnetic field near the surface differs substantially from that in the bulk of the superconductor. This difference should be taken into account in interpreting experimental data on the local magnetic field in the surface region of the superconductor and in thin superconducting films (with a thickness of less than or equal to λ, where λ is the depth of penetration of the magnetic field into the superconductor). It is shown that, as in the case of a regular lattice of vortices, the value of λ can be determined from observations of the distribution of the local magnetic field in type-II superconductors with an uncorrelated random lattice of vortices.     

Crystal and molecular structure of bis(2-isotropyliminomethinylphenyl) telluride

Scientific-Research Institute of Physical and Organic Chemistry, Rostov State University. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 3, pp. 104–106, May–June, 1991.     

Molecular and crystal structure of 2-(N-benzyl-N-phenylhydrazinoethylidene)-3-(2H)-benzo[b]-thiophenone

X-ray structural analysis was used to determine the molecular and crystal structure of 2-(N-benzyl-N-phenylhydrazinoethylidene)-3-(2H)-benzo[b]thiophenone. The crystals are monoclinic, the space group isC2/c,a=16.022(6),b=11.202(3),c=22.111(4) Å, =81.08(3)°, and andZ=8. It was shown that the ability of hydrazones of a similar class to exhibit photochromic properties is a function of the steric stresses in the molecules and their confirmation.Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 12, pp. 2805–2809, December, 1992.     

1,3-dioxenium cations: Synthesis and properties

The features and prospects of the new reaction of 1,3-keto-enols, ketones, and acids yielding 1,3-dioxenium salts were investigated. The results of studies of the structure, topomerization, and transformations of 1,3-dioxenium cations — a new family of stable heterocyclic cations of the allyl type — were generalized.     

Tetra- and hexaatomic cyclic clusters of main-group elements (XY)2 and (XY)3: an ab initio and density functional study

The electronic and molecular structure of planar (cyclic and linear) tetra- and hexaatomic clusters (XY) _n (XY = CC, BN, BeO, LiF; n = 2, 3) was studied using the ab initio CCD(full)/6-311+G** method and density functional approach (B3LYP/6-311+G**). The stability of cyclic clusters C₆, B₃N₃, and Be₃O₃ with D_3h symmetry is mainly determined by the aromaticity of their -electron systems.     

Three-dimensional structure of 3-acylindoles

On the basis of a comparison of the experimental dipole moments with the calculated values, as well as data from the UV, IR, and PMR spectra, it is shown that 3-acylindoles exist in the form of equilibrium mixtures of the planar S-cis and S-trans conformers with preponderance of the latter.DeceasedTranslated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1647–1652, December, 1982.     

Phenylmercury derivatives of aminomethylene- and hydroxymethylene-substituted 1-methyloxindoles, 1-indanones,and 1,3-indanediones

A number of phenylmercury derivatives of 3-hydroxymethylene- and 3-aminomethylene-substituted 1-methyloxindoles, 1-indanones, and 1,3-indanediones were synthesized. It is shown that the preferred tautomeric structures of the potentially metallotropic and prototropic hydroxymethylene keto (hydroxy vinyl aldehyde) derivatives of the indicated compounds and 3-hydroxybenzo[b]-2-formylthiophene coincide precisely. An aminomethylene structure with an N-H bond is realized for the phenylmercury derivatives of the corresponding azomethines in all cases.Communication 28 from the series Benzenoid-Quinoid Tautomerism of Azomethines and Their Structural Analogs. See [1] for communication 27.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 65–68, January, 1979.