2.
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g
?1 at a charge/discharge rate of 1 A g
?1), good rate capability (a decay of 33 % in
Csp with charge/discharge rates increasing from 1 to 20 A g
?1), and high cycle stability (only a small decrease of 4.2 % in
Csp after 1000 cycles at a scan rate of 100 mV s
?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg
?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in
Csp after 2000 and 5000 cycles, respectively).
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