脲基苯乙炔4-′(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物的合成

本文通过异氰酸酰化反应合成了含有脲基的苯乙炔新型配体及以它作为辅助配体的4′-(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物,初步研究了铂(II)络合物的光物理性质,发现由于脲基的存在,当浓度大于3.32×10-5mol/L时铂(II)络合物能够发生分子间簇集.     

A Novel Proton Sensor with Luminescence and Color Signaling Based on Platinum(II) Terpyridyl Acetylide Complex

Molecular switches that are controllable, reversible and readable at molecular level are an essential compo-nent of molecular electronics1 and chemical sensors.2-6 Of particular interest are the molecules which show dramatic and reversible changes in color and/or lumi-nescence in visible spectral region upon exposure to specific substrates. A number of chromophore- spacer-receptor systems that can selectively recognize specific guest molecules at their receptor site and pro-duce measurable col…     

Synthesis and Luminescent Properties of an Acetylide-Bridged Dinuclear Platinum(II) Terpyridyl Complex

Introduction Luminescent coordinatively unsaturated platinum(II) complexes are appealing from photochemical and pho-tophysical perspective.1,2 In particular, platinum(II) ter-pyridyl complexes have attracted considerable attention due to their rich spectroscopic2a-d and biological proper-ties.2a,e-g However, the development of the photochem-istry of these complexes is limited by their short-lived MLCT excited state in solution at room temperature. The lack of emission originates from low-l…     

Interlayer Energy Transfer from Naphthalene to Anthracene Chromophores Organized in Langmuir—Blodgett Films

Interlayer energy transfer between 2,3-naphthol-10-hexadecylaza-15-crown-5(NC16) and N-[1-(9-methoxyanthryl)] decylaza-15-crown-5(A10C) within multilayer Langmuir-Blodgett films has been studied by steady-state fluorescence spectra. The donor and acceptor could be separated precisely by inserting stearic acid (SA) spacers. The efficiency of the energy transfer increases with the decrease in the donor-acceptor distance by a quadratic manner, suggesting the donor excitations are delocalized in the layer.     

Photoisomerization of norbornadiene group in a rigid bichromophoric compound initiated by remote keto chromophore: long-distance through-bond triplet energy transfer

A diad compound 3β(bicyclo[2,2,1]hepta-2,5-diene-2-methylcarboxylate-3-carboxy)-an-drost-5-en-17-one (NBD-S-ONE) was synthesized and its photochemistry was examined. Irradiation of NBD-S-ONE in acetonitrile at λ > 300 nm selectively excited the keto chromophore. After intersystem crossing, the triplet energy of the keto group was transferred to the NBD group with 18.6% efficiency via a through-bond mechanism, resulting in the isomerization of the latter group to the quadricyclane group.     

Synthesis and Study of Two-Photon Induced Fluorescence of Novel Dyes

Morerecently,thesynthesisofnewdyeswithlargeupconvertedfluorescencebecomesthefocusoftheresearchandhasopenedupamyriadofapplications.Theapplicationsincludetwo-photoninducedlasing',two-photonopticalpowerlimiting',threedimensionalopticaldatastorage',andphotodynamictherapy'.Nevertheless,thistechniquehasneverreacheditsfullpotentialduetothelackofdyeswhichexhibithighupconvertedfluorescentilltensity.ThisrepoFtdescribesthesynthesisandpropertiesoftwo-photoninducedfluorescencedyeswhicharespecificallydesign…     

疏水作用对光化学和光物理过程的影响 Ⅻ.2-羟基-4-烷氧基二苯甲酮在不良溶剂中的簇集

测定了2-羟基-4-甲氧基二苯甲酮(HMDB)和2-羟基-4-辛氧基二苯甲酮(HODB)在良溶剂和不良溶剂中的吸收光谱。在不良溶剂(乙二醇-水的混合溶剂)中,带长链的HODB发生簇集。由于簇集体内极性较小,HODB的吸收光谱与其在环己烷中相似。HMDB不发生簇集。     

ENHANCEMENT OF ENERGY TRANSFER FROM THE TERMINAL CHROMOPHORE OF POLYETHER TO EUROPIUM CATION(Ⅲ)VIA COMPLEXATION

The fluorescence spectra of naphthalene end-labelled polyethylene glycol)(N-P_nN) in methanol solution in the presence of europium cation(Ⅲ) was investigated. Selective excitation of the naphthalene group of N-P_n-N re-sults in the emission of europium cation. suggesting that the polyether chain complexes with europium cation, thus efficient energy transfer from naphthalene chromophore to europium cation occurs. Photoirradiation of N-P-N in solution leads to intramolecular dimerization of the two terminal naphthalene groups to give a crown ether. The complexation of this photochemically synthesized crown ether and europium cation was also studied.     

Colorimetric and electrochemical Pb~(2+) detection by imine-bridged tetrathiafulvalene-pyridine derivatives

Imine-bridged TTF-π-pyridine derivatives, 2NTTF, 3NTTF and 4NTTF, were synthesized and the cation-binding study was performed. It is noted that with the addition of the micromolar concentration of Pb2+ to the solution, these compounds display remarkable changes in solution color, 1H NMR spectra and electrochemical properties. The nitrogen atom of the imine-bridge in 2NTTF not only serves as a π-conjugated spacer but also participates in the sensing and coordinating properties.     

Nafion-Induced Metal-Metal Interactions in a Platinum(II) Terpyridyl Acetylide Complex:a Luminescent Sensor for Detection of Volatile Organic Compounds

Introduction The design of new solid-state sensor materials that can selectively adsorb volatile organic compounds (VOC) and produce measurable color and/or lumines-cence changes is of potential significance in the sense of environmental and public safety control.1-5 The use of metal complexes as optical sensors for VOC detection has been reported, and most of them are based on the susceptibility of metal-to-ligand charge transfer (MLCT) and/or metal-metal-to-ligand charge transfer (MMLC…