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排序方式: 共有824条查询结果,搜索用时 62 毫秒
1.
Masaharu Asano Jinhua Chen Yasunari Maekawa Takahiro Sakamura Hitoshi Kubota Masaru Yoshida 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2624-2637
A novel process comprising the UV‐induced photografting of styrene into poly(tetrafluoroethylene) (PTFE) films and subsequent sulfonation has been developed for preparing proton‐conducting membranes. Although under UV irradiation the initial radicals were mainly generated on the surface of the PTFE films by the action of photosensitizers such as xanthone and benzoyl peroxide, the graft chains were readily propagated into the PTFE films. The sulfonation of the grafted films was performed in a chlorosulfonic acid solution. Fourier transform infrared and scanning electron microscopy were used to characterize the grafted and sulfonated membranes. With a view to use in fuel cells, the proton conductivity, water uptake, and mechanical properties of the prepared membranes were measured. Even through the degree of grafting was lower than 10%, the proton conductivity in the thickness direction of the newly prepared membranes could reach a value similar to that of a Nafion membrane. In comparison with γ‐ray radiation grafting, UV‐induced photografting is very simple and safe and is less damaging to the membranes because significant degradation of the PTFE main chains can be avoided. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2624–2637, 2007 相似文献
2.
H. Maekawa K. Tsubakihara A. Ohnishi 《The European Physical Journal A - Hadrons and Nuclei》2007,33(3):269-272
We study the hyperon-nucleus potential with distorted-wave impulse wave approximation (DWIA) using the Green's function method.
In order to include the nucleon and hyperon potential effects in Fermi averaging, we introduce the local optimal momentum
approximation of target nucleons. We can describe the quasi-free Λ , Σ and Ξ production spectra in a better way than in the
standard Fermi-averaged t -matrix treatments. 相似文献
3.
Takaaki Kakitsuka Shinji Matsuo Seok–Hwan Jeong Toru Segawa Hiroshi Okamoto Yoshihiro Kawaguchi Yasuhiro Kondo Yuzo Yoshikuni Hiroyuki Suzuki 《Optical and Quantum Electronics》2006,38(12-14):1053-1060
We theoretically investigated a digitally tunable laser with a chirped ladder filter and a ring resonator to obtain a wide wavelength tuning range covering the whole C- or L- band. The clear relation between the tuning range and laser structure, especially the ladder filter, is described analytically. The introduction of a chirped structure into a ladder filter is effective in achieving both wide tunability and a stable lasing mode. A numerical simulation based on multimode rate equations shows that a tuning range of over 40 nm and a mode suppression ratio over 40 dB can be achieved by introducing a chirped ladder filter. 相似文献
4.
S. Takahashi T. Yamashita H. Imamura S. Maekawa 《Journal of magnetism and magnetic materials》2002,240(1-3):100-102
The effect of spin relaxation on tunnel magnetoresistance (TMR) in a ferromagnet/superconductor/ferromagnet (FM/SC/FM) double tunnel junction is theoretically studied. The spin accumulation in SC is determined by balancing of the spin-injection rate and the spin-relaxation rate. In the superconducting state, the spin-relaxation time τs becomes longer with decreasing temperature, resulting in a rapid increase of TMR. The TMR of FM/SC/FM junctions provides a useful probe to extract information about spin-relaxation in superconductors. 相似文献
5.
Kiyoshi Tanemura Tsuneo Suzuki Takaaki Horaguchi Mikio Sudo 《Journal of heterocyclic chemistry》1991,28(2):305-309
A new heterocycle, furo[4,3,2-de][1]benzopyran ( 2 ), was synthesized. A key step in the sequence was the allylic bromination of 3,4-dihydrofuro[4,3,2-de][1]benzopyran ( 8 ) to give 3-bromo-3,4-dihydrofuro[4,3,2-de][1]-benzopyran ( 10 ) using N-bromosuccinimide under irradiation and high dilution conditions. Bromide 10 was dealt with 1,8-diazabicyclo[5.4.0]undec-7-ene to afford compound 2 . Several reactions of 2 were examined. Protonation of 2 in trifluoroacetic acid occurred at the 2-position to form a pyrylium ion 12 . Catalytic hydrogenation of 2 with palladium on charcoal proceeded smoothly to give 8 . Reduction of 2 by sodium and ethanol afforded 3-ethyl-4-hydroxybenzofuran ( 14 ). Electrophilic substitutions of 2 such as formylation, acetylation, and bromination, occurred easily at the 2-position. The above results show that compound 2 has both properties of benzofuran and 4-methylenepyran. 相似文献
6.
Junsaku Nitta Yiping Lin Takaaki Koga Tatsushi Akazaki 《Physica E: Low-dimensional Systems and Nanostructures》2004,20(3-4):429
We report on electron g-factor in an InAs-inserted In0.53Ga0.47As/In0.52Al0.48As heterostructure. The gate voltage dependence of g-factor is obtained from the coincidence method. The obtained g-factor values are surprisingly smaller than the g-factor value of bulk InAs, and it is close to the bare g-factor value of In0.53Ga0.47As. The large change in g-factor is observed by applying the gate voltage. The obtained gate voltage dependence is not simply explained by the energy dependence of g-factor. 相似文献
7.
8.
T. Ohishi S. Maekawa T. Ishikawa D. Kamoto 《Journal of Sol-Gel Science and Technology》1997,8(1-3):511-515
A new technique for preparing anti-reflection/anti-static thin films for CRTs at low temperature has been developed. Double-layered
films of SiO2/SnO2 were formed on a CRT panel surface by the sol-gel method using photoirradiation. The new method makes it possible to reduce
heat treatment temperature (°C) by almost 50% and treatment time to approximately 33% of the conventional levels. 相似文献
9.
Takaaki Tsuchida Gang Zheng Ravindra K. Pandey William R. Potter David A. Bellnier Barbara W. Henderson Harubumi Kato Thomas J. Dougherty 《Photochemistry and photobiology》1997,66(2):224-228
Human serum albumin (HSA) is one of the key components in human blood that may influence drug distribution. As such, it is important to know the affinity of any drug for albumin. Previously, Photofrina mixture of monomeric, dimeric and oligomeric porphyrins, has been subjected to HSA binding studies. However, due to its complex nature, binding studies on Photofrin or other hematoporphyrin derivatives with HSA are inconclusive. In this report, the binding properties of some components (dimers and trimers) of Photofrin® and the relationship between murine photosensitizing efficacy and those binding properties were investigated. The interaction of these porphyrins with HSA was investigated by direct ultrafiltration and fluorescent titration techniques with fluorescent probes such as dansyl-L-proline (DP), which is known to interact selectively with site II on HSA. Porphyrins also were tested for antitumor activity in a mouse model following intravenous administration and exposure to laser light. Together, the results suggest that the photosensitizers that were preferentially bound to site II of HSA were most effective at controlling murine tumor regrowth 相似文献
10.
Takaaki Horaguchi Hiroaki Yagoh Kiyoshi Tanemura Tsuneo Suzuki 《Journal of heterocyclic chemistry》1986,23(3):657-663
4,5-Dihydro-3H-naphtho[1,8-bc]furans 4 and 6 which have various substituents (R1 and R2) have been synthesized from 8-oxo-5,6,7,8-tetrahydro-1-naphthyloxyacetic acids 1 and 3 or their ethyl esters 2 . The reaction of acids 1 and 3 with sodium acetate in acetic anhydride gave a mixture of furans 4 and 6 and lactones 5 and 7 . The ratios of the products were varied according to the types of substituents (R1 and R2) in acids 1 and 3 . As the substituent R1 (R2 = hydrogen) in acids 1 was changed from hydrogen to a methyl, ethyl or isopropyl group, production of furans 4 became more difficult. However, when a phenyl group was used as the substituent, furan 4 was obtained in good yield. Similarly, as the substituent R2 (R1 = hydrogen) in acids 1 was changed from hydrogen to a methyl, ethyl or isopropyl group, furan formation was more difficult. In contrast, acids 3 which had electron-withdrawing substituents such as chlorine, bromine or a nitro group at the 4-position afforded furans 6 in good yield. 4,5-Dihydro-3H-naphtho[1,8-bc]furans 4 and 4,5-dihydro-3H-naphtho[1,8-bc]furan-2-carbocylic acids 8 were synthesized from the reaction of esters 2 and potassium hydroxide in dioxane. When the substituents R1 or R2 in esters 2 were varied from hydrogen to a methyl, ethyl or isopropyl group the total yields of furans 4 and furancarboxylic acids 8 were reduced. 相似文献