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环状芴基张力半导体由于其特殊的分子结构,发射状排布的p轨道和纳米级空腔等诸多特点,引起了科学家广泛的关注.相对于直链型芴基半导体,环状芴基张力半导体展现出独特的光电性质.然而,迄今为止其振动性质没有被报道.对四元环芴的晶体与直链四聚芴粉末样品进行拉曼光谱表征和归一化处理,并结合理论计算.结果表明,与直链寡聚芴相比,环芴类似于碳纳米管的G峰发生了偏移,并且低频区域拉曼频移峰的峰强增加.其原因是由于张力的引入,改变了芴基主链的骨架和电子结构,加强芴骨架上π电子离域,同时使环芴中每个芴单元都参与到振动中.该研究结果为芴基张力半导体材料拉曼光谱的研究提供了一定的工作基础. 相似文献
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Flavan-3-ols are a series of natural products widely present in plants and show versatile biological activities. The structures of such compounds are characterized by owing two adjacent chiral centers and three rings. Their interesting structures and promising biological activities have driven increasing research developments toward the preparation of enantioenriched flavan-3-ols. This review summarizes the recent approaches for the asymmetric synthesis of chiral flavan-3-ols from two strategies in the construction of chiral centers. The key steps in the synthetic protocol involve Sharpless asymmetric dihydroxylation, Shi asymmetric epoxidation and Sharpless asymmetric epoxidation. 相似文献
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Dr. Yinxiang Zeng Zhihao Pei Dr. Yan Guo Dr. Deyan Luan Prof. Xiaojun Gu Prof. Xiong Wen Lou 《Angewandte Chemie (International ed. in English)》2023,62(45):e202312145
Constructing multifunctional interphases to suppress the rampant Zn dendrite growth and detrimental side reactions is crucial for Zn anodes. Herein, a phytic acid (PA)-ZnAl coordination compound is demonstrated as a versatile interphase layer to stabilize Zn anodes. The zincophilic PA-ZnAl layer can manipulate Zn2+ flux and promote rapid desolvation kinetics, ensuring the uniform Zn deposition with dendrite-free morphology. Moreover, the robust PA-ZnAl protective layer can effectively inhibit the hydrogen evolution reaction and formation of byproducts, further contributing to the reversible Zn plating/stripping with high Coulombic efficiency. As a result, the Zn@PA-ZnAl electrode shows a lower Zn nucleation overpotential and higher Zn2+ transference number compared with bare Zn. The Zn@PA-ZnAl symmetric cell exhibits a prolonged lifespan of 650 h tested at 5 mA cm−2 and 5 mAh cm−2. Furthermore, the assembled Zn battery full cell based on this Zn@PA-ZnAl anode also delivers decent cycling stability even under harsh conditions. 相似文献
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电镀液和电镀层中钯和钴的分光光度法同时测定 总被引:2,自引:0,他引:2
在PH=4.5的HAc-NaAc介质中,钴和钯都能与2-「2-(6-甲基苯并噻唑)偶氮」-5-「N-甲基-N-乙羧基」苯甲酸(简称MCB)形成络合物。在λ=710nm处Co-MCB不吸收;在610.5nm处Co-MCB有最大吸收,而Pd-MCB也有一定的吸收值。利用这一差异,在可610.5nm处测定Pd和Co的合量,而在710nm处测定Pd的含量学与化学传感再利用系数法算出Co的含量。测定了纯性范 相似文献
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Mingyang Li Xinjun He Yinxiang Zeng Meiqiong Chen Ziyang Zhang Hao Yang Pingping Fang Xihong Lu Yexiang Tong 《Chemical science》2015,6(12):6799-6805
Hydrogen gas is emerging as an attractive fuel with high energy density for the direction of energy resources in the future. Designing integrated devices based on a photoelectrochemical (PEC) cell and a microbial fuel cell (MFC) represents a promising strategy to produce hydrogen fuel at a low price. In this work, we demonstrate a new solar-microbial (PEC–MFC) hybrid device based on the oxygen-deficient Nb2O5 nanoporous (Nb2O5–x NPs) anodes for sustainable hydrogen generation without external bias for the first time. Owing to the improved conductivity and porous structure, the as-prepared Nb2O5–x NPs film yields a remarkable photocurrent density of 0.9 mA cm–2 at 0.6 V (vs. SCE) in 1 M KOH aqueous solution under light irradiation, and can achieve a maximum power density of 1196 mW m–2 when used as an anode in a MFC device. More importantly, a solar-microbial hybrid system by combining a PEC cell with a MFC is designed, in which the Nb2O5–x NPs electrodes function as both anodes. The as-fabricated PEC–MFC hybrid device can simultaneously realize electricity and hydrogen using organic matter and solar light at zero external bias. This novel design and attempt might provide guidance for other materials to convert and store energy. 相似文献
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Dual‐Doped Molybdenum Trioxide Nanowires: A Bifunctional Anode for Fiber‐Shaped Asymmetric Supercapacitors and Microbial Fuel Cells 下载免费PDF全文
Minghao Yu Xinyu Cheng Yinxiang Zeng Zilong Wang Prof. Yexiang Tong Prof. Xihong Lu Prof. Shihe Yang 《Angewandte Chemie (International ed. in English)》2016,55(23):6762-6766
A novel in situ N and low‐valence‐state Mo dual doping strategy was employed to significantly improve the conductivity, active‐site accessibility, and electrochemical stability of MoO3, drastically boosting its electrochemical properties. Consequently, our optimized N‐MoO3?x nanowires exhibited exceptional performances as a bifunctional anode material for both fiber‐shaped asymmetric supercapacitors (ASCs) and microbial fuel cells (MFCs). The flexible fiber‐shaped ASC and MFC device based on the N‐MoO3?x anode could deliver an unprecedentedly high energy density of 2.29 mWh cm?3 and a remarkable power density of 0.76 μW cm?1, respectively. Such a bifunctional fiber‐shaped N‐MoO3?x electrode opens the way to integrate the electricity generation and storage for self‐powered sources. 相似文献
8.
A scheme of circular controlled quantum teleportation, which is a novel version of bidirectional controlled quantum teleportation, is proposed using a specific genuine seven-qubit entangled state as quantum channel, and then it is generalized to the scene with a general genuine seven-qubit entangled state as channel. This means that with the control of the supervisor Daniel while Alice teleportates an unknown qubit state to Bob, Bob can also teleportate an unknown qubit state to Charlie and Charlie can also teleportate an unknown qubit state to Alice circularly, simultaneously. Compared with the BCQT schemes proposed before, the intrinsic efficiency of our scheme is optimal.
相似文献9.
Dr. Yan Zhang Dr. Margaret A. Hopkins Dr. David J. Liptrot Dr. Hamideh Khanbareh Prof. Pim Groen Xuefan Zhou Prof. Dou Zhang Yinxiang Bao Prof. Kechao Zhou Prof. Chris R. Bowen Dr. David R. Carbery 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):7882-7886
We demonstrate that trimethylamine borane can exhibit desirable piezoelectric and pyroelectric properties. The material was shown to be able operate as a flexible film for both thermal sensing, thermal energy conversion and mechanical sensing with high open circuit voltages (>10 V). A piezoelectric coefficient of d33≈10–16 pC N−1, and pyroelectric coefficient of p≈25.8 μC m−2 K−1 were achieved after poling, with high pyroelectric figure of merits for sensing and harvesting, along with a relative permittivity of 6.3. 相似文献
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Icotinib, 4-[(3-ethynylphenyl)amino]-6,7-benzo-12-crown-4-quinazoline, is a new antitumor agent. The metabolic pathway of icotinib in rats was studied using liquid chromatography/tandem mass spectrometry (LC/MS(n)) analysis. Full scan and selected ion monitoring modes were used to profile the possible metabolites of icotinib in rat urine, feces and bile samples. Four phase I metabolites (M1-M4) and two phase II metabolites (M5, M6) were detected and characterized. Multiple-stage mass spectrometry and nuclear magnetic resonance (NMR) spectrometry were employed to elucidate structures of metabolites. Icotinib was metabolized to open the crown ether ring to form the main phase I metabolites. During metabolism, a reactive metabolite was formed. Using semicarbazide as a trapping agent, an intermediate arising from opening of the crown ether ring was detected as an aldehyde product by LC/MS/MS. These data indicated that ring opening of the crown ether was triggered by hydroxylation at the 8'-position of the ring to form a hemiacetal intermediate, which was further oxidized or reduced. Finally, the metabolic pathway of icotinib in rats was proposed. 相似文献