The formation of ion-acoustic solitons (IASs) in an unmagnetized plasma with negative ions has been investigated through the KdV equation in both the situations \(Q^{\prime}\left( { = m_{j} /m_{i} = {\text{negative}}\;{\text{to}}\;{\text{positive}}\;{\text{ion}}\;{\text{mass}}\;{\text{ratio}}} \right)\) less and greater than one and the mKdV equation only for \(Q^{\prime} > 1\). The existence of both KdV and mKdV solitons has been established for \(\alpha \left( { = {\text{ion}}\;{\text{to}}\;{\text{electron}}\;{\text{temperature}}\;{\text{ratio}}} \right)\; > \;\beta \left( { = {\text{negative}}\;{\text{ion}}\;{\text{to}}\;{\text{electron}}\;{\text{temperature}}\;{\text{ratio}}} \right)\) and \(\alpha < \beta\), which is the new outcome of the current investigation. Furthermore, the existence of both compressive and rarefactive solitons for \(Q^{\prime} > 1\) and \(Q^{\prime} < 1\) has been demonstrated.
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