全文获取类型
收费全文 | 1294篇 |
免费 | 7篇 |
国内免费 | 2篇 |
专业分类
化学 | 463篇 |
晶体学 | 41篇 |
力学 | 70篇 |
数学 | 127篇 |
物理学 | 602篇 |
出版年
2022年 | 10篇 |
2021年 | 19篇 |
2020年 | 23篇 |
2019年 | 32篇 |
2018年 | 36篇 |
2017年 | 45篇 |
2016年 | 43篇 |
2015年 | 21篇 |
2014年 | 42篇 |
2013年 | 53篇 |
2012年 | 43篇 |
2011年 | 47篇 |
2010年 | 43篇 |
2009年 | 45篇 |
2008年 | 52篇 |
2007年 | 54篇 |
2006年 | 45篇 |
2005年 | 36篇 |
2004年 | 52篇 |
2003年 | 37篇 |
2002年 | 38篇 |
2001年 | 39篇 |
2000年 | 34篇 |
1999年 | 21篇 |
1998年 | 12篇 |
1996年 | 20篇 |
1995年 | 14篇 |
1994年 | 16篇 |
1993年 | 13篇 |
1992年 | 9篇 |
1990年 | 12篇 |
1989年 | 15篇 |
1988年 | 8篇 |
1987年 | 12篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 15篇 |
1976年 | 14篇 |
1975年 | 11篇 |
1974年 | 13篇 |
1973年 | 13篇 |
1972年 | 14篇 |
1971年 | 16篇 |
1970年 | 8篇 |
1969年 | 10篇 |
排序方式: 共有1303条查询结果,搜索用时 27 毫秒
1.
Molecular n-v complexes of quinoline N-oxides with BF3 have been studied by electronic and IR spectroscopy. In most case the donor centre is the oxygen atom of the N-oxide group.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1087–1092, August, 1994. 相似文献
2.
3.
Andreev V. N. Kolyadko E. A. Podlovchenko B. I. 《Russian Journal of Electrochemistry》2004,40(5):580-583
Radioactive tracer studies confirm the earlier electrochemical results that carbon monoxide can virtually completely displace iodine adatoms. For the first time, it is found that iodine adatoms are not displaced by carbon monoxide when iodide anions are adsorbed in the presence of an upd silver monolayer. The possible reasons for the effect observed are discussed. 相似文献
4.
The diffuse scattering of x rays in a four-layer waveguide-type heterostructure is investigated. The dynamic enhancement of
diffuse scattering is detected experimentally in regions corresponding to the excitation of waveguide modes for both the incident
and scattered waves.
Pis’ma Zh. éksp. Teor. Fiz. 66, No. 4, 219–223 (25 August 1997) 相似文献
5.
S. S. Andreev A. D. Akhsakhalyan M. A. Bibishkin N. I. Chkhalo S. V. Gaponov S. A. Gusev E. B. Kluenkov K. A. Prokhorov N. N. Salashchenko F. Schafers S. Yu. Zuev 《Central European Journal of Physics》2003,1(1):191-209
We present research investigations in the field of multilayer optics in X-ray and extreme ultra-violet ranges (XUV), aimed
at the development of optical elements for applications in experiments in physics and in scientific instrumentation. We discuss
normal incidence multilayer optics in the spectral region of “water window”, multilayer optics for collimation and focusing
of hard X-ray, multilayer dispersing elements for X-ray spectroscopy of high-temperature plasma, multilayer dispersing elements
for analysis of low Z-elements. Our research pays special attention to optimization of multilayer optics for projection EUV-lithography
(ψ-13nm) and short period multilayer optics. 相似文献
6.
Results of investigations into the physical properties of a number of new nonlinear crystals are presented. The parameters of frequency converters manufactured on their basis are compared, and second-harmonic generation of CO2 lasers first excited by frequency conversion in LiInSe2, AgGa1– x
InxSe2, AgxGaxGexS2(1 + x), and Hg1–x
CdxGa2S4 crystals is investigated. The superiority of HgGa2S4, Hg1–x
CdxGa2S4, and AgGa1–x
InxSe2 over the well-known crystals has been demonstrated for frequency conversion both within the middle-IR range and from the visible range to the middle-IR range. Advantages of LiInSe2 and AgGa1–x
InxSe2 crystals are demonstrated for the direct frequency conversion of femtosecond laser radiation to the middle-IR range compared to the cascade frequency conversion and direct frequency conversion in LiInS2 crystals. 相似文献
7.
Hyperfine structure of a hydrogen-like atom due to orbit-orbit,spin-orbit,and spin-spin interactions
A nonrelativistic model of a hydrogen-like atom is considered. This model is used to calculate corrections to the energy spectrum of the atom. The analysis is based on a Hamiltonian that includes the intratomic fields generated by the electron and the nucleus. 相似文献
8.
E. Sh. Finkel'shtein N. V. Ushakov N. A. Pritula E. A. Andreev N. A. Platé 《Russian Chemical Bulletin》1992,41(1):185-187
The thermally initiated and platinum-catalyzed polymerization of 1-silacyclobutanes with substitutents containing a trimethylsilyl group was carried out. Soluble, high-molecular-weight, heterochain siltrimethylene polymers were obtained, containing trimethylsilyl groups removed from the main chain by various bridges.A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 223–225, January, 1992. 相似文献
9.
N. A. Anikin A. S. Mendkovich M. B. Kuzminskiy A. M. Andreev 《Russian Chemical Bulletin》2008,57(2):428-430
A new fast computational method for mass calculations of docking complexes by the AM1/PM3 semiempirical methods is proposed.
The computation time is shortened by at least an order of magnitude compared to alternative schemes of quantum chemical calculations.
The root-mean-square deviation of the AM1 calculated energies of formation of complexes from the results obtained by conventional
diagonalization procedure is at most 0.4 kcal mol−1.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 418–420, February, 2008. 相似文献
10.
A.V. Andreev B. Janoušová V. Sechovský Y. Homma Y. Shiokawa 《Czechoslovak Journal of Physics》2002,52(2):275-278
We present the first single-crystal study of Fe and Ni doped U(Co1-x
T
x
)Al compounds in comparison to the parent compound, the itinerant 5f-electron metamagnet UCoAl. Magnetization and specific-heat data measured in the temperature range of (1.8-300) K and in fields up to 10 T are analyzed and discussed. Both compounds exhibit a strong uniaxial anisotropy with the dominating magnetic response along the c-axis of the hexagonal ZrNiAl-type structure. Ni substitution yields an increase of the critical field for metamagnetism; UCo0.95Fe0.05Al is ferromagnetic below 30 K. Temperature evolution of the entropy change between 0 and 10 T points to involvement of magnetic correlations or spin fluctuations in the paramagnetic compounds UCoAl and UCo0.95Ni0.05Al. 相似文献