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1.
An intermolecular aldol reaction of 20S-camptothecin-7-aldehyde in the presence of strong bases affords an unusual dimeric compound, the structure and stereochemistry of which was assigned on the basis of NMR analysis and MM2 calculations. 相似文献
2.
R. L. Moreira P. Saint-Grgoire M. Lopez M. Latour 《Journal of Polymer Science.Polymer Physics》1989,27(3):709-722
The thermal and dielectric behaviors of poly(vinylidene fluoride-trifluoroethylene) copolymers near the ferroelectric-to-paraelectric phase transition are investigated for samples with 20, 25, 30, and 40 mol% trifluoroethylene (TrFE). The data suggest that the transition becomes continuous for a particular composition near 50 mol% TrFE. Experimental data are sensitive to thermal history (kinetics of crystallization, and kinetics and cycling over the structural transition). It is found that several anomalies are present at the structural change, and in particular the 30 mol% TrFE sample shows the most marked anomalies. These phenomena can be attributed to defects, but another possibility would be the existence of an intemediate supplementary phase. Both hypotheses are discussed. 相似文献
3.
J. Łukasik G. Auger M. L. Begemann-Blaich N. Bellaize R. Bittiger F. Bocage B. Borderie R. Bougault B. Bouriquet J. L. Charvet A. Chbihi R. Dayras D. Durand J. D. Frankland E. Galichet D. Gourio D. Guinet S. Hudan P. Lautesse F. Lavaud A. Le Fèvre R. Legrain O. Lopez U. Lynen W. F. J. Müller L. Nalpas H. Orth E. Plagnol E. Rosato A. Saija C. Schwarz C. Sfienti B. Tamain W. Trautmann A. Trzciński K. Turzó E. Vient M. Vigilante C. Volant B. Zwiegliński 《Acta Physica Hungarica A》2006,25(2-4):229-239
Directed and elliptic flow for the 197Au+197Au system at incident energies between 40 and 150 MeV per nucleon has been measured using the INDRA 4π multi-detector. For semi-central collisions, the excitation function of elliptic flow shows a transition from in-plane to out-of-plane emission at around 100 MeV per nucleon. The directed flow changes sign at a bombarding energy between 50 and 60 MeV per nucleon and remains negative at lower energies. Molecular dynamics calculations (CHIMERA) indicate sensitivity of the global squeeze-out transition on the σ NN and demonstrate the importance of angular momentum conservation in transport codes at low energies. 相似文献
4.
Normal human dermal fibroblasts: proteomic analysis of cell layer and culture medium. 总被引:7,自引:0,他引:7
Federica Boraldi Luca Bini Sabrina Liberatori Alessandro Armini Vitaliano Pallini Roberta Tiozzo Ivonne Pasquali Ronchetti Daniela Quaglino 《Electrophoresis》2003,24(7-8):1292-1310
Proteins present within the cell layer and those released in the cell medium from in vitro cultured normal human dermal fibroblasts were separated and characterized in terms of their isoelectric point and molecular weight, by two-dimensional (2-D) gel electrophoresis. All spots in the synthetic gel were firstly analyzed by the Melanie 3 software and compared with those of breast cancer cells, colorectal epithelial cells, HL60, lymphoma cells, and platelets, already available on-line. From the identification of 144 spots from both the cell layer and the medium, we were able to recognize 89 different proteins, since a certain number of spots represented different isoforms of the same molecule. Identifications were performed by matching with on-line 2-D databases, and by matrix assisted laser-desorption/ionization-time of flight-mass spectrometry (MALDI-TOF-MS), in order to confirm the identification by matching, or to identify new proteins. The procedure we used allows (i) to design a highly reproducible reference map of the proteome of adult human normal fibroblasts in culture, (ii) to evaluate protein species produced in the cell layer as well as those released in the culture medium, and (iii) to compare data from gel matching with those obtained by MS. This work represents an essential step for a better knowledge of mesenchymal cells, given the widespread use of this cell type in both clinical and experimental investigations. 相似文献
5.
N. Segovia M. A. Armienta C. Valdes M. Mena J. L. Seidel M. Monnin P. Pea M. B. E. Lopez A. V. Reyes 《Radiation measurements》2003,36(1-6):379-383
Soil radon has been monitored at two fixed stations in the northern flank of Popocatepetl Volcano, a high risk volcano located 60 km SE from Mexico City. Water samples from three springs were also studied for radon as well as major and trace elements. Radon in the soil was recorded using track detectors. Radon in the water samples was evaluated using the liquid scintillation method and an Alphaguard. The major elements were determined through conventional chemical methods and trace elements using an ICP-MS equipment. Soil radon levels were low, indicating a moderate diffuse degassing through the flanks of the volcano. Groundwater radon had almost no relation with the eruptive stages. Water chemistry was stable in the reported time (2000–2002). 相似文献
6.
M. Lopez Noriega 《The European Physical Journal C - Particles and Fields》2007,49(1):315-319
The strong suppression of high-pT hadrons observed in heavy ion collisions at RHIC indicates the interaction of high energy partons with a dense colored medium
prior to hadronization. We review the main results from the high-pT hadron analysis at RHIC and what they tell us about the medium. We then concentrate on the new possibilities that the wider
kinematic range at the LHC will offer and how they will help us to better characterize the medium produced in these collisions. 相似文献
7.
Katalytische Epoxidierung und 1,2‐Dihydroxylierung von Olefinen mit Bispidin‐Eisen(II)/H2O2‐Systemen
8.
L. M. Lopez Marin D. Promé M. A. Lanéelle M. Daffé J. C. Promé 《Journal of the American Society for Mass Spectrometry》1992,3(6):656-661
Mycobacteria contain species- and type-specific antigens. Among them, glycopeptidolipids are present in medically relevant organisms belonging to Mycobacterium avium or M. fortuitum complexes. Fast-a tom bombardment mass spectrometry of glycopeptidolipids has proven to be difficult. In this article the cationization method with a metanitrobenzyl alcohol matrix, doped with sodium iodide, is described for analyzing these molecules. The molecular weight of the intact glycopeptidolipids was successfully determined and, using mass-analyzed ion kinetic energy spectrometry, the complete sequences of the peptide and saccharide moieties were elucidated. Moreover, the two structural variants present in these molecules were clearly differentiated. Application of the method showed that the same structural variant occurs in the glycopeptidolipids from two serologically related species of the M. fortuitum complex. 相似文献
9.
We shall prove here that any binary relation on a base E with cardinality n > 6 is reconstructible from its restrictions of cardinality 2, 3, 4 and (n - 1). This proof needs results of part I of this paper where we characterize any pair of relations R, R' which are 2-, 3- and 4-hypomorphic. As a corollary we obtain that any binary relation is (n - 4)-reconstructible (when n > 9). 相似文献
10.
Kochocki JA Allison WW Alner GJ Ambats I Ayres DS Balka LJ Barr GD Barrett WL Benjamin D Border P Brooks CB Cobb JH Cockerill DJ Coover K Courant H Dahlin B DasGupta U Dawson JW Edwards VW Fields TH Kirby-Gallagher LM Garcia-Garcia C Giles RH Goodman MC Heller K Heppelman S Hill N Hoftiezer JH Jankowski DJ Johns K Joyce T Kafka T Litchfield PJ Lopez FV Lowe M Mann WA Marshak ML May EN McMaster L Milburn RH Miller W Napier A Oliver WP Pearce GF Perkins DH Peterson EA Price LE Roback D Rosen DB 《Physical review D: Particles and fields》1990,42(9):2967-2973