全文获取类型
收费全文 | 805篇 |
免费 | 42篇 |
国内免费 | 2篇 |
专业分类
化学 | 597篇 |
晶体学 | 5篇 |
力学 | 16篇 |
数学 | 73篇 |
物理学 | 158篇 |
出版年
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 13篇 |
2019年 | 13篇 |
2018年 | 9篇 |
2017年 | 7篇 |
2016年 | 14篇 |
2015年 | 23篇 |
2014年 | 25篇 |
2013年 | 32篇 |
2012年 | 44篇 |
2011年 | 56篇 |
2010年 | 28篇 |
2009年 | 30篇 |
2008年 | 46篇 |
2007年 | 54篇 |
2006年 | 57篇 |
2005年 | 41篇 |
2004年 | 35篇 |
2003年 | 32篇 |
2002年 | 38篇 |
2001年 | 17篇 |
2000年 | 14篇 |
1999年 | 6篇 |
1998年 | 9篇 |
1997年 | 3篇 |
1996年 | 10篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 14篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 11篇 |
1986年 | 3篇 |
1985年 | 13篇 |
1984年 | 17篇 |
1983年 | 3篇 |
1982年 | 16篇 |
1981年 | 9篇 |
1980年 | 4篇 |
1979年 | 8篇 |
1978年 | 8篇 |
1977年 | 3篇 |
1976年 | 5篇 |
1975年 | 5篇 |
1974年 | 8篇 |
1973年 | 6篇 |
排序方式: 共有849条查询结果,搜索用时 197 毫秒
1.
Romanenko G. V. Letyagin G. A. Maryunina K. Yu. Bogomyakov A. S. Nishihara S. Inoue K. Ovcharenko V. I. 《Russian Chemical Bulletin》2020,69(8):1530-1536
Russian Chemical Bulletin - The study is concerned with structural rearrangements in the crystals of heterospin complexes Cu(hfac)2 with nitroxide radicals LR (hfac is hexafluoroacetylacetonate, LR... 相似文献
2.
S. I. Anisimov V. V. Zhakhovskii N. A. Inogamov K. Nishihara A. M. Oparin Yu. V. Petrov 《JETP Letters》2003,77(11):606-610
Molecular-dynamics (MD) simulation of the destruction of a crystal film heated by a femtosecond laser pulse was carried out. Heating is assumed to be instantaneous, because there is no time for the material to be displaced during the pulse. Film destruction is caused by the interaction of unloading waves. It can be considered as a model of a more complex process of splitting out of a thin surface layer from a massive target in the case where the layer remains solid after heating. It was found that the crystal order is broken due to the stretching strains and to the strong anisotropy of residual stress, resulting in a bipartition of the layer separating from the target. The lattice stretching and the formation of anisotropic stresses are due to the expansion of a heated lattice. 相似文献
3.
Oscillation is found in many biological systems, and among them the enzymatic oscillatory reaction has been well studied using an enzyme solution. We show in this study for the first time that oscillation occurs when catalase is immobilized to controlled pore glass (CPG). The oscillatory wave mode changes with the distance among the CPG, electrode, or dialysis membrane. The lower substrate concentration results in oscillation with a longer period. This tendency agrees with a previous study using an enzyme solution. Furthermore, we show that the oscillation occurs when no dialysis membrane is used. These results show the wider applicability of the system to analysis or novel device fabrication. 相似文献
4.
Yoshikazu Takada 《Annals of the Institute of Statistical Mathematics》1998,50(2):325-335
This paper gives a condition which implies the nonexistence of parametric statistical procedures with bounded risk or error performance characteristics. Many examples for which such a condition is satisfied are considered. 相似文献
5.
The engineering of many modern electronic devices demands control over a crystal down to the thickness of a single layer of atoms—and future demands will be even more challenging. Such control is achieved by the method of crystal growth known as epitaxy, and that makes this method the subject of intense study. More than that, recent advances are revolutionizing our knowledge of how surfaces grow. In fact, growing surfaces show a beautifully rich variety of phenomena, many of which are only now beginning to be uncovered. In the past few years many surface imaging techniques have been used to give us a close look at how crystals grow—while they are growing. The purpose of this article will be to illustrate some of the ways real surfaces grow and change as revealed by some of the latest in situ microscopic imaging technologies.
It is often said that crystal growth is more of an art than a science. Here we will show that it is emphatically both. 相似文献
6.
7.
Masahiro Nakao Chikako Yamazaki Hiroshi Tominaga Takako Yamaguchi Yoshikazu Fujita 《Analytical sciences》2006,22(2):313-316
A simple and highly sensitive spectrophotometric method for the determination of anthracycline anticancer agents, such as Daunorubicin hydrochloride (DAU), was established by using aluminum(III) and Chromazurol S (CAS) in a nonionic surfactant micellar medium. In the case of determination of DAU, the apparent molar absorptivity was 1.3 x 10(5) dm3 mol(-1) cm(-1) at 615 nm. Beer's law was obeyed in the concentration range of 0.028 - 2.82 microg ml(-1) for DAU. Owing to no need for solvent extraction, this method could be applied to assays of DAU and related drugs in pharmaceutical preparations. 相似文献
8.
9.
Sakuratani Y Yamada J Kasai K Noguchi Y Nishihara T 《SAR and QSAR in environmental research》2005,16(5):403-431
External validation of the biodegradability prediction model CATABOL was conducted using test data of 338 existing chemicals and 1123 new chemicals under the Japanese Chemical Substances Control Law. CATABOL predicts that 1089 chemicals will have a BOD < 60% while 925 (85%) actually have an observed BOD<60%. The percentage of chemicals with an observed BOD value <60% tends to increase as the predicted BOD values decrease. In contrast, 340 chemicals were predicted to have a BOD > or = 60% and 234 (69%) actually had an observed BOD > or = 60%. The prediction of poor biodegradability was more accurate than the predictions of high biodegradability. The features of chemical structures affecting CATABOL predictability were also investigated. 相似文献
10.
D. N. Dybtsev M. P. Yutkin E. V. Peresypkina A. V. Virovets Y. Hasegawa H. Nishihara V. P. Fedin 《Russian Chemical Bulletin》2007,56(9):1782-1786
The reaction of Co(NO3)2·6H2O with 1,3,5-benzenetricarboxylic acid (H3btc, trimesic acid) in DMF at 100 °C afforded the coordination polymer [Co3(dmf)6(btc)(Hbtc)(H2btc)]··9H2O (1) (dmf is N,N′-dimethylformamide, DMF). According to the X-ray diffraction study, the metal-organic coordination polymer is composed of
planar honeycomb (6,3) networks, in which the organic benzenetricarboxylate anions and the inorganic Co2+ cations play a role of three-connected nodes. Disordered water molecules are intercalated between the layers. A study of
the magnetic properties showed the presence of a weak antiferromagnetic coupling between the Co2+ ions (S = 3/2).
Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1719–1723, September, 2007. 相似文献