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排序方式: 共有110条查询结果,搜索用时 15 毫秒
1.
The present paper deals with the experimental and theoretical determination of energies of conjugation of organic molecules.A computation process has been applied, first to simple molecules comprising an hydrocarbon (styrene), an oxygen function (benzaldehyde) and a nitrogen function (aniline). The results are compared with those obtained from the literature.The application of this computation process to naphthoic acids permits the determination of energies of conjugation and isomerization of these molecules. 相似文献
2.
Study of the cis-trans isomerization of enalapril by reversed-phase liquid chromatography 总被引:2,自引:0,他引:2
Trabelsi H Bouabdallah S Sabbah S Raouafi F Bouzouita K 《Journal of chromatography. A》2000,871(1-2):189-199
Enalapril is a dipeptidic angiotensin converting enzyme inhibitor. It exists as a mixture of two conformers in solution with respect to the peptide bond involving the proline amino group. The RPLC of such products may yield peak splitting or multiple peaks as a result of the slow kinetics of the conformation change. In this study, the influence of the flow-rate, pH, temperature, organic modifier and counter ion on the peak shape and the separation of the cis and trans conformers are examined qualitatively by HPLC. It appears that decrease of relaxation time for isomerization with concomitant improvement in peak shape is favoured by a decrease in pH and flow-rate, increase of temperature, choice of organic solvent (nature, amount) and cationic counter ion concentration in the mobile phase. The elution order of the isomers was dependent on the nature of the organic modifier whereas the separation selectivity was improved by an increase of pH or the addition of a negatively charged counter ion. In addition, an NMR investigation on enalapril is described. 相似文献
3.
Mechanical and physico-chemical characterization of cyclodextrin finished polyamide fibers 总被引:2,自引:0,他引:2
Yassine El Ghoul Bernard Martel Michel Morcellet Christine Campagne Ahmida El Achari Sadok Roudesli 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):47-52
We present the study of the cyclodextrin (CDs) finishing of polyamide fibers (PA) by means of citric acid (CTR) as crosslinking agent. We observed that the mode of grafting happened by the formation of a crosslinked polymer formed between CTR and CDs. This polymer physically adhered to the fibers network and was resistant to hot water washings. Modified fibers were characterized by evaluating the contact angle with a polar liquid and by studying the hysteresis of damping of PA fibers (Cahn balance) with various grafting rates and by studying the absorptivity of grafted fabrics via the technique of the posed drop (Digidrop® instrument). Then a mechanical characterization of the PA fabrics grafted with various proportions of CDs was accomplished, by traction and tear tests by using a tensile-test bench Lohmergy. Finally a topographic study of PA grafted surfaces was approached by atomic force microscopy (AFM and LFM; contact and non-contact mode) which permitted to evaluate the roughness and the chemical heterogeneity of the grafted surfaces. 相似文献
4.
Using our technique of combustion of small amount of a substance, we determined by calorimetry the standard molar enthalpy of formation in the condensed state and atT=298.15 K of the three isomers of bromo and iodobenzoic acids. Associating to these values their standard molar enthalpies of sublimation previously measured, it was possible to determine their standard molar enthalpies of formation in the gaseous state and atT=298.15 K. The experimental values of the thermodynamic properties f
H
m
o
(cr, 298.15 K), f
H
m
o
(cr, 298.15 K), sub
H
m
o
(298.15 K), and f
H
m
o
(g, 298.15 K) are given for the two series. From the experimental value of the standard molar enthalpy of atomization, it was possible to determine an enthalpy value for the Cb-Br and Cb-I bonds. The experimental and theoretical values of the resonance energy of bromo and iodobenzoic acids are compatible. The relative stability of some monosubstituted derivatives of benzoic acid studied in our laboratory is also discussed.Part I is concerned with Ref. 22 (for bromobenzoic acids) and with Ref. 23 (for iodobenzoic acids). 相似文献
5.
A novel gas diffusion-flow injection method has been developed for the rapid and sensitive determination of total inorganic carbon (TIC) in water. The method is based on the diffusion of CO2 across gas permeable membrane from a donor stream containing 0.1 M HCl to an acceptor stream of sodium acetate (10−5 mol l−1 and pH 10). The CO2 trapped in the acceptor stream passes through an electrochemical flow cell contains a tungsten oxide wire and a silver/silver chloride electrode, where it was sensitively detected. The parameters affecting the sensitivity of the electrode such as buffer concentration, pH, flow rate and injected volume were studied in detail. The electrode response was linear in the concentration range from 5 to 100 μg ml−1 CO32− with a correlation coefficient (R2) of 0.998. Precision (R.S.D.) was 1.42% for 20 μg ml−1 standard solution of CO32− (n=10). The detection limit was 0.20 μg ml−1 CO32−. The method was evaluated by the injection of real natural water samples and an average recovery of 100.1% was obtained. The sampling rate was 30 samples h−1. The method is simple, feasible with satisfactory accuracy and precision and thus could be used for monitoring TIC in water. 相似文献
6.
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8.
We relate the brace products of a fibration with section tothe differentials in its Serre spectral sequence. In the particularcase of free loop fibrations, we establish a link between thesedifferentials and Browder operations in the fiber. Applicationsand several calculations (for the particular cases of spheresand wedges of spheres) are given. 2000 Mathematical SubjectClassification: 55P35, 55Q15, 55R05, 55R20. 相似文献
9.
Alexandru Dimca Fayçal Maaref Claude Sabbah Morihiko Saito 《Mathematische Annalen》2000,318(1):107-125
Using local cohomology and algebraic -Modules, we generalize a comparison theorem between relative de Rham cohomology and Dwork cohomology due to N. Katz, P. Monsky,
A. Adolphson and S. Sperber.
Received June 10, 1999 / Published online July 20, 2000 相似文献
10.