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1.
We report on the simultaneous generation of phase-conjugate signals by degenerate four-wave mixing (DFWM) and holographic processes using a nanosecond pulse and a CW lasers in polyvinyl alcohol (PVA) films doped with four kinds of saturable absorbing dyes. For the pulse laser, of the four kinds of dye-doped PVA films, the erythrosine B-doped PVA and uranine doped-PVA films generate PC signals only by the DFWM process, while the other dye-doped PVA films generate PC signals simultaneously by not only the DFWM process but also the holographic process. Especially, the safranin T-doped PVA film generates strong PC signals by the holographic process. In contrast, all of the dye-doped PVA films generate the two types of PC signals for the CW laser. The fading of dye molecules is found to result in the generation of the holographic component of PC signals which governs the temporal behavior of the total PC signals. 相似文献
2.
Masaki Kurokiba Naoto TanakaAtusi Tani 《Journal of Mathematical Analysis and Applications》2002,272(2):448-457
In this paper we consider the Eguchi-Oki-Matsumura equation which consists of the fourth- and second-order coupled equations of parabolic type. It is shown that this system admits the unique global solution. 相似文献
3.
H. Sato A. Tani A. J. Fielding S. S. Eaton G. R. Eaton N. E. Whitehead M. Ikeya 《Applied magnetic resonance》2004,26(4):601-616
Nitrate radical NO32− in calcitic evaporate was discovered in Antarctica. The distribution and formation of nitrate radical NO32− in the calcite have been studied by pulse and continuous-wave electron spin resonance. In samples that had been annealed
to destroy the NO32−, regeneration of the radical by γ-rays or UV light indicated that the radical was formed by UV light (with wavelengths less
than 340 nm) from solar rays, not by environmental radiation. The nonuniform spatial distribution of the nitrate radical,
which was deduced from high ratios of local spin density to total spin density, suggests that the nitrate impurity was introduced
into the calcium carbonate after carbonate grain formation. Formation of the carbonate-containing nitrate requires the presence
of high amounts of nitrate and a dry climate. Formation of the nitrate radical requires sample exposure to UV light. These
conditions are satisfied in the environment of Antarctica. 相似文献
4.
Takanari Yasui Takeshi Ohtsuka Tetsu Suzuki Shigeki Okajima Kazuya Nakayama Mitsuru Tomioka Katsuhiro Kamimura Takeo Namekata Hiroaki Minamide Hiromasa Ito 《International Journal of Infrared and Millimeter Waves》2006,27(2):199-210
A new, wide-band, high-speed and high-sensitivity THz detector has been developed. The prototype detector consists of a parabolic
cylindrical mirror, a long wire antenna and a Schottky barrier diode. Direct detection measurements have shown a stable sensitivity
of 150 ± 50 V/W for 1–2 THz without any adjustments. The long wire antenna was fixed at the focus of parabolic cylindrical
mirror then it has been realized less operation steps, easy coupling to the external THz signals and a dramatic enhancement
in the practicality of this system. The optically polished mirror and frosted surface one showed comparable sensitivities,
thus easy polishing and less cost mirror fabrication can be applied for this system. The radiation pattern showed a maximum
radiation angle of approximately 23° with its dominant main lobe, which was attributed to the wire antenna character and confirmed
good agreements with classical antenna theory. 相似文献
5.
The magnesium-butadiene 1 : 1 (1), 1 : 2 (II) and 1 : 3 addition compounds obtained by the direct metalation of butadiene with metallic magnesium were isolated. These compounds have a polymeric structure. Structural analysis of these compounds by NMR and IR methods was carried out. The process for the formation of II via I and III via II was investigated. The results of protolysis and alkylation of the above magnesium compounds corresponded well to those of crotylmagnesium compounds. 相似文献
6.
7.
8.
Mechanism for polymerization of ε-caprolactam in the presence of both sodium and aluminum caprolactamate was investigated at 171°C. The role of Al(Cap)3 as an initiator was revealed. The apparent rate constant of propagation reaction decreased with the increase in the concentration of Al(Cap)3, as the two different metal salts interact even at 171°C. The activation energy of the overall polymerization reaction with this catalyst system was estimated to be 41.18 kcal/mole. 相似文献
9.
Summary A porous polymer resin loaded with hydrous zirconium oxide (Zr-gel) was evaluated as a stationary phase for the liquid chromatographic separation of disubstituted aromatic compounds. The prepared Zr-gel was used to separate disubstituted phenols andortho-substituted benzoic acid derivatives in reversed-phase mode. The retention time of catechol was greater than those of other disubstituted phenols; this implies that the Zr-gel has specificity for the phenolic hydroxyl group. The retention behavior ofortho-substituted benzoic acid derivatives on the Zr-gel was also evaluated in reversedphase mode using buffer. Phthalic acid was specifically retained in the vicinity of pH 6.0, which has been regarded as the equal adsorbic point. Similar behavior was also observed for salicylic acid, although the retention time of salicylic acid was less than that of phthalic acid. It seems that the specific retention behavior of hydrous zirconium oxide is a result of complexation with ligands such as hydroxyl and carboxyl groups. The results of this study have revealed that the retention mechanism of hydrous zirconium oxide is a combination of ion exchange and interaction based on complexation with ligands. 相似文献
10.
Hisaya Tani Tuyoshi Konomi 《Journal of polymer science. Part A, Polymer chemistry》1968,6(8):2281-2293
The high molecular weight polymer of α-piperidone, which had been unobtainable with the use of alkali metal, trialkyl aluminum, or Grignard reagent as catalyst, was prepared with M–AlEt3, (where M is alkali metal), MAlEt4 or KAlEt3 (piperidone) as catalyst and N-acyl-α-piperidone as initiator. From the determination of the behavior of the solution viscosity of poly-α-piperidone in m-cresol at 30°C. the value of 0.27 for the Huggins constant was obtained. Examination of the correlation between the number-average molecular weight, determined by endgroup titration, and the intrinsic viscosity gave a somewhat small value for the endgroup COOH. This may be considered due to the consumption of N-acyl-α-piperidone by a propagating polymer in the course of polymerization. The thermal stabilities of the polyamides, nylons 4, 5, and 6, was in the order nylons 6 > 5 > 4 according to differential thermal and thermogravimetric analyses, Poly-α-piperidone, which has a reduced viscosity of 0.7, shows a melting point of 270°C.. which was expected from the zigzag pattern of the correlation between melting points and numbers of CH2 groups for polyamino-acid polymers. 相似文献