P-polarized nonlinear surface polaritons near the surface of a saturable self-defocusing medium: Threshold case

We have obtained the solution of the stationary problem for P-polarized nonlinear surface polaritons (NLSP) near the interface of two media, one of which is optically linear and the other having an optical nonlinearity with saturation and a dielectric function of the form: =_xx=_zz=₀+a|E|²/(1+b|E|²), where E is the amplitude of the electric field. On this basis the NLSP energy and propagation properties, the polarization structure and the localization depth of the NLSP field as well as the physically allowed region in the parameter space have been investigated for the case in which the parameter ₀ is positive, b is non-negative, and a and ₁ are negative (₁ is the dielectric function of the linear medium); ₀>|₁|.     

Anisotropy resolved multidimensional emission spectroscopy (ARMES): A new tool for protein analysis

Structural analysis of proteins using the emission of intrinsic fluorophores is complicated by spectral overlap. Anisotropy resolved multidimensional emission spectroscopy (ARMES) overcame the overlap problem by the use of anisotropy, with chemometric analysis, to better resolve emission from different fluorophores. Total synchronous fluorescence scan (TSFS) provided information about all the fluorophores that contributed to emission while anisotropy provided information about the environment of each fluorophore. Here the utility of ARMES was demonstrated via study of the chemical and thermal denaturation of human serum albumin (HSA).     

A fluorescence anisotropy method for measuring protein concentration in complex cell culture media

The rapid, quantitative analysis of the complex cell culture media used in biopharmaceutical manufacturing is of critical importance. Requirements for cell culture media composition profiling, or changes in specific analyte concentrations (e.g. amino acids in the media or product protein in the bioprocess broth) often necessitate the use of complicated analytical methods and extensive sample handling. Rapid spectroscopic methods like multi-dimensional fluorescence (MDF) spectroscopy have been successfully applied for the routine determination of compositional changes in cell culture media and bioprocess broths. Quantifying macromolecules in cell culture media is a specific challenge as there is a need to implement measurements rapidly on the prepared media. However, the use of standard fluorescence spectroscopy is complicated by the emission overlap from many media components. Here, we demonstrate how combining anisotropy measurements with standard total synchronous fluorescence spectroscopy (TSFS) provides a rapid, accurate quantitation method for cell culture media. Anisotropy provides emission resolution between large and small fluorophores while TSFS provides a robust measurement space. Model cell culture media was prepared using yeastolate (2.5 mg mL^–1) spiked with bovine serum albumin (0 to 5 mg mL^–1). Using this method, protein emission is clearly discriminated from background yeastolate emission, allowing for accurate bovine serum albumin (BSA) quantification over a 0.1 to 4.0 mg mL^–1range with a limit of detection (LOD) of 13.8 μg mL^–1.     

Influence of cation substitution on the magnetic properties of the FeCr2S4 ferrimagnet

The influence of cation substitution on the magnetic properties of single and polycrystals of FeCr₂S₄ spinel has been studied. The tetrahedral A-site substitution of the Fe by Cu in Fe_1−xCu_xCr₂S₄ was found to increase significantly the value of temperature T_m of the spin-glass like magnetization anomaly, whereas the octahedral B-site substitution of the Cr by In decreases T_m. This effect is suggested to result from a structural transformation influenced by variation of internal (chemical) pressure due to lattice contraction (Cu) or expansion (In). The observed reduced values of the Curie temperature for Cu-substituted single crystals compared to that of the polycrystalline samples are attributed to presence of Cl ions in samples detected by electron-probe microanalysis. The observed reduced value of saturation magnetization in the polycrystals compared to the single crystals is ascribed to the effect of surface anisotropy. Based on the experimental data the superexchange is concluded to be the dominant exchange interaction for 0≤x≤0.5 in Fe_1−xCu_xCr₂S₄, whereas the indirect exchange through the charge carriers is considered of minor importance.     

Representations of the Quantum Algebra Uq(un, 1)

The main aim of the paper is to study infinite-dimensional representations of the real form U _q (u _{n, 1}) of the quantized universal enveloping algebra U _q (gl _{n + 1}). We investigate the principal series of representations of U _q (u _{n, 1}) and calculate the intertwining operators for pairs of these representations. Some of the principal series representations are reducible. The structure of these representations is determined. Then we classify irreducible representations of U _q (u _{n, 1}) obtained from irreducible and reducible principal series representations. All *-representations in this set of irreducible representations are separated. Unlike the classical case, the algebra U _q (u _{n, 1}) has finite-dimensional irreducible *-representations.     

Double Salts Iodide Scintillators: Cesium Barium Iodide,Cesium Calcium Iodide,and Barium Bromine Iodide

In this study we review the state‐of‐the‐art for double salt iodide scintillators, in particular cesium barium iodide (CBI), cesium calcium iodide (CCI) and barium bromine iodide (BBI), as well as report on their scintillation and optical properties. Double salt iodides inherently have high density and atomic number which translates to good stopping power for energetic particles, in particular gamma rays. Light yields of 54,000 ph/MeV for CBI, 51,000 ph/MeV for CCI, and 46,000 ph/MeV for BBI were measured. A FWHM energy resolution for the 662 keV full absorption peak was observed at 5.7% for CBI, 16.3% for CCI and 3.56% for BBI. The principal scintillation decay timing for CBI was 840 ns, 462 ns for BBI, and two distinct time components of 9 ns and 1900 ns were observed for CCI.